Conductometric analysis for the formation of poly(vinylidene fluoride)-based ion track membranes

Yamaki, Tetsuya; Nuryanthi, N.*; Koshikawa, Hiroshi; Asano, Masaharu; Sawada, Shinichi; Hasegawa, Shin; Maekawa, Yasunari; Voss, K.-O.*; Trautmann, C.*; Neumann, R.*

ECS Transactions, 35(24), p.1 - 12, 2011/05

https://doi.org/10.1149/1.3643329

Our focus has been placed on ion track membranes of poly(vinylidene fluoride) (PVDF), a type of fluoropolymer, because of their superior chemical, mechanical and ferro-electric properties. The aim of this study is to investigate the formation of the PVDF track membranes in more detail by electrolytic conductometry. Interestingly, application of a higher voltage to the conductometry cell as well as irradiation with a higher-LET beam promoted track etching up to breakthrough probably because electrophoretic migration of dissolved products occurred out of each pore.