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Journal Articles

Evaluation of indoor air dose rate based on Cs-137 depth distribution in surrounding artificially paved surfaces surveyed 10 years after the Fukushima Daiichi Nuclear Power Plant accident

Kobayashi, Hikaru*; Suto, Masahito*; Otsuki, Kentaro*; Yoshimura, Kazuya; Yoshida, Hiroko*

Japan Architectural Review (Internet), 6(1), p.e12353_1 - e12353_12, 2023/00

Journal Articles

Oxidation of anatase TiO$$_{2}$$(001) surface using supersonic seeded oxygen molecular beam

Katsube, Daiki*; Ono, Shinya*; Takayanagi, Shuhei*; Ojima, Shoki*; Maeda, Motoyasu*; Origuchi, Naoki*; Ogawa, Arata*; Ikeda, Natsuki*; Aoyagi, Yoshihide*; Kabutoya, Yuito*; et al.

Langmuir, 37(42), p.12313 - 12317, 2021/10

 Times Cited Count:1 Percentile:6.77(Chemistry, Multidisciplinary)

We investigated the oxidation of oxygen vacancies at the surface of anatase TiO$$_{2}$$(001) using supersonic seeded molecular beam (SSMB) of oxygen. The oxygen vacancies at the top-surface and sub-surface could be eliminated by the supply of oxygen using an SSMB. These results indicate that the interstitial vacancies can be mostly assigned to oxygen vacancies, which can be effectively eliminated by using an oxygen SSMB. Oxygen vacancies are present on the surface of anatase TiO$$_{2}$$(001) when it is untreated before transfer to a vacuum chamber. These vacancies, which are stable in the as-grown condition, could also be effectively eliminated using the oxygen SSMB.

Journal Articles

Thermally altered subsurface material of asteroid (162173) Ryugu

Kitazato, Kohei*; Milliken, R. E.*; Iwata, Takahiro*; Abe, Masanao*; Otake, Makiko*; Matsuura, Shuji*; Takagi, Yasuhiko*; Nakamura, Tomoki*; Hiroi, Takahiro*; Matsuoka, Moe*; et al.

Nature Astronomy (Internet), 5(3), p.246 - 250, 2021/03

 Times Cited Count:43 Percentile:96.93(Astronomy & Astrophysics)

Here we report observations of Ryugu's subsurface material by the Near-Infrared Spectrometer (NIRS3) on the Hayabusa2 spacecraft. Reflectance spectra of excavated material exhibit a hydroxyl (OH) absorption feature that is slightly stronger and peak-shifted compared with that observed for the surface, indicating that space weathering and/or radiative heating have caused subtle spectral changes in the uppermost surface. However, the strength and shape of the OH feature still suggests that the subsurface material experienced heating above 300 $$^{circ}$$C, similar to the surface. In contrast, thermophysical modeling indicates that radiative heating does not increase the temperature above 200 $$^{circ}$$C at the estimated excavation depth of 1 m, even if the semimajor axis is reduced to 0.344 au. This supports the hypothesis that primary thermal alteration occurred due to radiogenic and/or impact heating on Ryugu's parent body.

Journal Articles

STM-induced SiO$$_{2}$$ decomposition on Si(110)

Yano, Masahiro; Uozumi, Yuki*; Yasuda, Satoshi; Asaoka, Hidehito; Tsukada, Chie*; Yoshida, Hikaru*; Yoshigoe, Akitaka

e-Journal of Surface Science and Nanotechnology (Internet), 16, p.370 - 374, 2018/08

Journal Articles

Characterization of SiO$$_{2}$$ reduction reaction region at void periphery on Si(110)

Yano, Masahiro; Uozumi, Yuki*; Yasuda, Satoshi; Tsukada, Chie*; Yoshida, Hikaru*; Yoshigoe, Akitaka; Asaoka, Hidehito

Japanese Journal of Applied Physics, 57(8S1), p.08NB13_1 - 08NB13_4, 2018/07

 Times Cited Count:2 Percentile:9.42(Physics, Applied)

Oral presentation

Quest for microorganisms existing at high atmosphere and space

Yokobori, Shinichi*; Yang, Y.*; Sugino, Tomohiro*; Kawaguchi, Yuko*; Itahashi, Shiho*; Fujisaki, Kenta*; Fushimi, Hidehiko*; Hasegawa, Sunao*; Hashimoto, Hirofumi*; Hayashi, Nobuhiro*; et al.

no journal, , 

Oral presentation

Alteration of organic compounds of interstellar origin in the solar system; Simulation experiments on the ground and in space

Kobayashi, Kensei*; Kawamoto, Yukinori*; Sarker, P. K.*; Ono, Keisuke*; Kuwahara, Hideharu*; Obayashi, Yumiko*; Kaneko, Takeo*; Mita, Hajime*; Yabuta, Hikaru*; Yoshida, Satoshi*; et al.

no journal, , 

Oral presentation

Alteration of amino acid precursors in the solar system; Simulation experiments on the ground and in space

Kobayashi, Kensei*; Kawamoto, Yukinori*; Sarker, P. K.*; Kuwahara, Hideharu*; Obayashi, Yumiko*; Kaneko, Takeo*; Mita, Hajime*; Yabuta, Hikaru*; Yoshida, Satoshi*; Narumi, Issei; et al.

no journal, , 

no abstracts in English

Oral presentation

Tanpopo project; Survival of microbes in outer space

Yokobori, Shinichi*; Kawaguchi, Yuko*; Yang, Y.*; Kawashiri, Narutoshi*; Shiraishi, Keisuke*; Shimizu, Yasuyuki*; Takahashi, Yuta*; Sugino, Tomohiro*; Narumi, Issei; Sato, Katsuya; et al.

no journal, , 

no abstracts in English

Oral presentation

Current status of preparation of TANPOPO mission (astrobiology exposure and micrometeoroid capture experiments) and investigation of survivability of microbes in space

Yokobori, Shinichi*; Kawaguchi, Yuko*; Yang, Y.*; Kawashiri, Narutoshi*; Shiraishi, Keisuke*; Shimizu, Yasuyuki*; Takahashi, Yuta*; Sugino, Tomohiro*; Narumi, Issei; Sato, Katsuya; et al.

no journal, , 

no abstracts in English

Oral presentation

Current status of preparation of TANPOPO mission (astrobiology exposure and micrometeoroid capture experiments) and investigation of survivability of microbes in space

Yokobori, Shinichi*; Kawaguchi, Yuko*; Shimizu, Yasuyuki*; Kawashiri, Narutoshi*; Shiraishi, Keisuke*; Sugino, Tomohiro*; Takahashi, Yuta*; Yang, Y.*; Tanigawa, Yoshiaki*; Hashimoto, Hirofumi*; et al.

no journal, , 

no abstracts in English

Oral presentation

Experiments on microbes in TANPOPO mission on the International Space Station

Yokobori, Shinichi*; Kawaguchi, Yuko*; Harada, Miyu*; Murano, Yuka*; Tomita, Kaori*; Hayashi, Nobuhiro*; Tabata, Makoto*; Kawai, Hideyuki*; Okudaira, Kyoko*; Imai, Eiichi*; et al.

no journal, , 

no abstracts in English

Oral presentation

Study on adsorption reaction of CH$$_{3}$$Cl on Si(100)2$$times$$1 by means of SR-XPS

Tsukada, Chie; Yoshida, Hikaru; Okada, Michio*; Yoshigoe, Akitaka; Yaita, Tsuyoshi

no journal, , 

Cs in clay mineral will be easy to desorb as halide. We should investigate the desorption mechanism. The clay mineral is constructed mainly by oxide with Si and Al. Thus, Si substrate and CH$$^{3}$$Cl are selected as the reaction model materials. The final purpose is to reveal the reaction for CH$$^{3}$$Cl molecular beam on Cs/Si substrate by means of XPS with synchrotron radiation (SR-XPS). As the first step, the purpose in this study is to reveal the adsorption reaction for CH$$^{3}$$Cl molecular beam on Si(100)2$$times$$1 by means of SR-XPS. The CH$$^{3}$$Cl will adsorb at CH$$^{3}$$ and/or Cl group on the Si dimer atom, respectively.

Oral presentation

Application attempt for Cs adsorbent of the Au nanoparticle fabricated by solution plasma method

Tsukada, Chie; Yoshida, Hikaru; Ogawa, Satoshi*; Yoshigoe, Akitaka; Yagi, Shinya*; Yaita, Tsuyoshi

no journal, , 

We focus on the Au nanoparticle, which is fabricated by solution plasma method, as the adsorbent with high density and high efficiency of Cs$$^{+}$$ in solution. To remove the Cs from the solution, we attempt two methods, which are the Cs adsorption on the Au nanoparticle surface and the interaction between the Cs and the L-cysteine on Au nanoparticle. Judging from the results of SR-XPS for the sample at the latter method, we suggest the interaction between the Cs and the COOH group of L-cysteine on Au nanoparticle.

Oral presentation

Study on influence of radioactive contamination derived from nuclear power plant accident on building space, 2; Study on measurement method of direction radiation dose rate intended for field survey

Yamamori, Ryo*; Kobayashi, Hikaru*; Honta, Shohei*; Yoshino, Hiroshi*; Nozaki, Atsuo*; Ichijo, Yusuke*; Yoshida, Hiroko*; Furuta, Takuya

no journal, , 

Understanding radiation field is important to predict radiation dose rate in newly constructing buildings in an area widely contaminated by radioactive nuclei. Radiation dose rate at the site is not sufficient, and directional spectra of the radiations are important to consider the shielding effect of the building. Radiation directional spectra can be measured by scintillator partially shielded by lead collimators but the angle of view highly depends on the combination of the scintillator and the collimators. We adopts a method to measure the directional spectra by adopting 3 inch scintillator with placing a plate of lead collimator in front of the scintillator and subtract the values from the spectra measured without lead collimator. We simulates the optimal size of the lead collimator and found that the 15 cm diameter plate placing at 3 cm from the scintillator is the best for our purpose, 90 degree angle of view.

Oral presentation

Study on adsorption reaction of CH$$_{3}$$Cl on Si(100)2$$times$$1 by means of SR-XPS

Tsukada, Chie; Yoshida, Hikaru; Okada, Michio*; Yoshigoe, Akitaka; Yaita, Tsuyoshi

no journal, , 

To achieve Cs decontamination in clay minerals by using CH$$_{3}$$Cl gas, we have investigated the adsorption reactions and adsorption states of CH$$_{3}$$Cl at Si surfaces. In this conference, we report that dissociative adsorption of CH$$_{3}$$Cl to form CH$$_{3}$$ and Cl was revealed from the high energy-resolutions photoemission spectra.

Oral presentation

Initial oxidation of copper alloy surfaces with a hyperthermal oxygen molecular beam

Tsuda, Yasutaka*; Makino, Takamasa*; Yoshida, Hikaru; Yoshigoe, Akitaka; Fukuyama, Tetsuya*; Okada, Michio*

no journal, , 

Initial stage of corrosion is one of the central topics in material science. In the present study, we report the results of oxidation on Cu$$_{3}$$Pd(111) and Cu$$_{3}$$Pt(111) with a hyperthermal O$$_{2}$$ molecular beam (HOMB) with variable incident energies, using X-ray photoemission spectroscopy in conjunction with synchrotron radiation. All experiments were performed using the Surface Reaction Analysis Apparatus constructed in BL23SU at SPring-8. The Cu$$_{3}$$Pd(111) and Cu$$_{3}$$Pt(111) samples were cleaned by Ar+ sputtering and annealing. The kinetic energy of the HOMB was set to be 2.3 eV. From the uptake curves, it was found that the oxidation of Cu$$_{3}$$Pt is less effective than that on Cu$$_{3}$$Au and Cu$$_{3}$$Pd. This suppression of the surface reactivity may be caused by the Pt-rich subsurface layer.

Oral presentation

XPS analysis for Cs adsorbed on L-cysteine/Au nanoparticle

Tsukada, Chie*; Yoshida, Hikaru; Ogawa, Satoshi*; Yoshigoe, Akitaka; Yagi, Shinya*; Yaita, Tsuyoshi

no journal, , 

The decontamination of radioactive Cs from the soil and the water has been required in Fukushima. Gold nanoparticles (AuNPs) are attractive candidate for Cs adsorbent. AuNPs fabricated by solution plasma method is not covered by dispersant and is almost clean. It is known that L-cysteine rapidly adsorbs and exists with high density on the AuNPs surface. The electrostatic attractive force may be useful to induce interactions between -COO- of L-cysteine and Cs$$^{+}$$ ion in aqueous solution. This study reveals the adsorption reaction between the Cs and the Cys/AuNP. Cys/AuNP has a peak and CsCl/Cys/AuNP has no peak in Na 1s spectra. Cys/AuNP has no peak and CsCl/Cys/AuNP has a peak for Cs 3$$d_{5/2}$$ spectra. From these results, Na$$^{+}$$ on Cys/AuNP is replaced by Cs$$^{+}$$ after reaction in CsCl aqueous solution. Cys/AuNP and CsCl/Cys/AuNP have a O 1s peak, where the peak position of CsCl/Cys/AuNP is higher than that ofCys/AuNP. This indicates the further polarization of -COO- by replacing Na$$^{+}$$ by Cs$$^{+}$$.

Oral presentation

Development of $$gamma$$-ray directional radiation dose detector with good efficiency for field survey

Yamamori, Ryo*; Kobayashi, Hikaru*; Honta, Shohei*; Yoshino, Hiroshi*; Nozaki, Atsuo*; Ichijo, Yusuke*; Hijikata, Yoshio*; Yoshida, Hiroko*; Furuta, Takuya

no journal, , 

Understanding radiation field is important to predict radiation dose rate in newly constructing buildings in an area widely contaminated by radioactive nuclei. Directional spectra of the radiations are important to consider the shielding effect of the building. We adopts a method to measure the directional spectra by adopting a plate of lead collimator in front of the scintillator and subtract the values from the spectra measured without lead collimator. We investigated a possible weight saving detection system having sufficient detection efficiency. The investigation was carried out for the condition of the collimator radius ($$phi$$ = 10, 15, 20 cm) and the distance between collimator and detector ($$ell$$ = 1, 3, 5 cm). We found that three combinations satisfied the 90$$^{circ}$$ field view and the detection efficiency became better with larger collimator radius. On the other hand, larger collimator radius indicate heavier detection system. Therefore, we developed an optimum detection system for field survey with the 15 cm diameter plate (10kg), the scintillator (3.4kg), and the folder (1.0kg).

Oral presentation

Automatic pressure control toward UHV surface process researches

Ajikawa, Yusuke*; Yamamoto, Yukio*; Yoshida, Hikaru; Yoshigoe, Akitaka

no journal, , 

A very small amount of gas control was indispensable for surface reaction experiments under ultrahigh vacuum conditions. Normally, it has been performed with a variable leak valve by the manual operation. However, the manual operation can not apply for advanced experiments such as multi-measurements. The automatic precise valve control would lead to the burden reduction and reproducible improvement. The antomatic control also has a metrit to avid the loss of control for the apparatus. In this conference, we will report recent developments of the automatic pressure control system and some results of precise pressure control from 10$$^{-8}$$ to 10$$^{-4}$$ Pa.

24 (Records 1-20 displayed on this page)