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Jing, Z.*; Yamaguchi, Toshio*; Hattori, Takanori; Yamada, Takeshi*; Tamatsukuri, Hiromu; Matsuura, Masato*; Zhou, Y.*
Journal of Physical Chemistry Letters (Internet), 17(29), p.8419 - 8428, 2026/07
Times Cited Count:0 Percentile:0.00(Chemistry, Physical)We conducted high-pressure neutron diffraction and quasielastic neutron scattering on a series of aqueous alkaline chloride solutions and clarified that the pressure- and ion-induced modifications to the water structure and diffusion originate from distinct physical mechanisms. Applying gigapascal pressure transforms the tetrahedral hydrogen-bonded network structure of water into a dense random packing, due to the collapse of the second and third coordination shells and an increase in the number of interstitial water molecules, regardless of the ion species. On the contrary, dissolved ions disturb the second shell but preserve the inherent tetrahedral network structure of water at ambient pressure. The anomalous trend of water diffusion from Li
to Cs
under the ambient conditions disappears under the gigapascal pressure, and all the ions show a behavior of structure-making ions.
telier effect in an Al-Mg-Zn-based crossover aluminum alloyZhang, X.*; Li, Y.*; Wei, S.*; Guo, H.*; He, Z.*; Yang, C.*; Gong, W.; Harjo, S.; Zhou, D.*; Li, Z.*; et al.
Acta Materialia, 308, p.121990_1 - 121990_18, 2026/04
Times Cited Count:8 Percentile:99.16(Materials Science, Multidisciplinary)Jing, Z.*; Yamaguchi, Toshio*; Machida, Shinichi*; Hattori, Takanori; Zhou, Y.*
Journal of Chemical Physics, 163(19), p.194505_1 - 194505_12, 2025/11
Times Cited Count:0 Percentile:0.00(Chemistry, Physical)Ion solvation in a range of gigapascal pressure is of great significance for high-pressure chemical synthesis and the circulation of matter within the Earth's interior. We perform neutron scattering (NS) experiments and molecular dynamics simulations of deuterated aqueous solutions of MCl (M = Li, Na, K, Rb, and Cs) at 0.1 MPa and 0.7 GPa/298 K. An empirical potential structure refinement method analyzes the NS data. Upon compression to 0.7 GPa, the outer-shell water molecules enter the nearest neighbor of ions, and the solvated ion clusters become denser. The hydration factor
and static hydration number
based on the orientation distribution of the water dipole in the first solvation shell, show that the compression weakens the hydration ability of the ions. Compression suppresses the diffusion of ions, particularly of the structure-breaking ions. The ionic diffusion coefficient
residence time of water molecules
and dynamic hydration number
indicate that Rb
and Cs
exhibit characteristics of structure-making ions under compression. The dynamic properties are more pressure-sensitive than the static structure.
Cho, S. H.*; Cho, S. W.*; Lv, Z.*; Sekine, Yurina; Liu, S.*; Zhou, M.*; Nuxoll, R. F.*; Kanatzidis, E. E.*; Ghaffari, R.*; Kim, D.*; et al.
Lab on a Chip, 25(7), p.1647 - 1655, 2025/04
Times Cited Count:16 Percentile:98.63(Biochemical Research Methods)Amino acids are essential for protein synthesis and metabolic processes in support of homeostatic balance and healthy body functions. This study quantitatively investigates eccrine sweat as a significant channel for loss of amino acids during exercise, to improve an understanding of amino acid turnover and to provide feedback to users on the need for supplement intake. The measurement platform consists of a soft, skin-interfaced microfluidic system for real-time analysis of amino acid content in eccrine sweat. This system relies on integrated fluorometric assays and smartphone-based imaging techniques for quantitative analysis.
Hojo, Tomohiko*; Koyama, Motomichi*; Kumai, Bakuya*; Zhou, Y.*; Shibayama, Yuki; Shiro, Ayumi*; Shobu, Takahisa; Saito, Hiroyuki*; Ajita, Saya*; Akiyama, Eiji*
ISIJ International, 65(2), p.284 - 296, 2025/02
Times Cited Count:0 Percentile:0.00(Metallurgy & Metallurgical Engineering)Hu, F. F.*; Qin, T. Y.*; Ao, N.*; Su, Y. H.; Zhou, L.*; Xu, P. G.; Parker, J. D.*; Shinohara, Takenao; Chen, J.*; Wu, S. C.*
Engineering Fracture Mechanics, 306, p.110267_1 - 110267_18, 2024/08
Times Cited Count:5 Percentile:43.19(Mechanics)Qin, T. Y.*; Hu, F. F.*; Xu, P. G.; Zhang, H.*; Zhou, L.*; Ao, N.*; Su, Y. H.; Shobu, Takahisa; Wu, S. C.*
International Journal of Fatigue, 185, p.108336_1 - 108336_13, 2024/08
Times Cited Count:20 Percentile:89.57(Engineering, Mechanical)Zhou, L.*; Zhang, H.*; Qin, T. Y.*; Hu, F. F.*; Xu, P. G.; Ao, N.*; Su, Y. H.; He, L. H.*; Li, X. H.*; Zhang, J. R.*; et al.
Metallurgical and Materials Transactions A, 55(7), p.2175 - 2185, 2024/07
Times Cited Count:4 Percentile:36.86(Materials Science, Multidisciplinary)Zeng, Z.*; Zhou, C.*; Zhou, H.*; Han, L.*; Chi, R.*; Li, K.*; Kofu, Maiko; Nakajima, Kenji; Wei, Y.*; Zhang, W.*; et al.
Nature Physics, 20(7), p.1097 - 1102, 2024/07
Times Cited Count:33 Percentile:96.08(Physics, Multidisciplinary)
- and
-processes following
-process in the collapsar jetHe, Z.*; Kajino, Toshitaka*; Kusakabe, Motohiko*; Zhou, S.-G.*; Koura, Hiroyuki; Chiba, Satoshi*; Li, H.*; Lin, Y.*
Astrophysical Journal Letters, 966(2), p.L37_1 - L37_7, 2024/05
Times Cited Count:10 Percentile:67.35(Astronomy & Astrophysics)
neutron diffractionZhou, Y.*; Song, W.*; Zhang, F.*; Wu, Y.*; Lei, Z.*; Jiao, M.*; Zhang, X.*; Dong, J.*; Zhang, Y.*; Yang, M.*; et al.
Journal of Alloys and Compounds, 971, p.172635_1 - 172635_7, 2024/01
Times Cited Count:8 Percentile:42.29(Chemistry, Physical)Yang, D. S.*; Wu, Y.*; Kanatzidis, E. E.*; Avila, R.*; Zhou, M.*; Bai, Y.*; Chen, S.*; Sekine, Yurina; Kim, J.*; Deng, Y.*; et al.
Materials Horizons, 10(11), p.4992 - 5003, 2023/09
Times Cited Count:31 Percentile:86.80(Chemistry, Multidisciplinary)This paper presents a set of findings that enhances the performance of these systems through the use of microfluidic networks, integrated valves and microscale optical cuvettes formed by three-dimensional printing in hard/soft hybrid materials systems, for accurate spectroscopic and fluorometric assays. Field studies demonstrate the capability of these microcuvette systems to evaluate the concentrations of copper, chloride, and glucose in sweat, along with the sweat pH, with laboratory grade accuracy and sensitivity.
Fe
intermetallic compoundCao, Y.*; Zhou, H.*; Khmelevskyi, S.*; Lin, K.*; Avdeev, M.*; Wang, C.-W.*; Wang, B.*; Hu, F.*; Kato, Kenichi*; Hattori, Takanori; et al.
Chemistry of Materials, 35(8), p.3249 - 3255, 2023/04
Times Cited Count:9 Percentile:47.78(Chemistry, Physical)Hydrostatic and chemical pressure are efficient stimuli to alter the crystal structure and are commonly used for tuning electronic and magnetic properties in materials science. However, chemical pressure is difficult to quantify and a clear correspondence between these two types of pressure is still lacking. Here, we study intermetallic candidates for a permanent magnet with a negative thermal expansion (NTE). Based on in situ synchrotron X-ray diffraction, negative chemical pressure is revealed in Ho
Fe
on Al doping and quantitatively evaluated by using temperature and pressure dependence of unit cell volume. A combination of magnetization and neutron diffraction measurements also allowed one to compare the effect of chemical pressure on magnetic ordering with that of hydrostatic pressure. Intriguingly, pressure can be used to control suppression and enhancement of NTE. Electronic structure calculations indicate that pressure affected the top of the majority band with respect to the Fermi level, which has implications for the magnetic stability, which in turn plays a critical role in modulating magnetism and NTE. This work presents a good example of understanding the effect of pressure and utilizing it to control properties of functional materials.
Zhang, H.*; Wu, S. C.*; Ao, N.*; Zhang, J. W.*; Li, H.*; Zhou, L.*; Xu, P. G.; Su, Y. H.
International Journal of Fatigue, 166, p.107296_1 - 107296_11, 2023/01
Times Cited Count:33 Percentile:88.05(Engineering, Mechanical)Miao, Z.-Q.*; Xia, C.-J.*; Lai, X.-Y.*; Maruyama, Toshiki; Xu, R.-X.*; Zhou, E.-P.*
International Journal of Modern Physics E, 31(4), p.2250037_1 - 2250037_20, 2022/04
Times Cited Count:18 Percentile:87.28(Physics, Nuclear)Zhang, W. Q.*; Yamaguchi, Toshio*; Fang, C. H.*; Yoshida, Koji*; Zhou, Y. Q.*; Zhu, F. Y.*; Machida, Shinichi*; Hattori, Takanori; Li, W.*
Journal of Molecular Liquids, 348, p.118080_1 - 118080_11, 2022/02
Times Cited Count:5 Percentile:29.36(Chemistry, Physical)The ion hydration and association and hydrogen-bonded water structure in an aqueous 3 mol/kg RbCl solution were investigated at 298 K/0.1 MPa, 298 K/1 GPa, 523 K/1 GPa, and 523 K/4 GPa by neutron diffraction combined with EPSR methods. The second hydration layer of Rb
and Cl
becomes evident under elevated pressure and temperature conditions. The average oxygen coordination number of Rb
(Cl
) in the first hydration layer increases from 6.3 (5.9) ambient pressure to 8.9 (9.1) at 4 GPa, while decreasing coordination distance from 0.290 nm (0.322 nm) to 0.288 nm (0.314 nm). The orientation of the water dipole in the first solvation shell of Rb
and a central water molecule is sensitive to pressure, but that in the first solvation shell of Cl
does not change very much. The number of contact-ion pairs Rb
-Cl
decreases with elevated temperature and increases with elevated pressure. Water molecules are closely packed, and the tetrahedral hydrogen-bonded network of water molecules no longer exists in extreme conditions.
Naeem, M.*; Zhou, H.*; He, H.*; Harjo, S.; Kawasaki, Takuro; Lan, S.*; Wu, Z.*; Zhu, Y.*; Wang, X.-L.*
Applied Physics Letters, 119(13), p.131901_1 - 131901_7, 2021/09
Times Cited Count:23 Percentile:73.89(Physics, Applied)
-Orbital component in the Borromean nucleus
BYang, Z. H.*; Kubota, Yuki*; Corsi, A.*; Yoshida, Kazuki; Sun, X.-X.*; Li, J. G.*; Kimura, Masaaki*; Michel, N.*; Ogata, Kazuyuki*; Yuan, C. X.*; et al.
Physical Review Letters, 126(8), p.082501_1 - 082501_8, 2021/02
Times Cited Count:94 Percentile:97.22(Physics, Multidisciplinary)A quasifree (
,
) experiment was performed to study the structure of the Borromean nucleus
B, which had long been considered to have a neutron halo. By analyzing the momentum distributions and exclusive cross sections, we obtained the spectroscopic factors for
and
orbitals, and a surprisingly small percentage of 9(2)% was determined for
. Our finding of such a small
component and the halo features reported in prior experiments can be explained by the deformed relativistic Hartree-Bogoliubov theory in continuum, revealing a definite but not dominant neutron halo in
B. The present work gives the smallest
- or
-orbital component among known nuclei exhibiting halo features and implies that the dominant occupation of
or
orbitals is not a prerequisite for the occurrence of a neutron halo.
decay of
USun, M. D.*; Liu, Z.*; Huang, T. H.*; Zhang, W. Q.*; Andreyev, A. N.; Ding, B.*; Wang, J. G.*; Liu, X. Y.*; Lu, H. Y.*; Hou, D. S.*; et al.
Physics Letters B, 800, p.135096_1 - 135096_5, 2020/01
Times Cited Count:15 Percentile:74.21(Astronomy & Astrophysics)
C level structure by
-ray spectroscopyHosomi, Kenji; Ma, Y.*; Ajimura, Shuhei*; Aoki, Kanae*; Dairaku, Seishi*; Fu, Y.*; Fujioka, Hiroyuki*; Futatsukawa, Kenta*; Imoto, Wataru*; Kakiguchi, Yutaka*; et al.
Progress of Theoretical and Experimental Physics (Internet), 2015(8), p.081D01_1 - 081D01_8, 2015/08
Times Cited Count:15 Percentile:62.72(Physics, Multidisciplinary)Level structure of the
C hypernucleus was precisely determined by means of
-ray spectroscopy. We identified four
-ray transitions via the
C
reaction using a germanium detector array, Hyperball2. The spacing of the ground-state doublet
was measured to be
(stat)
(syst)keV from the direct
transition. Excitation energies of the
and
states were measured to be
, keV and
, keV, respectively. The obtained level energies provide definitive references for the reaction spectroscopy of
hypernuclei.