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Journal Articles

Synergistic solvent extraction of lanthanide ions with mixtures of D2EHPA and MIDPA in phosphonium-based ionic liquids

Matsumiya, Masahiko*; Nomizu, Daiki*; Tsuchida, Yusuke*; Sasaki, Yuji

Hydrometallurgy, 199, p.105539_1 - 105539_8, 2021/02

 Times Cited Count:0 Percentile:0(Metallurgy & Metallurgical Engineering)

The synergistic solvent extraction of lanthanide(III) with mixtures of di-(2-ethylhexyl)phosphoric acid (D2EHPA, A) and monoisodecyl phosphoric acid (MIDPA, B) in phosphonium-based ionic liquid was investigated. In the case of D2EHPA or MIDPA single extractant system, Ln(III) (Ln = Pr and Nd) was extracted as [LnA$$_{3}$$HA] or [LnB$$_{3}$$HB], respectively, the extracted species of Tb(III) or Dy(III) were determined by slope analysis. According to the equilibrium constants ($$K_{rm A}$$, $$K_{rm B}$$ and $$K_{rm AB}$$) and the formation constants ($$beta_{1}$$, $$beta_{1}$$ and $$beta_{3}$$), it was found that the extracted complex [TbHA$$_{2}$$B$$_{2}$$ or [DyHA$$_{2}$$B$$_{2}$$] was more stable than [LnA$$_{3}$$HA] or [LnB$$_{3}$$HB]. The synergistic extraction effects were investigated to study the possibility of separating Dy(III) from Pr(III) and Nd(III) according to their separation factors.

Journal Articles

Precious metal extraction by N,N,N',N'-tetraoctyl-thiodiglycolamide and its comparison with N,N,N',N'-tetraoctyl-diglycolamide and methylimino-N,N'-dioctylacetamide

Sasaki, Yuji; Morita, Keisuke; Saeki, Morihisa*; Hisamatsu, Shugo; Yoshizuka, Kazuharu*

Hydrometallurgy, 169, p.576 - 584, 2017/05

 Times Cited Count:11 Percentile:57.36(Metallurgy & Metallurgical Engineering)

The novel tridentate extractant including soft donor has developed and examined. The extractant, tetraoctyl-thiodiglycolamide (TDGA), is analogous structure to tetraoctyl-diglycolamide (TODGA) and methylimino-dioctylacetamide (MIDOA), but with sulfur donor instead of ether oxygen or nitrogen atoms of TODGA or MIDOA. From the present work, TDGA can extract silver, palladium, gold, and mercury from acidic solutions to n-dodecane. In addition to these results, the distribution ratios of hard and soft acid metals by using TDGA, TODGA, and MIDOA are compared, where the metal-complexations with each donor atom are investigated. 1H-NMR and IR studies for the metal-TDGA complexes indicate the role on donor atoms, S and N, of TDGA.

Journal Articles

Simultaneous recovery and separation of rare earth elements in ferromanganese nodules by using ${{it Shewanella putrefaciens}}$

Fujimoto, Jun*; Tanaka, Kazuya; Watanabe, Naoko*; Takahashi, Yoshio*

Hydrometallurgy, 166, p.80 - 86, 2016/12

 Times Cited Count:5 Percentile:32.77(Metallurgy & Metallurgical Engineering)

We examined recovery of REEs in Fe-Mn nodules by using ${{it Shewanella putrefaciens}}$ (Fe-reducing bacterium). In this method, Fe-Mn nodule decomposition and REE recovery were achieved simultaneously in a single solution system. Fe-Mn nodules were reductively decomposed in NaCl solution under anaerobic conditions with daily addition of sodium lactate as an electron donor. During the decomposition of Fe-Mn nodule, REEs released from the Fe-Mn nodule were adsorbed on bacterial cells. Of the conditions studied here, the best REE adsorption rates were obtained with 0.5M NaCl solution at pH7 with daily addition of 1 mmol sodium lactate.

Journal Articles

Silver extraction by $$N,N,N',N'$$-tetraoctyl-thiodiglycolamide

Sasaki, Yuji; Suzuki, Tomoya; Morita, Keisuke; Yoshizuka, Kazuharu*

Hydrometallurgy, 159, p.107 - 109, 2016/01

 Times Cited Count:5 Percentile:32.77(Metallurgy & Metallurgical Engineering)

The novel tridentate extractant including soft donor has developed and examined. The extractant, tetraoctyl-thiodiglycolamide (S-DGA), is analogous structure to tetraoctyl-diglycolamide (TODGA), but with sulfur donor instead of ether oxygen of TODGA. S-DGA has unique property to extract silver from acidic solutions to n-dodecane with relatively high D values. We investigated the extraction behavior of Ag in various acids, HNO$$_{3}$$, H$$_{2}$$SO$$_{4}$$, and HClO$$_{4}$$.

Journal Articles

In situ X-ray diffraction investigation of the evolution of a nanocrystalline lithium-ion sieve from biogenic manganese oxide

Yu, Q.; Sasaki, Keiko*

Hydrometallurgy, 150, p.253 - 258, 2014/12

 Times Cited Count:8 Percentile:39.73(Metallurgy & Metallurgical Engineering)

Journal Articles

Characterization of secondary arsenic-bearing precipitates formed in the bioleaching of enargite by $$Acidithiobacillus ferrooxidans$$

Sasaki, Keiko*; Takatsugi, Koichiro*; Kaneko, Kenji*; Kozai, Naofumi; Onuki, Toshihiko; Tuovinen, O. H.*; Hirajima, Tsuyoshi*

Hydrometallurgy, 104(3-4), p.424 - 431, 2010/10

 Times Cited Count:19 Percentile:69.02(Metallurgy & Metallurgical Engineering)

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