Local disorder in proton conductor BaSnInO analyzed by neutron diffraction/ atomic pair distribution function

Igawa, Naoki; Kodama, Katsuaki; Taguchi, Tomitsugu*; Yoshida, Yukihiko*; Matsukawa, Takeshi*; Hoshikawa, Akinori*; Ishigaki, Toru*

Transactions of the Materials Research Society of Japan, 43(6), p.329 - 332, 2018/12

https://doi.org/10.14723/tmrsj.43.329

For the understanding of the crystal structural effect on the electrical properties, the local disorder in BaSnInO which is one of the excellent proton conductors for solid oxide fuel cells was estimated by using the Atomic Pair Distribution Function (PDF) analysis method with the neutron diffraction. The local structure is almost the same as the average structure which was estimated by the Rietveld analysis using the cubic crystal structure (space group, ) in the atomic distance range of 6. The PDF profile was fitted better using the tetragonal crystal structure with the space group of 4/ than those with in the range 6. Those results indicate the presence of the local disorder in the lattice. In this work, the relationship between the average and local structures of BaSnInO will be discussed.

Local structural analysis on the parent compound of iron-based superconductor PrFeAsO by atomic pair distribution function

Kodama, Katsuaki; Ishikado, Motoyuki*; Ikeda, Kazutaka*; Shamoto, Shinichi; Otomo, Toshiya*

no journal, ,