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加藤 匠馬*; 永岡 美佳; Guo, H.*; 藤田 博喜; 相田 卓*; Smith, R. L. Jr.*
Environmental Science and Pollution Research, 28(39), p.55725 - 55735, 2021/10
被引用回数:0 パーセンタイル:0(Environmental Sciences)本研究では、土壌中のSrを無添加でスクリーニングする方法の開発を目的として、模擬土壌(粘土鉱物のバーミキュライト,モンモリロナイト,カオリナイト)及び実際の土壌(照沼)に熱水浸出を行い、有機酸を生成した。安定ストロンチウム(SrCl)を土壌に吸着させ、10種類の有機酸を用いて、水熱条件下(120
200
C)での模擬土壌からのSrの溶出量を0.3Mまで評価した。ストロンチウムを吸着したバーミキュライト(Sr-V)については、0.1Mのクエン酸が150
C、1時間の処理でSrの溶出に有効であることがわかった。これらの結果をもとに、照沼土壌の有機物からの有機酸の生成について検討した。照沼土壌の水熱処理では、200
C、0.5hの反応時間で最大量の有機酸が生成された。照沼土壌からのSrの溶出の可能性を確認するために、ストロンチウムを吸着した照沼土壌(Sr-S)を調べた。Sr-Sでは、200
Cで0.5hの反応時間で水熱処理を行うと、室温でSrの40%が溶出し、土壌中のSrのスクリーニングに無添加の方法が使えることがわかった。無添加の水熱浸出法は、化学分析の第一段階で固体を焼成する必要がないため、土壌中の金属の日常的なモニタリングや緊急時の対応にも応用できる。
Yang, B.*; 恩田 裕一*; 脇山 義史*; 吉村 和也; 関本 均*; Ha, Y.*
Environmental Pollution, 208(Part B), p.562 - 570, 2016/01
被引用回数:16 パーセンタイル:50.19(Environmental Sciences)In this study, we investigated the temporal changes of radiocesium in soil, irrigation water, and rice plant in two adjacent rice paddies, with and without surface-soil-removal practice, in Fukushima Prefecture for over three years (2012 to 2014). Our results showed that radiocesium migrated into 24-28 cm soil layers and that the concentration and inventory of radiocesium in paddy soils generally decreased. The newly added radiocesium to paddies through irrigation water contributed only the maximum values of 0.15% and 0.75% of the total amount present in normal and decontaminated paddies, respectively, throughout the study period. The change trend of radiocesium concentration in suspended sediment in irrigation water exponentially decreased. Radiocesium accumulation in rice plant also decreased with time in both paddies. However, the transfer factor of radiocesium for rice plant in the decontaminated paddy increased compared with normal paddy.
Hu, P.*; 尹 永根; 石川 覚*; 鈴井 伸郎; 河地 有木; 藤巻 秀; 井倉 将人*; Yuan, C.*; Huang, J.*; Li, Z.*; et al.
Environmental Science and Pollution Research, 20(9), p.6306 - 6316, 2013/09
被引用回数:44 パーセンタイル:76.72(Environmental Sciences), a species in the family Crassulaceae, has been reported to be a Cd hyperaccumulator exhibiting fast growth, large biomass, asexual reproduction and perennial habit and showing remarkable potential in the phytoextraction of Cd from polluted soils. The aims of this study are to investigate whether and how the nitrogen form (nitrate (NO
) versus ammonium (NH
)) influences cadmium (Cd) uptake and translocation and subsequent Cd phytoextraction by the
. This is the first report of successful visualisation and quantification of Cd uptake and root-to-shoot translocation in intact plants of the hyperaccumulator species
supplied with different forms of inorganic N using positron-emitting tracer imaging system (PETIS), a real-time imaging method.
Awual, M. R.; Hossain, M. A.*; Shenashen, M. A.*; 矢板 毅; 鈴木 伸一; 城 昭典*
Environmental Science and Pollution Research, 20(1), p.421 - 430, 2013/01
被引用回数:161 パーセンタイル:97.33(Environmental Sciences)The weak-base adsorbents clarified that these are selective to arsenic(V) over competing of chloride, nitrate and sulfate anions. The solution pH played an important role in arsenic(V) removal and higher pH can cause lower adsorption capacities. Low concentration level of arsenic(V) also removed by these adsorbents even at high flow rate. Adsorbed arsenic(V) on adsorbents was quantitatively eluted with 1 M HCl acid and regenerated into hydrochloride form simultaneously for next adsorption operation after rinsing with water.
坂東 昭次; ヤマネヨシヒロ*; ムラカミユキオ*
Nuclear Techniques in Environmental Pollution, p.169 - 181, 1970/00
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