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under redox atmosphere and CO/NO catalytic reaction studied by dispersive XAFSMatsumura, Daiju; Okajima, Yuka; Nishihata, Yasuo; Mizuki, Junichiro; Taniguchi, Masashi*; Uenishi, Mari*; Tanaka, Hirohisa*
Journal of Physics; Conference Series, 190, p.012154_1 - 012154_6, 2009/11
Times Cited Count：10 Percentile：90.06Pd/LaFeO is known to keep the metal particle size small even after the long time redox processes because Pd atoms make complex oxide with LaFeO perovskite-type crystal under the oxidative atmosphere. We observed the local structure of Pd atoms by dispersive optics from the viewpoint of dynamical structure change of Pd during metal-oxide change and CO-NO catalytic reaction. It was recognized that, under the reductive atmosphere, Pd atoms show similar speed of movement from oxide to metal state both on LaFeO and Al
O. However, under the oxidative atmosphere, Pd atoms on LaFeO show faster movement from metal to oxide state with single reaction step than those on AlO with two-step oxidation. In addition, many differences in structure and shape between Pd particles on LaFeO and AlO are observed.
Matsuda, Yasuhiro*; Her, J. L.*; Inami, Toshiya; Owada, Kenji; Ouyang, Z. W.*; Okada, Kyoko*; Nojiri, Hiroyuki*; Mitsuda, Akihiro*; Wada, Hirofumi*; Yoshimura, Kazuyoshi*; et al.
Journal of Physics; Conference Series, 190, p.012019_1 - 012019_6, 2009/11
Times Cited Count：7 Percentile：85.61Izumi, Yudai*; Imazu, Akiko*; Mimoto, Aki*; Tanaka, Masafumi*; Nakagawa, Kazumichi*; Tanaka, Masahito*; Agui, Akane; Muro, Takayuki*
Journal of Physics; Conference Series, 190, p.012209_1 - 012209_4, 2009/11
Times Cited Count：8 Percentile：87.5Soft X-ray natural circular dichroism spectra of serine and alaninethin films, were measured in absolute value with the focus at the oxygen 1s to 
transition of COO
. The soft X-ray natural circular dichroism spectra intensity of L-Ala was about ten times as large as that of L-Ser. Those differences would reflect the chiral environment of the core hole oxygen atoms of COO.
-edgesIshimatsu, Naoki*; Sasada, Ryohei*; Maruyama, Hiroshi*; Ichikawa, Takayuki*; Miyaoka, Hiroki*; Kimura, Toru*; Tsubota, Masami*; Kojima, Yoshitsugu*; Tsumuraya, Takao*; Oguchi, Tamio*; et al.
Journal of Physics; Conference Series, 190, p.012070_1 - 012070_4, 2009/11
Times Cited Count：5 Percentile：79.63We have investigated the effect of hydrogenation on La 
and 
electronic states in metallic LaH
by X-ray absorption near edge structure at the La -edges. As the hydrogen content 
increases from 0 to 2.6, white-line intensity at the La 
-edges shows a remarkable increase in the range of 
2.0. This is interpreted as the increase in La hole induced by interstitial H atoms on the octahedral sites. On the other hand, the shoulder structure at the La 
-edge disappears in the process of = 0.0 
2.0, indicating that the 
-
hybridization is weakened by H atoms on the tetrahedral sites. This study demonstrates that H atoms on the two interstitial H sites provide different contribution to the modification of the electronic states.
