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Journal Articles

Safe and rapid development of capillary electrophoresis for ultratrace uranyl ions in radioactive samples by way of fluorescent probe selection for actinide ions from a chemical library

Haraga, Tomoko; Ouchi, Kazuki; Sato, Yoshiyuki; Hoshino, Hitoshi*; Tanana, Rei*; Fujihara, Takashi*; Kurokawa, Hideki*; Shibukawa, Masami*; Ishimori, Kenichiro; Kameo, Yutaka; et al.

Analytica Chimica Acta, 1032, p.188 - 196, 2018/11

 Times Cited Count:1 Percentile:62.19(Chemistry, Analytical)

The development of safe, rapid and highly sensitive analytical methods for radioactive samples, especially actinide (An) ions, represents an important challenge. Here we propose a methodology for selecting appropriate emissive probes for An ions with very low consumption and emission of radioactivity by capillary electrophoresis-laser-induced fluorescence detection (CE-LIF), using a small chemical library of probes with eight different chelating moieties. It was found that the emissive probe, which possesses the tetradentate chelating moiety, was suitable for detecting uranyl ions. The detection limit for the uranyl-probe complex using CE-LIF combined with dynamic ternary complexation and on-capillary concentration techniques was determined to be 0.7 ppt. This method was successfully applied to real radioactive liquid samples collected from nuclear facilities.

Journal Articles

Rapid collection of iron hydroxide for determination of Th isotopes in seawater

Okubo, Ayako; Obata, Hajime*; Magara, Masaaki; Kimura, Takaumi; Ogawa, Hiroshi*

Analytica Chimica Acta, 804, p.120 - 125, 2013/12

 Times Cited Count:1 Percentile:93.65(Chemistry, Analytical)

This work introduces a novel method of recovery of iron hydroxide using a DIAION CR-20 chelating resin column to determine Th isotopes in seawater with a sector field (SF) inductively coupled plasma mass spectrometer (ICP-MS). Thorium isotopes in seawater were coprecipitated with iron hydroxide, and this precipitate was sent to chelating resin column. The chelating column quantitatively collected $$^{232}$$Th with iron hydroxide in seawater at flow rates of 20-25 mL/min. Based on this flow rate, a 5 L sample was processed within 3-4 h.

Journal Articles

Fission track-secondary ion mass spectrometry as a tool for detecting the isotopic signature of individual uranium containing particles

Esaka, Fumitaka; Lee, C. G.; Magara, Masaaki; Kimura, Takaumi

Analytica Chimica Acta, 721, p.122 - 128, 2012/04

 Times Cited Count:24 Percentile:22.81(Chemistry, Analytical)

A fission track technique was used as a sample preparation method for subsequent isotope abundance ratio analysis of individual uranium containing particles with secondary ion mass spectrometry (SIMS) to measure the particles with higher enriched uranium efficiently. This method was then applied to the analysis of a real inspection swipe sample taken at a nuclear facility. As a consequence, the range of $$^{235}$$U/$$^{238}$$U isotope abundance ratio between 0.0276 and 0.0438 was obtained, which was higher than that measured by SIMS without using a fission track technique (0.0225 and 0.0341). This indicates that the fission track - SIMS method is a powerful tool to identify the particle with higher enriched uranium in environmental samples efficiently.

Journal Articles

A method for the determination of extraction capacity and its application to $$N,N,N',N'$$-tetraalkylderivatives of diglycolamide-monoamide/n-dodecane media

Sasaki, Yuji; Sugo, Yumi; Suzuki, Shinichi; Kimura, Takaumi

Analytica Chimica Acta, 543(1-2), p.31 - 37, 2005/07

 Times Cited Count:85 Percentile:6.25(Chemistry, Analytical)

The detailed study of extraction capacity of diglycolamide (DGA) with and without DHOA, N,N'-dihexyloctanamide as a modifier, was performed by using the novel analytical method for the determination of the limit of metal concentration in the organic phase (LOC). The effect on modifier was studied and it is confirmed that LOC increases with DHOA concentration. It is noteworthy that LOC reaches to the stoichiometric value, which is obtained by the extraction reaction, by using 0.1M TODGA mixed with more than 0.5M DHOA into n-dodecane. Without modifier, relation of the different DGA compounds with LOC was investigated, and it is clear that LOC using N,N,N',N'-tetradodecyl-diglycolamide (TDdDGA), whose extractant can suppress the third phase, reaches to the stoichiometric value. From this work, it is obvious that the application of the condition without the third phase formation, e.g., enough concentration of modifier coexisted and DGA with long alkyl chain, is important to attain the stochiometric LOC value.

Journal Articles

Rapid and quantitative electrolytic preparation and speciation of neptunium ions of various oxidation states using multi-step column electrodes

Aoyagi, Hisao*; Kitatsuji, Yoshihiro; Yoshida, Zenko; Kihara, Sorin*

Analytica Chimica Acta, 538(1-2), p.283 - 289, 2005/05

 Times Cited Count:12 Percentile:60.14(Chemistry, Analytical)

Redox behavior of Np(III), (IV), (V) and (VI) ions in aqueous perchloric, nitric and sulphuric acid solutions was elucidated by using column electrodes connected in series in a flow system. Using a glassy carbon fiber working electrode as the column electrode was found to be very useful for the investigation of current-potential relations of not only reversible redox processes such as Np(VI)/(V) or Np(IV)/(III) but also irreversible processes such as Np(V)/(IV) or Np(V)/(III), the latter not observed by conventional voltammetry which uses a glassy carbon or platinum electrode. Quantitative electrolysis could be executed even if the redox process was completely irreversible by the use of the column electrodes. By taking advantage of column electrode electrolysis, a novel method was developed for the rapid preparation of a neptunium species of a desired oxidation state, including unstable species. The multi-step column electrode system was demonstrated to be useful for the coulometric determination and speciation of Np(IV), (V) and (VI) in aqueous HNO$$_{3}$$ solution as an example.

Journal Articles

Cumulative study on solvent extraction of elements by ${it N,N,N',N'}$-tetraoctyl-3-oxapentanediamide (TODGA) from nitric acid into ${it n}$-dodecane

Zhu, Z.-X.; Sasaki, Yuji; Suzuki, Hideya*; Suzuki, Shinichi; Kimura, Takaumi

Analytica Chimica Acta, 527(2), p.163 - 168, 2004/12

 Times Cited Count:178 Percentile:1.39(Chemistry, Analytical)

The extraction of 75 elements by ${it N,N,N',N'}$-tetraoctyl-3-oxapentanediamide (TODGA) from nitric acid to ${it n}$-dodecane was investigated and discussed concerning distribution ratios (D) of metal ions and their ionic radii. The extractability for elements depends strongly on their oxidation state. Monovalent and pentavalent ions were not extractable. In divalent metal extraction, Ca(II) (ionic radius: 100 pm) showed the highest D value and the D decreased with increase or decrease of the ionic radius. Tri- and tetravalent ions with ionic radii of 87-113 pm and 83-94 pm, respectively, showed the D over 1000, and the extracted chemical forms were determined to be M(TODGA)$$_{3}$$(NO$$_{3}$$)$$_{{it n}}$$ or M(TODGA)$$_{4}$$(NO$$_{3}$$)$$_{{it n}}$$ (${it n}$=3 or 4). The oxonium ions with higher oxidation states than tetravalent one forms the complicated metal-complex with TODGA, and the number of TODGA associated in those extraction reactions was confirmed to be 2 at most.

Journal Articles

Feasibility study of solid sampling electrothermal vaporization inductively coupled plasma mass spectrometry for the determination of particulate uranium in swipe samples from nuclear facilities

Lee, C. G.; Iguchi, Kazunari; Esaka, Konomi; Magara, Masaaki; Esaka, Fumitaka; Sakurai, Satoshi; Watanabe, Kazuo; Usuda, Shigekazu

Analytica Chimica Acta, 517(1-2), p.215 - 220, 2004/07

 Times Cited Count:3 Percentile:87.68(Chemistry, Analytical)

In this study, we discussed the feasibility of solid sample ETV-ICP-MS for the particle analysis of the environmental swipe samples in order to establish the fission track-ETV-ICP-MS method. Samples used were solid samples containing Tl, Pb and U in polycarbonate film, and their standard solutions. The analytical performance will be reported in terms of the optimization of temperature program, and sensitivity and precision in isotope ratio measurement.

Journal Articles

Solvent extraction of uranium, neptunium, plutonium, americium, curium and californium ions by bis(1-phenyl-3-methyl-4-acylpyrazol-5-one) derivatives

Takeishi, Hideyo; Kitatsuji, Yoshihiro; Kimura, Takaumi; Meguro, Yoshihiro; Yoshida, Zenko; Kihara, Sorin*

Analytica Chimica Acta, 431(1), p.69 - 80, 2001/03

 Times Cited Count:25 Percentile:35.3

no abstracts in English

Journal Articles

Plutonium(III)-ion selective electrode of liquid membrane type using multidentate phosphine oxide ionophore

Kitatsuji, Yoshihiro; Aoyagi, Hisao; Yoshida, Zenko; Kihara, Sorin*

Analytica Chimica Acta, 387, p.181 - 187, 1999/00

 Times Cited Count:9 Percentile:62.55

no abstracts in English

Journal Articles

Determination of nitrogen in uranium-plutonium mixed oxide fuel by gas chromatography after fusion in an inert gas atmosphere

Hiyama, Toshiaki; Hiyama, Toshiaki; Takahashi, Toshio; Kamimura, Katsuichiro

Analytica Chimica Acta, 345(1), p.131 - 137, 1997/06

None

Journal Articles

Journal Articles

Determination of nitrogen in UN, PuN and (U, Pu)N by oxidation in circulating oxygen and gas chromatographic measurement of the combustion gases

Handa, Nuneo; Shiozawa, Kenichi; Iwai, Takashi; Arai, Yasuo

Analytica Chimica Acta, 239, p.107 - 113, 1990/00

 Times Cited Count:9 Percentile:51.38

no abstracts in English

Journal Articles

Enhancement of ruthenium determination in inductively coupled plasma/atomic emission spectrometry by addition of periodic acid

Adachi, Takeo; Takeishi, Hideyo; Sasaki, Yuji; *

Analytica Chimica Acta, 218, p.77 - 84, 1989/00

 Times Cited Count:16 Percentile:32.24

no abstracts in English

Journal Articles

Determination of traces of ruthenium by addition of cerium(IV)and atomic absorption spectrometry

*; *; ; ;

Analytica Chimica Acta, 183, p.217 - 223, 1986/00

 Times Cited Count:17 Percentile:31.78

no abstracts in English

Journal Articles

Atomic absorption spectrometric determination of the isotopic composition of lithium by an ultimate absorbance-ratio technique

Analytica Chimica Acta, 183, p.225 - 230, 1986/00

 Times Cited Count:4 Percentile:71.1

no abstracts in English

Journal Articles

Anodic stripping voltammetry at a nickel-based mercury film electrode

;

Analytica Chimica Acta, 172, p.39 - 47, 1985/00

 Times Cited Count:6 Percentile:60

no abstracts in English

Journal Articles

Accurate determination of sulfur at trace levels by isotope dilution mass spectrometry

Analytica Chimica Acta, 147, p.417 - 421, 1983/00

 Times Cited Count:11 Percentile:34.97

no abstracts in English

Journal Articles

An Improved gravimetric method for determining oxygen in binary and ternary uranium oxides by addition of alkali or alkaline earth metal nitrate

Fujino, Takeo; ;

Analytica Chimica Acta, 147, p.423 - 428, 1983/00

 Times Cited Count:1 Percentile:88.68

no abstracts in English

Journal Articles

Rapid determination of mercury in air with gold-coated quartz wool as collector

;

Analytica Chimica Acta, 106(2), p.405 - 410, 1979/00

 Times Cited Count:19

no abstracts in English

Journal Articles

Determination of oxygen in ternary uranium oxides by a gravimetric alkaline earth addition method

Fujino, Takeo; Tagawa, Hiroaki

Analytica Chimica Acta, 107, p.365 - 371, 1979/00

 Times Cited Count:2

no abstracts in English

34 (Records 1-20 displayed on this page)