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論文

The BCC $$rightarrow$$ FCC hierarchical martensite transformation under dynamic impact in FeMnAlNiTi alloy

Li, C.*; Fang, W.*; Yu, H. Y.*; Peng, T.*; Yao, Z. T.*; Liu, W. G.*; Zhang, X.*; 徐 平光; Yin, F.*

Materials Science & Engineering A, 892, p.146096_1 - 146096_11, 2024/02

 被引用回数:0 パーセンタイル:0.04(Nanoscience & Nanotechnology)

The quasi-static superelastic responses and hierarchical martensite transformation from body-centered cubic (BCC) to face-centered cubic (FCC) under dynamic impact in Fe$$_{42}$$Mn$$_{34}$$Al$$_{15}$$Ni$$_{7.5}$$Ti$$_{1.5}$$ alloys were investigated. Polycrystalline and oligocrystalline alloys were produced through solution heat treatment and cyclic heat treatment processes, respectively. The results show the volume fraction of residual martensite for oligocrystalline alloys is lower, which exhibits better superelastic responses compared with polycrystalline alloys. Dynamic impact tests indicate that, despite the weakening of the grain boundary strengthening effect, the ultimate strength of the oligocrystalline alloys closely matches that of the polycrystalline alloys under dynamic impact. The martensite transformation of the FeMnAlNiTi alloy is characterized as hierarchical under dynamic impact, and increasing strain rates and grain sizes can enhance the BCC $$rightarrow$$ FCC martensite transformation, resulting in higher martensite phase fractions for oligocrystalline alloys. The increase in ultimate strength is attributed to the dynamic Hall-Petch effect introduced by more martensite phase interfaces under dynamic impact.

論文

Stacking fault driven phase transformation in CrCoNi medium entropy alloy

He, H.*; Naeem, M.*; Zhang, F.*; Zhao, Y.*; Harjo, S.; 川崎 卓郎; Wang, B.*; Wu, X.*; Lan, S.*; Wu, Z.*; et al.

Nano Letters, 21(3), p.1419 - 1426, 2021/02

 被引用回数:41 パーセンタイル:95.34(Chemistry, Multidisciplinary)

In CrCoNi, a so-called medium-entropy alloy, an fcc-to-hcp phase transformation has long been anticipated. Here, we report an in situ loading study with neutron diffraction, which revealed a bulk fcc-to-hcp phase transformation in CrCoNi at 15 K under tensile loading. By correlating deformation characteristics of the fcc phase with the development of the hcp phase, it is shown that the nucleation of the hcp phase was triggered by intrinsic stacking faults. The confirmation of a bulk phase transformation adds to the myriads of deformation mechanisms available in CrCoNi, which together underpin the unusually large ductility at low temperatures.

論文

Strong local moment antiferromagnetic spin fluctuations in V-doped LiFeAs

Xu, Z.*; Dai, G.*; Li, Y.*; Yin, Z.*; Rong, Y.*; Tian, L.*; Liu, P.*; Wang, H.*; Xing, L.*; Wei, Y.*; et al.

npj Quantum Materials (Internet), 5(1), p.11_1 - 11_7, 2020/02

 被引用回数:4 パーセンタイル:40.81(Materials Science, Multidisciplinary)

We use neutron scattering to study Vanadium (hole)-doped LiFe$$_{1-x}$$V$$_{x}$$As. In the undoped state, LiFeAs exhibits superconductivity at $$T_mathrm{c} = 18$$ K and transverse incommensurate spin excitations similar to electron overdoped iron pnictides. Upon Vanadium doping to form LiFe$$_{0.955}$$V$$_{0.045}$$, the transverse incommensurate spin excitations in LiFeAs transform into longitudinally elongated ones in a similar fashion to that of potassium (hole)-doped Ba$$_{0.7}$$K$$_{0.3}$$Fe$$_{2}$$As$$_{2}$$ but with dramatically enhanced magnetic scattering and elimination of superconductivity. This is different from the suppression of the overall magnetic excitations in hole-doped BaFe$$_{2}$$As$$_{2}$$ and the enhancement of superconductivity near optimal hole doping. These results are consistent with density function theory plus dynamic mean field theory calculations, suggesting that Vanadium doping in LiFeAs may induce an enlarged effective magnetic moment $$S_mathrm{eff}$$ with a spin crossover ground state arising from the inter-orbital scattering of itinerant electrons.

論文

Coexistence of ferromagnetic and stripe-type antiferromagnetic spin fluctuations in YFe$$_{2}$$Ge$$_{2}$$

Wo, H.*; Wang, Q.*; Shen, Y.*; Zhang, X.*; Hao, Y.*; Feng, Y.*; Shen, S.*; He, Z.*; Pan, B.*; Wang, W.*; et al.

Physical Review Letters, 122(21), p.217003_1 - 217003_5, 2019/05

 被引用回数:5 パーセンタイル:42.69(Physics, Multidisciplinary)

We report neutron scattering measurements of single-crystalline YFe$$_{2}$$Ge$$_{2}$$ in the normal state, which has the same crystal structure as the 122 family of iron pnictide superconductors. YFe$$_{2}$$Ge$$_{2}$$ does not exhibit long-range magnetic order but exhibits strong spin fluctuations. Like the iron pnictides, YFe$$_{2}$$Ge$$_{2}$$ displays anisotropic stripe-type antiferromagnetic spin fluctuations at ($$pi, 0, pi$$). More interesting, however, is the observation of strong spin fluctuations at the in-plane ferromagnetic wave vector ($$0, 0, pi$$). These ferromagnetic spin fluctuations are isotropic in the ($$H, K$$) plane, whose intensity exceeds that of stripe spin fluctuations. Both the ferromagnetic and stripe spin fluctuations remain gapless down to the lowest measured energies. Our results naturally explain the absence of magnetic order in YFe$$_{2}$$Ge$$_{2}$$ and also imply that the ferromagnetic correlations may be a key ingredient for iron-based materials.

論文

Observation of $$e^+e^-topi^+pi^-pi^0chi_{b1,2}(1P)$$ and search for $$e^+e^-tophichi_{b1,2}(1P)$$ at $$sqrt{s}$$ = 10.96 - 11.05 GeV

Yin, J. H.*; 谷田 聖; Belle Collaboration*; 他189名*

Physical Review D, 98(9), p.091102_1 - 091102_9, 2018/11

AA2018-0718.pdf:0.5MB

 被引用回数:4 パーセンタイル:23.83(Astronomy & Astrophysics)

We report searches for the processes $$e^+e^-topi^+pi^-pi^0chi_{bJ}$$ and $$e^+e^-tophichi_{bJ}$$ (J=1,2) in the vicinity of the $$Upsilon(11020)$$ resonance using energy scan data collected by the Belle experiment at the KEKB collider. We observe $$e^+e^-to pi^+pi^-pi^0chi_{b1}$$ and find evidence for $$e^+e^-to omegachi_{b2}$$ processes for data with center-of-mass energies from 10.96 to 11.05~GeV for the first time. The statistical significance for $$pi^+pi^-pi^0chi_{b1}$$ and $$omegachi_{b2}$$ are $$6.1sigma$$ and $$4.0sigma$$, respectively. We investigate energy dependence of the $$e^+e^-topi^+pi^-pi^0chi_{bJ}$$ cross section and find that it is consistent with production of $$Upsilon(10860)$$ and $$Upsilon(11020)$$ resonances without significant non-resonant contribution. Assuming $$e^+e^-to pi^+pi^-pi^0chi_{bJ}$$ proceeds via $$Upsilon(10860)$$ and $$Upsilon(11020)$$, the branching fraction $$mathcal{B}(Upsilon(11020)topi^+pi^-pi^0chi_{bJ})=(8.6pm4.1pm6.1^{+4.5}_{-2.5})times10^{-3}$$ is measured for the first time, where the first error is statistical, the second is systematic, and the third from the branching fraction of $$Upsilon(11020)to e^+e^-$$. The signals for $$e^+e^-to phichi_{bJ}$$ are not significant, and the upper limits of the Born cross sections at the 90% confidence level are $$0.6$$ and $$1.0$$~pb for $$e^+e^-to phichi_{b1}$$ and $$phichi_{b2}$$, respectively, for center-of-mass energies from 10.96 to 11.05 GeV.

論文

Faradaically selective membrane for liquid metal displacement batteries

Yin, H.*; Chung, B.*; Chen, F.*; 大内 隆成*; Zhao, J.*; 田中 伸幸; Sadoway, D. R.*

Nature Energy (Internet), 3(2), p.127 - 131, 2018/02

 被引用回数:55 パーセンタイル:87.54(Energy & Fuels)

リチウムイオン選択性を有する多孔質伝導膜を用い、正極と負極の電極金属を分離することで、性能劣化が小さく、高い充放電効率が得られるこれまでにない概念の溶融塩蓄電池の開発を行った。多孔質伝導膜にセラミックスの窒化チタン焼結体を、正・負極材に、それぞれ鉛及びリチウム鉛を使用した蓄電池を作製し、作動温度410$$^{circ}$$Cにおける100サイクル試験を行った。初期の100サイクル平均の性能で、充放電効率が90%以上と優れた性能を達成するとともに、その間の充放電効率の低下速度は1サイクル当たり0.0017%が得られた。これは10年経過後も充放電効率の劣化は10%以下と高寿命であることを示している。また、多孔質状金属(ステンレス及びチタン)に窒化チタンをコーティングした多孔質伝導膜を使用した場合においても、同様の充放電効率を示すことを明らかにした。このように本開発で導入した金属を基盤とする多孔質伝導膜は、低電気抵抗が可能な薄膜化かつ工業的スケールアップに向けた大型化が期待できるものである。

論文

Uniaxial pressure effect on the magnetic ordered moment and transition temperatures in BaFe$$_{2-x}$$T$$_{x}$$As$$_{2}$$ ($$T$$ = Co,Ni)

Tam, D. M.*; Song, Y.*; Man, H.*; Cheung, S. C.*; Yin, Z.*; Lu, X.*; Wang, W.*; Frandsen, B. A.*; Liu, L.*; Gong, Z.*; et al.

Physical Review B, 95(6), p.060505_1 - 060505_6, 2017/02

 被引用回数:23 パーセンタイル:71.49(Materials Science, Multidisciplinary)

We use neutron diffraction and muon spin relaxation to study the effect of in-plane uniaxial pressure on the antiferromagnetic (AF) orthorhombic phase in BaFe$$_{2-x}$$T$$_{x}$$As$$_{2}$$ and its Co- and Ni-substituted members near optimal superconductivity. In the low-temperature AF ordered state, uniaxial pressure necessary to detwin the orthorhombic crystals also increases the magnetic ordered moment, reaching an 11% increase under 40 MPa for BaFe$$_{1.9}$$Co$$_{0.1}$$As$$_2$$, and a 15% increase for BaFe$$_{1.915}$$Ni$$_{0.085}$$As$$_2$$. We also observe an increase of the AF ordering temperature ($$T_N$$) of about 0.25 K/MPa in all compounds, consistent with density functional theory calculations that reveal better Fermi surface nesting for itinerant electrons under uniaxial pressure. The doping dependence of the magnetic ordered moment is captured by combining dynamical mean field theory with density functional theory, suggesting that the pressure-induced moment increase near optimal superconductivity is closely related to quantum fluctuations and the nearby electronic nematic phase.

論文

Spin excitations in optimally P-doped BaFe$$_2$$(As$$_{0.7}$$P$$_{0.3}$$)$$_2$$ superconductor

Hu, D.*; Yin, Z.*; Zhang, W.*; Ewings, R. A.*; 池内 和彦*; 中村 充孝; Roessli, B.*; Wei, Y.*; Zhao, L.*; Chen, G.*; et al.

Physical Review B, 94(9), p.094504_1 - 094504_7, 2016/09

AA2016-0252.pdf:2.18MB

 被引用回数:16 パーセンタイル:59.36(Materials Science, Multidisciplinary)

最適Pドープされた超伝導体BaFe$$_2$$(As$$_{0.7}$$P$$_{0.3}$$)$$_2$$ (T$$_c$$=30K)におけるスピン励起の温度及びエネルギー依存性が非弾性中性子散乱実験を使って調べられた。我々の実験結果は密度汎関数理論や動的平均場理論で予想される計算結果と矛盾しておらず、BaFe$$_2$$(As$$_{0.7}$$P$$_{0.3}$$)$$_2$$における平均プニクトゲン高さの減少が、電子相関の強さを弱め、磁気励起の有効バンド幅の増加に寄与することを示唆している。

論文

From laboratory to field; ${it OsNRAMP5}$-knockdown rice is a promising candidate for Cd phytoremediation in paddy fields

高橋 竜一*; 石丸 泰寛*; Shimo, H.*; Bashir, K.*; 瀬野浦 武志*; 杉本 和彦*; 小野 和子*; 鈴井 伸郎; 河地 有木; 石井 里美; et al.

PLOS ONE (Internet), 9(6), p.e98816_1 - e98816_7, 2014/06

 被引用回数:51 パーセンタイル:86.7(Multidisciplinary Sciences)

Previously, we reported that OsNRAMP5 functions as a manganese, iron, and cadmium (Cd) transporter. The shoot Cd content in ${it OsNRAMP5}$ RNAi plants was higher than that in wild-type (WT) plants, whereas the total Cd content (roots plus shoots) was lower. For efficient Cd phytoremediation, we produced ${it OsNRAMP5}$ RNAi plants using the natural high Cd-accumulating cultivar Anjana Dhan (A5i). Using a positron-emitting tracer imaging system, we assessed the time-course of Cd absorption and accumulation in A5i plants. Enhanced $$^{107}$$Cd translocation from the roots to the shoots was observed in A5i plants. To evaluate the phytoremediation capability of A5i plants, we performed a field experiment in a Cd-contaminated paddy field. The biomass of the A5i plants was unchanged by the suppression of ${it OsNRAMP5}$ expression; the A5i plants accumulated twice as much Cd in their shoots as WT plants. Thus, A5i plants could be used for rapid Cd extraction and the efficient phytoremediation of Cd from paddy fields, leading to safer food production.

論文

Implications of NbTi short-sample test results and analysis for the ITER Poloidal Field Conductor Insert (PFCI)

Zanino, R.*; Bagnasco, M.*; Baker, W.*; Bellina, F.*; Bruzzone, P.*; della Corte, A.*; Ilyin, Y.*; Martovetsky, N.*; Mitchell, N.*; Muzzi, L.*; et al.

IEEE Transactions on Applied Superconductivity, 16(2), p.886 - 889, 2006/06

 被引用回数:7 パーセンタイル:40.69(Engineering, Electrical & Electronic)

那珂核融合研究所においてITERポロイダル磁場コイル導体インサート(PFCI)の実験が予定されている。このため、PFCIの適切な実験プログラムを作成することを目的として、NbTi短尺導体サンプル実験から得られた結果の解析を行った。特に、次の項目について検討を行った;(1)巻線内の導体ジョイントがクエンチする前に導体自身の分流開始温度Tcsを測定できる可能性に関する検討。(2)解析コードMithrandirを用いて短尺導体サンプルの実験結果を解析し、いわゆる突然の又は早期のクエンチの可能性に関する検討。(3)PFCI実験における熱量法によるACロス測定の可能性。検討の結果、Tcs及びACロスの測定は可能であることがわかった。しかし、突然のクエンチについては今後のこれらの検討が必要である。

口頭

Combination of $$^{13}$$N and $$^{15}$$N isotope methods for the estimation of fixation and early distribution of nitrogen in soybean

石井 里美; Nguyen Van Phi, H.*; 鈴井 伸郎; 河地 有木; 尹 永根; 大山 卓爾*; 藤巻 秀

no journal, , 

Various methods are used in the field of biological nitrogen fixation. In this study, we analyzed early dynamics of nitrogen fixation and subsequent transport in soybean by using radioactive and stable isotopes, $$^{13}$$N and $$^{15}$$N. $$^{13}$$N has an advantage for the analysis of kinetics and visualization, while $$^{15}$$N is beneficial for the analysis of distribution. $$^{13}$$N is the only practical radioisotope of nitrogen which has a very short half-life of only 9.97 min. In this study, we improved a rapid method to produce $$^{13}$$N$$_{2}$$ with higher radioactivity and sufficient purity. We fed the tracer gas to the underground part of soybean plants for 10 min and collected the serial images for one hour by PETIS. As a result, we finally obtained the image of transport to the aerial part successfully. The stable isotope $$^{15}$$N has been widely used for the analysis of fixation and export. In this study, we fed $$^{15}$$N$$_{2}$$ to the underground part of soybean plants for one hour and analyzed the time course of the distribution in the whole body. As a result, we found that about 10% of fixed nitrogen was exported from the root nodules in the initial one hour. From a methodological aspect, we concluded that the combination of $$^{13}$$N and $$^{15}$$N isotope is a strong tool for quantitative analysis of fixation and transport of nitrogen.

口頭

窒素固定イメージングを目指した新規$$^{13}$$N標識窒素ガス製造法の開発

石井 里美; 井倉 将人*; 鈴井 伸郎; 尹 永根; 河地 有木; 小柳 淳*; Nguyen Van Phi, H.*; 大山 卓爾*; 藤巻 秀

no journal, , 

植物にとって、窒素は最も重要な養分である。窒素栄養を効率よく獲得するために、ダイズ等のマメ科植物は根に根粒を形成し、根粒菌と共生することで、大気中の窒素を固定する機能を持つ。われわれはダイズの窒素栄養の獲得機構を解明することを目的として、$$^{13}$$N標識窒素ガス($$^{13}$$N$$_{2}$$ガス)を精製し、ポジトロンイメージング技術を用いて、根粒が窒素を固定する様子を可視化することに成功している。しかしながら、固定された窒素化合物がダイズの葉や実へ移動する様子は観察できていない。移動を観察するためには、100MBq以上の$$^{13}$$N$$_{2}$$ガスが必要であると考えられるが、これまでの精製方法では十分量の回収が困難であった。そこで本研究では、高純度の$$^{13}$$N$$_{2}$$ガスを100MBq以上の収量で回収し、窒素栄養動態のイメージングを可能にする、新しい製造方法を開発することを目的とした。新しい精製方法により約100MBqの$$^{13}$$N$$_{2}$$ガスを含むトレーサガスを25mLで回収することができた。また、ガスクロマトグラフィーの分析結果には、$$^{13}$$N$$_{2}$$Oのピークは認められなかった。すなわち本精製方法により$$^{13}$$N$$_{2}$$Oが$$^{13}$$N$$_{2}$$に完全に還元されていることがわかった。また、ダイズ植物の根に投与し、ポジトロンイメージングを行った結果、根粒及び茎にシグナルが認められ、窒素固定及び固定された窒素化合物の移行を観察することができた。

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  • 1