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Journal Articles

Concurrent operando neutron imaging and diffraction analysis revealing spatial lithiation phase evolution in an ultra-thick graphite electrode

Strobl, M.*; Baur, M. E.*; Samothrakitis, S.*; Molamud, F.*; Zhang, X.*; Tung, P. K. M.*; Schmidt, S.*; Woracek, R.*; Lee, J.*; Kiyanagi, Ryoji; et al.

Advanced Energy Materials, p.2405238_1 - 2405238_9, 2025/01

Journal Articles

Pseudotunnel magnetoresistance in twisted van der Waals Fe$$_3$$GeTe$$_2$$ homojunctions

Obata, Reiji*; Saito, Eiji; Kikkawa, Takashi; 13 of others*

Advanced Materials, p.2411459_1 - 2411459_11, 2025/00

 Times Cited Count:0 Percentile:0.00(Chemistry, Multidisciplinary)

Journal Articles

First-principles calculations on dislocations in MgO

Kiyohara, Shin*; Tsuru, Tomohito; Kumagai, Yu*

Science and Technology of Advanced Materials, 25(1), p.2393567_1 - 2393567_9, 2024/09

 Times Cited Count:0 Percentile:0.00(Materials Science, Multidisciplinary)

While ceramic materials are widely used in our society, their understanding of the plasticity is not fully understood. MgO is one of the prototypical ceramics, extensively investigated experimentally and theoretically. However, there is still controversy over whether edge or screw dislocations glide more easily. In this study, we directly model the atomic structures of the dislocation cores in MgO based on the first-principles calculations and estimate the Peierls stresses. Our results reveal that the screw dislocation on the primary slip system exhibits a smaller Peierls stress than the edge dislocation. The tendency is not consistent with metals, but rather with TiN, suggesting a characteristic inherent to ceramics.

Journal Articles

Coexistence of quantum-spin-hall and quantum-hall-topological-insulating states in graphene/hBN on SrTiO$$_3$$ substrate

Obata, Reiji*; Saito, Eiji; Kikkawa, Takashi; 7 of others*

Advanced Materials, 36(19), p.2311339_1 - 2311339_8, 2024/05

 Times Cited Count:0 Percentile:0.00(Chemistry, Multidisciplinary)

Journal Articles

Abnormal grain growth; A Spontaneous activation of competing grain rotation

Liss, K.-D.*; Xu, P. G.; Shiro, Ayumi*; Zhang, S. Y.*; Yukutake, Eitaro*; Shobu, Takahisa; Akita, Koichi*

Advanced Engineering Materials, 26(4), p.202300470_1 - 202300470_9, 2024/02

 Times Cited Count:3 Percentile:27.27(Materials Science, Multidisciplinary)

Journal Articles

Laser-induced creation of antiferromagnetic 180-degree domains in NiO/Pt bilayers

Meer, H.*; Wust, S.*; Schmitt, C.*; Herrgen, P.*; Fuhrmann, F.*; Hirtle, S.*; Bednarz, B.*; Rajan, A.*; Ramos, R.*; Ni$~n$o, M. A.*; et al.

Advanced Functional Materials, 33(21), p.2213536_1 - 2213536_6, 2023/05

 Times Cited Count:5 Percentile:46.83(Chemistry, Multidisciplinary)

Journal Articles

Enhanced arsenic removal from aqueous solutions via magnesium hydroxide coated iron nanoparticles

Maamoun, I.; Falyouna, O.*; Shariful, I. M.*; Eljamal, R.*; Bensaida, K.*; Tanaka, Kazuya; Tokunaga, Kohei; Eljamal, O.*

Advanced Materials Letters (Internet), 14(2), p.23021721_1 - 23021721_10, 2023/04

Journal Articles

Tough yet flexible superelastic alloys meet biomedical needs

Xu, X.*; Odaira, Takumi*; Xu, S.*; Hirata, Kenji*; Omori, Toshihiro*; Ueki, Kosuke*; Ueda, Kyosuke*; Narushima, Takayuki*; Nagasako, Makoto*; Kainuma, Ryosuke*; et al.

Advanced Materials & Processes, 180(7), p.35 - 37, 2022/10

Journal Articles

Flexible and tough superelastic Co-Cr alloys for biomedical applications

Odaira, Takumi*; Xu, S.*; Hirata, Kenji*; Xu, X.*; Omori, Toshihiro*; Ueki, Kosuke*; Ueda, Kyosuke*; Narushima, Takayuki*; Nagasako, Makoto*; Harjo, S.; et al.

Advanced Materials, 34(27), p.2202305_1 - 2202305_11, 2022/07

 Times Cited Count:24 Percentile:89.89(Chemistry, Multidisciplinary)

Journal Articles

Direct ${it in-situ}$ temperature measurement for lamp-based heating device

Sumita, Takehiro; Sudo, Ayako; Takano, Masahide; Ikeda, Atsushi

Science and Technology of Advanced Materials; Methods (Internet), 2(1), p.50 - 54, 2022/02

Journal Articles

Star-polymer-DNA gels showing highly predictable and tunable mechanical responses

Ohira, Masashi*; Katashima, Takuya*; Naito, Mitsuru*; Aoki, Daisuke*; Yoshikawa, Yusuke*; Iwase, Hiroki*; Takata, Shinichi; Miyata, Kanjiro*; Chung, U.-I.*; Sakai, Takamasa*; et al.

Advanced Materials, 34(13), p.2108818_1 - 2108818_9, 2022/01

 Times Cited Count:21 Percentile:86.92(Chemistry, Multidisciplinary)

Journal Articles

Work hardening behavior of hot-rolled metastable Fe$$_{50}$$Co$$_{25}$$Ni$$_{10}$$Al$$_{5}$$Ti$$_{5}$$Mo$$_{5}$$ medium-entropy alloy; In situ neutron diffraction analysis

Kwon, H.*; Harjo, S.; Kawasaki, Takuro; Gong, W.; Jeong, S. G.*; Kim, E. S.*; Sathiyamoorthi, P.*; Kato, Hidemi*; Kim, H. S.*

Science and Technology of Advanced Materials, 23(1), p.579 - 586, 2022/00

 Times Cited Count:11 Percentile:50.07(Materials Science, Multidisciplinary)

Journal Articles

High reactivity of H$$_{2}$$O vapor on GaN surfaces

Sumiya, Masatomo*; Sumita, Masato*; Tsuda, Yasutaka; Sakamoto, Tetsuya; Sang, L.*; Harada, Yoshitomo*; Yoshigoe, Akitaka

Science and Technology of Advanced Materials, 23(1), p.189 - 198, 2022/00

 Times Cited Count:6 Percentile:44.37(Materials Science, Multidisciplinary)

GaN is an attracting material for power-electronic devices. Understanding the oxidation at GaN surface is important for improving metal-oxide-semiconductor (MOS) devices. In this study, the oxidation at GaN surfaces depending on the GaN crystal planes (+c, -c, and m-plane) was investigated by real time XPS and DFT-MD simulation. We found that H$$_{2}$$O vapor has the highest reactivity due to the spin interaction between H$$_{2}$$O and GaN surfaces. The bond length between the Ga and N on the -c GaN surface was increased by OH attacking the back side of three-fold Ga atom. The chemisorption on the m-plane was dominant. The intense reactions of oxidation and Al$$_{x}$$Ga$$_{1-x}$$N formation for p-GaN were observed at the interface of the Al$$_{2}$$O$$_{3}$$ layer deposited by ALD using H$$_{2}$$O vapor. This study suggests that an oxidant gas other than H$$_{2}$$O and O$$_{2}$$ should be used to avoid unintentional oxidation during Al$$_{x}$$Ga$$_{1-x}$$N atomi layer deposition.

Journal Articles

Magnetically navigated protein transduction in vivo using iron oxide-nanogel chaperone hybrid

Kawasaki, Riku*; Sasaki, Yoshihiro*; Nishimura, Tomoki*; Katagiri, Kiyofumi*; Morita, Keiichi*; Sekine, Yurina; Sawada, Shinichi*; Mukai, Sadaatsu*; Akiyoshi, Kazunari*

Advanced Healthcare Materials, 10(9), p.2001988_1 - 2001988_8, 2021/05

 Times Cited Count:11 Percentile:58.28(Engineering, Biomedical)

Systems for "protein transduction", the intracellular delivery of functional proteins, are needed to address the deliverability challenges of protein therapy, but protein transfer in vivo remains difficult. In this study, we have developed a magnetically induced in vivo protein transfection system using a magnetic nanogel chaperone (MC) composed of iron oxide nanoparticles and polysaccharide nanogels. Experiments using an oral cancer model have shown that this MC system is useful for cancer treatment.

Journal Articles

Suppressed lattice disorder for large emission enhancement and structural robustness in hybrid lead iodide perovskite discovered by high-pressure isotope effect

Kong, L.*; Gong, J.*; Hu, Q.*; Capitani, F.*; Celeste, A.*; Hattori, Takanori; Sano, Asami; Li, N.*; Yang, W.*; Liu, G.*; et al.

Advanced Functional Materials, 31(9), p.2009131_1 - 2009131_12, 2021/02

 Times Cited Count:30 Percentile:82.95(Chemistry, Multidisciplinary)

The soft nature of organic-inorganic halide perovskites renders their lattice particularly tunable to external stimuli such as pressure, undoubtedly offering an effective way to modify their structure for extraordinary optoelectronic properties. However, these soft materials meanwhile feature a general characteristic that even a very mild pressure will lead to detrimental lattice distortion and weaken the critical light-matter interaction, thereby triggering the performance degradation. Here, using the methylammonium lead iodide as a representative exploratory platform, we observed the pressure-driven lattice disorder can be significantly suppressed via hydrogen isotope effect, which is crucial for better optical and mechanical properties previously unattainable.

Journal Articles

Development on laser cutting technique to suppress spatter particles aiming at disposal of radio-active waste

Naoe, Takashi; Teshigawara, Makoto; Futakawa, Masatoshi; Mizutani, Haruki; Muramatsu, Toshiharu; Yamada, Tomonori; Ushitsuka, Yuji*; Tanaka, Nobuatsu*; Yamasaki, Kazuhiko*

Proceedings of 8th International Congress on Laser Advanced Materials Processing (LAMP 2019) (Internet), 5 Pages, 2019/05

Laser cutting is one of the options in the disposal of radio-active waste, such as spallation neutron target vessel in J-PARC, etc. Due to unique characteristic of laser, such as non-contact system, it is more easily to provide remote-controlled system in comparison with conventional one, such as mechanical cutting machine, etc. However, a demerit of laser cutting is the sputter and fume caused by laser cutting, resulting in contamination with radio-active materials its surroundings. Recently it was developed that the spatter suppression technique by controlling laser beam profile in laser welding process. In order to apply this suppression technique to laser cutting, first of all, we attempted to observe the phenomenon at melting area during laser cutting using a high-speed video camera in order to make the physical model. The result showed that the appearance of fume and sputter were independently confirmed in the time evolution.

Journal Articles

Retreat from stress; Rattling in a planar coordination

Suekuni, Koichiro*; Lee, C. H.*; Tanaka, Hiromi*; Nishibori, Eiji*; Nakamura, Atsushi*; Kasai, Hidetaka*; Mori, Hitoshi*; Usui, Hidetomo*; Ochi, Masayuki*; Hasegawa, Takumi*; et al.

Advanced Materials, 30(13), p.1706230_1 - 1706230_6, 2018/03

 Times Cited Count:58 Percentile:89.18(Chemistry, Multidisciplinary)

Thermoelectric materials for highly efficient devices must satisfy conflicting requirements of high electrical conductivity and low thermal conductivity. In this paper, we studied the crystal structure and phonon dynamics of tetrahedrites (Cu,Zn)$$_{12}$$(Sb,As)$$_{4}$$S$$_{13}$$. The results revealed that the Cu atoms in a planar coordination are rattling, which effectively scatter phonons. These findings provide a new strategy for the development of highly efficient thermoelectric materials with planar coordination.

Journal Articles

Investigation of microstructure in additive manufactured Inconel 625 by spatially resolved neutron transmission spectroscopy

Tremsin, A. S.*; Gao, Y.*; Dial, L. C.*; Grazzi, F.*; Shinohara, Takenao

Science and Technology of Advanced Materials, 17(1), p.324 - 336, 2016/07

AA2016-0560.pdf:3.26MB

 Times Cited Count:20 Percentile:53.11(Materials Science, Multidisciplinary)

Journal Articles

Surface modification effects on hydrogen absorption property of a hydrogen storage alloy by short pulse laser irradiation

Abe, Hiroshi; Shimomura, Takuya; Tokuhira, Shinnosuke*; Shimada, Yukihiro*; Takenaka, Yusuke*; Furuyama, Yuta*; Nishimura, Akihiko; Uchida, Hirohisa*; Daido, Hiroyuki; Oshima, Takeshi

Proceedings of 7th International Congress on Laser Advanced Materials Processing (LAMP 2015) (Internet), 4 Pages, 2015/08

A short pulse laser (the nanosecond and femtosecond) was applied to hydrogen absorbing alloys surface layer, and a surface modification experiment was put into effective to aim at improvement of hydrogen adsorption functionally. It was investigated about correlation between an initial hydrogen absorption reaction rate of hydrogen alloys and a laser irradiation in this research. The laser irradiation condition was done with pulse width 100 fsec and energy 0.2 - 3.4 mJ/pulse. It blazed down on hydrogen absorbing alloys (LaNi$$_{4.6}$$Al$$_{0.4}$$) and changed local order in the surface. As a result, the initial hydrogen absorption reaction rate was 1.5 - 3.0 times as fast as a irradiated sample, and the result and laser irradiated sample found out that a hydrogen absorption function improves. A laser irradiation can conclude to be effective in surface modification of the hydrogen storage materials.

Journal Articles

The Study on application of laser technology for the reactor core dismantling

Iwai, Hiroki; Nakamura, Yasuyuki; Mizui, Hiroyuki; Sano, Kazuya; Morishita, Yoshitsugu

Proceedings of 7th International Congress on Laser Advanced Materials Processing (LAMP 2015) (Internet), 4 Pages, 2015/08

The reactor of FUGEN is characterized by its tube-cluster construction that contains 224 channels arranging both the pressure and the calandria tubes coaxially in each channel. And the periphery part of the core has the laminated structure of up to 150 mm thickness of carbon steel for radiation shielding. Method for dismantling the reactor core is also being studied with considering processes of dismantlement by remote-handling devices under the water for the radiation shielding. In order to shorten the term of the reactor dismantlement work and reduce the secondary waste, some cutting tests and literature research for various cutting methods had been carried out. As the result, the laser cutting method, which has feature of the narrow cutting kerf and the fast cutting velocity, was mainly selected for dismantling the reactor. In this presentation, current activities of FUGEN decommissioning and R&D of laser cutting tests are introduced.

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