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Khalil, A. M. E.*; Han, L.*; Maamoun, I.; Tabish, T. A.*; Chen, Y.*; Eljamal, O.*; Zhang, S.*; Butler, D.*; Memon, F. A.*
Advanced Sustainable Systems (Internet), 6(8), p.2200016_1 - 2200016_16, 2022/08
被引用回数:6 パーセンタイル:43.81(Green & Sustainable Science & Technology)Graphene-based materials have emerged as alternative adsorbents, but their success in removing pharmaceutical contaminants has been limited due to degradation caused by restacking and limited control over their sizes and porosities. Driven by this issue, in the current study, to counteract the restacking behavior, graphene sheets are supported on a thread/rod-like matrix structure in a boron nitride foam material, and a novel porous composite foam-supported graphene is synthesized. The as-prepared novel composite offers extraordinary features, such as high absorption kinetics, large available surface area, high porosity, ecofriendliness and cost-effective synthesis, and excellent affinity to emerging pharmaceutical contaminants. When batch-testing graphene-based foam material and porous graphene nanosheets to remove gemfibrozil (GEM) from wastewater samples, rapid adsorption kinetics (less than 5 min) are exhibited by the graphene-based foam. Column filter studies are conducted for both materials to test their performance in removing GEM from distilled water, synthetic graywater, and actual wastewater. Overall, the foam composite-based filter marginally outperforms the sand-supported graphene filter and significantly outperforms the unsupported graphene filter. A numerical MATLAB model is developed to simulate the reactive solute transport of GEM influent through the foam filter. Also, a formal sensitivity analysis is conducted to identify the key parameters influencing the model results.
Kim, J.*; 山中 暁*; 中島 啓*; 加藤 孝典*; Kim, Y.*; 福田 竜生; 吉井 賢資; 西畑 保雄; 馬場 将亮*; 武田 雅敏*; et al.
Advanced Sustainable Systems (Internet), 2(11), p.1800067_1 - 1800067_8, 2018/11
被引用回数:7 パーセンタイル:25.76(Green & Sustainable Science & Technology)An innovative electrothermodynamic cycle (pyroelectric effect with an external electric field) was recently presented, which is based on temporal temperature variations in wasted heat from engine exhaust gas. In this paper, for further improvement, a generating mechanism of the cycle is investigated using in-operando time-resolved synchrotron X-ray diffraction with generating assessment. The polarizations of the sample are gained from both crystal/domain changes and simultaneous electrical measurements. Three types of materials are prepared: soft and hard types of lead zirconate titanate (PZT) and lead magnesium niobate-lead titanate (PMN-PT). Among them, PMN-PT has the highest generating power. When an external electric field is applied, the PMN-PT exhibits only 180 domain rotations, whereas PZTs exhibit both 90 and 180 rotations. A strong driving force for 180 rotation depresses rotations in other angles and increases polarization changes. The results show that the material development, which has only 180 switching domains, has potential for use in the establishment of a high-efficiency waste heat recovery system.
山中 暁*; Kim, J.*; 中島 啓*; 加藤 孝典*; Kim, Y.*; 福田 竜生; 吉井 賢資; 西畑 保雄; 馬場 将亮*; 山田 昇*; et al.
Advanced Sustainable Systems (Internet), 1(3-4), p.1600020_1 - 1600020_6, 2017/04
プロジェクトとして取り組んできている自動車排ガスを用いた温度変化発電に関し、変換素子の材料選定等に重要となる性能指数について、素子の物理量の温度変化の測定を行うことで調べた。測定結果を用い、これまで提案されていたいくつかの性能指数の温度変化を詳しく調べて比較することで、と呼ばれる指数が最も発電量との相関が高いことを示した。この指数には唯一誘電正接()が含まれており、誘電体内での電気エネルギー損失が重要であることを示唆する結果となっている。