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Imai, Yosuke*; Tokiwa, Yuhei*; Ueno, Shusaku*; Tanida, Hajime; Watanabe, Iwao*; Matsubara, Hiroki*; Takiue, Takanori*; Aratono, Makoto*
Bulletin of the Chemical Society of Japan, 91(10), p.1487 - 1494, 2018/10
Times Cited Count:0 Percentile:100(Chemistry, Multidisciplinary)Competitive binding of binary mixed counterions to the headgroups of adsorbed surfactant films has been investigated at solution surfaces by total reflection X-ray absorption fine structure (XAFS) spectroscopy. The obtained extended XAFS spectra for bromide counterions are linear combinations of the spectra of fully hydrated bromide ions (free Br) and partially dehydrated bromide ions bound to the headgroups of the surfactant ions (bound Br). From the fraction of bound Br in counterion mixed systems, two series of the relative strengths of counterion binding are proposed for the trimethylammonium (TA
) and 3-methylimidazolium (MIM
) headgroups: (a) TA-SO
TA-Cl
TA-Br
TA-BF
and (b) MIM-Br
TA-Br
TA-BF
MIM-BF
. For the TA headgroup, matching the hydration of the headgroups and counterions gives series (a) according to Collins' law, which states that the tendency of contact ion pair formation becomes larger when the absolute values of the hydration enthalpies of the ions match. For the MIM headgroup, the number of binding sites of hydrogen bonds between the MIM headgroup and counterion is essential, which leads to series (b) because of competition between the counterion and water for interaction with the MIM headgroup.
Aoyagi, Noboru; Palladino, G.*; Nagasaki, Shinya*; Kimura, Takaumi
Bulletin of the Chemical Society of Japan, 91(6), p.882 - 890, 2018/06
Times Cited Count:1 Percentile:89.35(Chemistry, Multidisciplinary)The speciation and coordination geometries of M(III)-citrate complexes in aqueous solutions, where M denotes Eu, Tb, Lu, or Cm, are studied using potentiometric titration, nuclear magnetic resonance spectroscopies. Their photophysical properties are also characterized by time-resolved fluorescence spectra. The formation constants of mononuclear, dinuclear, and trinuclear Lu-citrate species were determined by potentiometric titration in 3.00 M NaClO aqueous media. Terminal carboxylic conformation in trinuclear complexes comprised both the five- and six-membered rings at different exchanging rates. Hydration states evaluated for Eu
ions are the chemical formula of [Eu(Cit)
(H
O)
]
and [Eu
(OH)
(Cit)
(H
O)
]
. These complexes in aqueous solution have geometrical similarity to the crystal structures in the literature. Furthermore, the entity of the hetero-trinuclear complex induces the intramolecular energy transfer from Tb
to Eu
. The incorporation of Cm
into these homo/hetero-trinuclear citrate complexes proved to be a successful trial to probe the formation of actinide polymer at a trace level.
Saptiama, I.*; Kaneti, Y. V.*; Oveisi, H.*; Suzuki, Yoshitaka; Tsuchiya, Kunihiko; Takai, Kimiko*; Sakae, Takeji*; Pradhan, S.*; Hossain, M. S. A.*; Fukumitsu, Nobuyoshi*; et al.
Bulletin of the Chemical Society of Japan, 91(2), p.195 - 200, 2018/02
Times Cited Count:31 Percentile:7.8(Chemistry, Multidisciplinary)no abstracts in English
Saptiama, I.*; Kaneti, Y. V.*; Suzuki, Yumi*; Suzuki, Yoshitaka; Tsuchiya, Kunihiko; Sakae, Takeji*; Takai, Kimiko*; Fukumitsu, Nobuyoshi*; Alothman, Z. A.*; Hossain, M. S. A.*; et al.
Bulletin of the Chemical Society of Japan, 90(10), p.1174 - 1179, 2017/10
Times Cited Count:34 Percentile:11.47(Chemistry, Multidisciplinary)no abstracts in English
Toyomori, Yuka*; Tsuji, Satoru*; Mitsuda, Shinobu*; Okayama, Yoichi*; Ashida, Shiomi*; Mori, Atsunori*; Kobayashi, Toru; Miyazaki, Yuji; Yaita, Tsuyoshi; Arae, Sachie*; et al.
Bulletin of the Chemical Society of Japan, 89(12), p.1480 - 1486, 2016/09
Times Cited Count:5 Percentile:69.82(Chemistry, Multidisciplinary)Suzuki, Tomoya; Morita, Keisuke; Sasaki, Yuji; Matsumura, Tatsuro
Bulletin of the Chemical Society of Japan, 89(5), p.608 - 616, 2016/05
Times Cited Count:3 Percentile:80.64(Chemistry, Multidisciplinary)In a previous study, we found that AMP03 adsorbs Rh(III) from the HNO solution with pH = 1.7 - 2.2. In this study, to understand the Rh(III) adsorption properties of AMP03 and clarify conditions for efficient recovery, we investigated the adsorption behaviors of Rh(III) from the HNO
solution. As a result, it was found that Rh(III) is effectively adsorbed from aqueous solution containing low H
and high NO
concentration. Considering the adsorption mechanism of Rh(III), we found that Rh
in aqueous solution is adsorbed with two betaine groups in AMP03 and three NO
.
Ninomiya, Kazuhiko; Nagatomo, Takashi*; Kubo, Kenya*; Ito, Takashi; Higemoto, Wataru; Kita, Makoto*; Shinohara, Atsushi*; Strasser, P.*; Kawamura, Naritoshi*; Shimomura, Koichiro*; et al.
Bulletin of the Chemical Society of Japan, 85(2), p.228 - 230, 2012/02
Times Cited Count:13 Percentile:52.4(Chemistry, Multidisciplinary)Elemental analysis of bulk materials can be performed by detecting the high-energy X-rays emitted from muonic atoms. Muon irradiation of standard bronze samples was performed to determine the muon capture probabilities for the elemental components from muonic X-ray spectra. Nondestructive elemental analysis of an ancient Chinese coin was also performed.
Ishii, Yasuo; Toyoshima, Atsushi; Tsukada, Kazuaki; Asai, Masato; Li, Z.*; Nagame, Yuichiro; Miyashita, Sunao*; Mori, Tomotaka*; Suganuma, Hideo*; Haba, Hiromitsu*; et al.
Bulletin of the Chemical Society of Japan, 84(9), p.903 - 911, 2011/09
Times Cited Count:14 Percentile:50.57(Chemistry, Multidisciplinary)The cation-exchange behavior of element 104, rutherfordium (Rf), was investigated together with its lighter group-4 homologues Zr and Hf, and the tetravalent pseudo-homologue Th in HF/HNO mixed solution. The results demonstrate that distribution coefficients (
) of Rf in HF/0.10 M HNO
decrease with increasing concentration of the fluoride ion [F
], indicating the consecutive formation of fluorido complexes of Rf. We also measured the
values of Rf and the homologues as a function of the hydrogen ion concentration [H
]. The log
values decrease linearly with an increase of log [H
] with slopes between -2.1 and -2.5. This indicates that these elements are likely to form the same chemical compounds: mixture of [MF]
and [MF
]
(M = Rf, Zr, Hf and Th) in the studied solution. It is also ascertained that sequence in the fluoride complex formation is Zr
Hf
Rf
Th.
Haba, Hiromitsu*; Akiyama, Kazuhiko*; Tsukada, Kazuaki; Asai, Masato; Toyoshima, Atsushi; Yaita, Tsuyoshi; Hirata, Masaru; Sueki, Keisuke*; Nagame, Yuichiro
Bulletin of the Chemical Society of Japan, 82(6), p.698 - 703, 2009/06
Times Cited Count:10 Percentile:57.16(Chemistry, Multidisciplinary)Chloride complexation of the group-4 elements Zr and Hf in 8.0-11.9 M HCl is investigated by Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy to characterize chloro complexes of the transactinide element, rutherfordium (Rf). The complexes of Zr and Hf successively vary with the concentration of HCl from a hydrated complex [M(HO)
]
at 8.0 M to a hexachloro complex [MCl
]
at 11.9 M (M = Zr and Hf). The present structural changes of the Zr and Hf complexes well reflect the previously studied anion-exchange behavior of Zr and Hf in HCl. From both the EXAFS and anion-exchange results, we suggest that Rf forms the same complexes as those of Zr and Hf in HCl, and that the complexation strength of the hexachloro complexes of the group-4 elements, [MCl
]
(M = Zr, Hf, and Rf), is in the sequence of Rf
Zr
Hf.
Wada, Atsushi*; Watanabe, Masayuki; Yamanoi, Yoshinori*; Nankawa, Takuya; Namiki, Kosuke*; Yamasaki, Mikio*; Murata, Masaki*; Nishihara, Hiroshi*
Bulletin of the Chemical Society of Japan, 80(2), p.335 - 345, 2007/02
Times Cited Count:18 Percentile:44.39(Chemistry, Multidisciplinary)Lanthanide complexes with linear and cyclic octadentate oligopyridine-amine ligands were synthesized, and their molecular structures were determined by single-crystal X-ray crystallography. All of the complexes had a distorted capped square antiprism (CSAP) geometry, and the coordination environments of lanthanide complexes were more distortedfor the complexes with the linear ligand than those with the cyclic ligand. The Eu complexes with the linear ligand showed more intense emissions, which were attributed to the
D
F
transition, than the complex withthe cyclic ligand in acetonitrile, which can be attributed to the distortion in the coordination environments. These results indicate that the coordination environments of lanthanide complexes, and thus the luminescence properties, can be controlled by tuning the geometrical structures of polydentate ligands.
Hakoda, Teruyuki; Sako, Toshihiro*; Shimada, Akihiko; Ishida, Tsuneo*; Kojima, Takuji
Bulletin of the Chemical Society of Japan, 79(5), p.731 - 737, 2006/05
Times Cited Count:5 Percentile:71.71(Chemistry, Multidisciplinary)no abstracts in English
Hirota, Koichi; Kojima, Takuji
Bulletin of the Chemical Society of Japan, 78(9), p.1685 - 1690, 2005/09
Times Cited Count:7 Percentile:66.38(Chemistry, Multidisciplinary)Decomposition behavior under electron-beam irradiation was examined for polychlorinated dibenzo-p-dioxin (PCDD) and polychlorinated dibenzofuran (PCDF) isomers in incinerator gases. Significant decomposition was obtained for all PCDD isomers over the investigated absorbed doses, which was resulted from oxidation reactions with OH radicals yielded by electron-beam irradiation. In the case of PCDFs, specific isomers having symmetrical structures such as 1, 2, 8, 9-, 2, 3, 7, 8-, and 3, 4, 6, 7-TeCDFs were yielded through the dechlorination of PeCDF isomers. Thermal electrons probably played a role in the dechlorination of PeCDF isomers.
Abe, Yasuhiro*; Takigami, Machiko; Sugino, Koji*; Taguchi, Mitsumasa; Kojima, Takuji; Umemura, Tomonari*; Tsunoda, Kinichi*
Bulletin of the Chemical Society of Japan, 76(8), p.1681 - 1685, 2003/08
Times Cited Count:5 Percentile:72.28(Chemistry, Multidisciplinary)The decomposition of phenolic endocrine disrupting chemicals (P-EDCs), such as phenol, 4-butylphenol (BuP), and bisphenol A (BPA), in aqueous solutions by potassium permanganate (KMnO) was studied and its efficiency was compared with that of hydroxyl radicals (OH
) generated by
Co
-ray irradiation. Various organic acids and inorganic carbon were formed in the decomposition of P-EDCs due to either KMnO
or OH
. They were formed via direct aromatic ring cleavage in the case of KMnO
and OH
addition-substitution reactions followed by aromatic ring cleavage in the case of OH
. Comparing the decrease in the P-EDCs based on the number of electrons, the amount of KMnO
spent to completely eliminate BuP and BPA was comparable to the amount of OH
. Although three times more KMnO
was needed for phenol than OH
, the complete conversion of phenol into organic acids and inorganic carbon was achieved with 720
M of electrons in both cases.
Wakeshima, Makoto*; Ino, Kentaro*; Hinatsu, Yukio*; Ishii, Yoshinobu
Bulletin of the Chemical Society of Japan, 76(8), p.1519 - 1525, 2003/08
Times Cited Count:2 Percentile:85.99(Chemistry, Multidisciplinary)no abstracts in English
Nakada, Masami; Kitazawa, Takafumi*; Saito, Takashi*; Wang, J.*; Takeda, Masuo*; Yamashita, Toshiyuki; Saeki, Masakatsu
Bulletin of the Chemical Society of Japan, 76(7), p.1375 - 1378, 2003/07
Times Cited Count:4 Percentile:76.18(Chemistry, Multidisciplinary)no abstracts in English
Hakoda, Teruyuki; Hashimoto, Shoji; Kojima, Takuji
Bulletin of the Chemical Society of Japan, 75(10), p.2177 - 2183, 2002/10
Times Cited Count:7 Percentile:64.45(Chemistry, Multidisciplinary)no abstracts in English
Takahashi, Yoshio*; Kimura, Takaumi
Bulletin of the Chemical Society of Japan, 74(10), p.1899 - 1900, 2001/10
Times Cited Count:0 Percentile:100(Chemistry, Multidisciplinary)no abstracts in English
Hirota, Koichi; Arai, Hidehiko; Hashimoto, Shoji
Bulletin of the Chemical Society of Japan, 73(12), p.2719 - 2724, 2000/12
Times Cited Count:7 Percentile:60.37(Chemistry, Multidisciplinary)no abstracts in English
Wahyuni, S.*; Hirota, Koichi; Hakoda, Teruyuki; Arai, Hidehiko; Hashimoto, Shoji; Kawamoto, Fumio*; Mukunoki, Yasuo*
Bulletin of the Chemical Society of Japan, 73(8), p.1939 - 1943, 2000/08
Times Cited Count:2 Percentile:82.19(Chemistry, Multidisciplinary)no abstracts in English
Naganawa, Hirochika; Suzuki, Hideya; Tachimori, Shoichi; Nasu, Akinobu*; Sekine, Tatsuya*
Bulletin of the Chemical Society of Japan, 73(3), p.623 - 630, 2000/03
Times Cited Count:3 Percentile:76.43(Chemistry, Multidisciplinary)no abstracts in English