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Yokokita, Takuya*; Komori, Yukiko*; Kikutani, Yuki*; Kino, Aiko*; Shiohara, Naoya*; Kasamatsu, Yoshitaka*; Yoshimura, Takashi*; Takahashi, Naruto*; Oe, Kazuhiro; Shinohara, Atsushi*
no journal, ,
We are planning to study a redox behavior of element 106, seaborgium (Sg) based on the comparison of the behaviors with those of molybdenum (Mo) and tungsten (W). In this work, we studied solvent extraction behaviors of Mo(VI), Mo(V), W(VI), and W(V) with Aliquat 336 from hydrochloric acid (HCl). Mo(V) is extracted with higher distribution ratios than those of Mo(VI) in 4 to 11 M HCl. Distribution ratios of Mo(V) obtained by reducing Mo(VI) electrochemically are in good agreement with those of [MoCl
].
Yokokita, Takuya*; Oe, Kazuhiro; Komori, Yukiko*; Kikutani, Yuki*; Kino, Aiko*; Nakamura, Kohei*; Kasamatsu, Yoshitaka*; Takahashi, Naruto*; Yoshimura, Takashi*; Takamiya, Koichi*; et al.
no journal, ,
We carried out solvent extraction of Mo(VI), Mo(V), W(VI) and W(V) in 0.01-0.36 M Aliquat 336 / 0.1-11 M HCl system as model experiments for element 106, seaborgium (Sg). The HCl solutions of Mo(VI), Mo(V), W(VI) and W(V) were prepared using macro amounts of Mo and W. Extraction behaviors of mononuclear Mo and W were also investigated using carrier-free radiotracers 
Mo and 
W, which were produced as 
U(n, f) and Ta (p, n) reaction, respectively. The distribution ratios (D) of Mo(V) and W(V) were higher than those of Mo(VI) and W(VI), respectively. These results suggest that reduction behavior of the group-6 elements can be observed by solvent extraction. The D values of carrier-free Mo(VI) and W(VI) are almost the same as those with macro amounts in 6-11 M HCl. This condition would be suitable for the Sg experiments.
Usui, Yoshiya*; Ueshima, Makoto*; Hase, Hideaki*; Ichihara, Hiroshi*; Aizawa, Koki*; Koyama, Takao*; Sakanaka, Shinya*; Ogawa, Tsutomu*; Yamaya, Yusuke*; Nishitani, Tadashi*; et al.
no journal, ,
In the back-arc area of the southern Tohoku region, there are several quaternary volcanos and active faults that have the potential to cause M7-class inland earthquakes. In the vicinity of some of the volcanoes, deep low-frequency earthquakes occur, implying the transfer of melt or aqueous fluid. So as to reveal the magma supply system around the area, it is important to reveal the distribution of the subsurface fluid. Also, understanding the fluid distribution helps elucidate the earthquake generation process. To delineate the subsurface electrical resistivity structure, the authors estimated the resistivity structure in the area by performing magnetotelluric surveys and generating the 3-D resistivity structure model with high resolution. In this study, the authors show the resultant electrical resistivity structure and discuss the subsurface fluid distribution as well as its relationship with the volcanic and seismic activities around the study area.
Yoshimura, Koki*; Fujii, Shun*; Morito, Makoto*; Sato, Tasuku*; Tahara, Junichiro*; Baba, Shoichiro*; Sanada, Yukihisa
no journal, ,
no abstracts in English
Matsunaga, Keita*; Aizawa, Koki*; Ogawa, Hiroki; Utsugi, Mitsuru*; Yoshimura, Ryokei*; Yamazaki, Kenichi*; Uchida, Kazunari*
no journal, ,
no abstracts in English