Nguyen, T. H.*; Le Ba, T.*; Tran, C. T.*; Nguyen, T. T.*; Doan, T. T. T.*; Do, V. K.; Watanabe, Masayuki; Pham, Q. M.*; Hoang, S. T.*; Nguyen, D. V.*; et al.
Hydrometallurgy, 213, p.105933_1 - 105933_11, 2022/08
A continuous counter-current extraction for the selective recovery of thorium (Th) and uranium (U) from the Yen Phu (Vietnam) rare earth concentrate leach solutions was systematically studied. The primary amine N1923 was used as an extractant which was prepared in the isoparaffin IP-2028 diluent. Thorium and uranium were selectively recovered in a hydrometallurgical circuit established by continuous mixer-settler extraction, scrubbing, and back-extraction at the laboratory scale. The desired purity of Th and U can be achieved by managing the volume ratio of organic to aqueous phase (O/A ratio) in the corresponding steps. Highly pure Th and U were recovered from the pregnant back-extraction liquor and the raffinate, respectively, which have satisfactory properties for further processing of the subsequent nuclear materials.
Matsumiya, Masahiko*; Nomizu, Daiki*; Tsuchida, Yusuke*; Sasaki, Yuji
Hydrometallurgy, 199, p.105539_1 - 105539_8, 2021/02
The synergistic solvent extraction of lanthanide(III) with mixtures of di-(2-ethylhexyl)phosphoric acid (D2EHPA, A) and monoisodecyl phosphoric acid (MIDPA, B) in phosphonium-based ionic liquid was investigated. In the case of D2EHPA or MIDPA single extractant system, Ln(III) (Ln = Pr and Nd) was extracted as [LnAHA] or [LnBHB], respectively, the extracted species of Tb(III) or Dy(III) were determined by slope analysis. According to the equilibrium constants (, and ) and the formation constants (, and ), it was found that the extracted complex [TbHAB or [DyHAB] was more stable than [LnAHA] or [LnBHB]. The synergistic extraction effects were investigated to study the possibility of separating Dy(III) from Pr(III) and Nd(III) according to their separation factors.
Sasaki, Yuji; Morita, Keisuke; Saeki, Morihisa*; Hisamatsu, Shugo; Yoshizuka, Kazuharu*
Hydrometallurgy, 169, p.576 - 584, 2017/05
The novel tridentate extractant including soft donor has developed and examined. The extractant, tetraoctyl-thiodiglycolamide (TDGA), is analogous structure to tetraoctyl-diglycolamide (TODGA) and methylimino-dioctylacetamide (MIDOA), but with sulfur donor instead of ether oxygen or nitrogen atoms of TODGA or MIDOA. From the present work, TDGA can extract silver, palladium, gold, and mercury from acidic solutions to n-dodecane. In addition to these results, the distribution ratios of hard and soft acid metals by using TDGA, TODGA, and MIDOA are compared, where the metal-complexations with each donor atom are investigated. 1H-NMR and IR studies for the metal-TDGA complexes indicate the role on donor atoms, S and N, of TDGA.
Fujimoto, Jun*; Tanaka, Kazuya; Watanabe, Naoko*; Takahashi, Yoshio*
Hydrometallurgy, 166, p.80 - 86, 2016/12
We examined recovery of REEs in Fe-Mn nodules by using (Fe-reducing bacterium). In this method, Fe-Mn nodule decomposition and REE recovery were achieved simultaneously in a single solution system. Fe-Mn nodules were reductively decomposed in NaCl solution under anaerobic conditions with daily addition of sodium lactate as an electron donor. During the decomposition of Fe-Mn nodule, REEs released from the Fe-Mn nodule were adsorbed on bacterial cells. Of the conditions studied here, the best REE adsorption rates were obtained with 0.5M NaCl solution at pH7 with daily addition of 1 mmol sodium lactate.
Sasaki, Yuji; Suzuki, Tomoya; Morita, Keisuke; Yoshizuka, Kazuharu*
Hydrometallurgy, 159, p.107 - 109, 2016/01
The novel tridentate extractant including soft donor has developed and examined. The extractant, tetraoctyl-thiodiglycolamide (S-DGA), is analogous structure to tetraoctyl-diglycolamide (TODGA), but with sulfur donor instead of ether oxygen of TODGA. S-DGA has unique property to extract silver from acidic solutions to n-dodecane with relatively high D values. We investigated the extraction behavior of Ag in various acids, HNO, HSO, and HClO.
Yu, Q.; Sasaki, Keiko*
Hydrometallurgy, 150, p.253 - 258, 2014/12
Sasaki, Keiko*; Takatsugi, Koichiro*; Kaneko, Kenji*; Kozai, Naofumi; Onuki, Toshihiko; Tuovinen, O. H.*; Hirajima, Tsuyoshi*
Hydrometallurgy, 104(3-4), p.424 - 431, 2010/10
no abstracts in English