Magnetic and dielectric properties of RCaMnO (R=Eu-Lu)

Yoshii, Kenji; Hiramitsu, Yusuke*; Yoneda, Yasuhiro; Okajima, Yuka; Nishihata, Yasuo; Mizuki, Junichiro; Ikeda, Naoshi*

Ferroelectrics, 379(1), p.183 - 190, 2009/05

https://doi.org/10.1080/00150190902852208

The magnetic and dielectric properties of perovskite manganites RCaMnO (R=Eu-Lu) have been investigated. Their dielectric constants were about 1000 at around room temperature. Inflections or peaks of temperature dependences of the dielectric constants were observed at around the charge-ordering temperatures determined from the magnetic measurements. Analyses of tan and EXAFS spectra suggested that the dielectric properties of this system are due to a spatial arrangement and transfer of the Mn-3d electrons. The observation of a two-peak structure of tan indicates that dielectric measurement can be used to observe homogeneity or in homogeneity of sample, as mentioned in our previous paper.