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Ito, Kengo*; Takahashi, Shin*; Kato, Chizu*; Fukutani, Satoshi*; Matsumura, Tatsuro; Fujii, Toshiyuki*
Journal of Radioanalytical and Nuclear Chemistry, 334, p.2467 - 2475, 2025/02
Times Cited Count:0 Percentile:0.00(Chemistry, Analytical)In this study, the solvent extraction behavior of tin (Sn), specifically Sn, from high-level radioactive waste was evaluated using six different extractants in a HNO
system. Among the tested extractants, N,N-Didodecyl-2-hydroxyacetoamide (HAA) exhibited higher efficiency, still not sufficient for industrial implementation. In systems where HCl was added to HNO
, both tributyl phosphate (TBP) and N,N,N,N'-tetra-2-ethylhexyl diglycolamide (TEHDGA) achieved D
values greater than 1 at
1 M HCl. However, due to practical challenges in industrial applications, HAA extraction in HNO
systems, particularly at low Sn concentrations (0.0008 M), may provide a more effective solution for Sn recovery.
Shimada, Asako; Tsukahara, Takehiko*; Nomura, Masao*; Takeda, Seiji
Journal of Radioanalytical and Nuclear Chemistry, 333(12), p.6297 - 6310, 2024/12
Times Cited Count:0 Percentile:0.00(Chemistry, Analytical)Ito, Kengo*; Kawakami, Takahiro*; Kato, Chizu*; Fukutani, Satoshi*; Matsumura, Tatsuro; Fujii, Toshiyuki*
Journal of Radioanalytical and Nuclear Chemistry, 333(10), p.5183 - 5189, 2024/10
Times Cited Count:1 Percentile:62.55(Chemistry, Analytical)Solvent extraction behaviors of Se (VI) from nitric acid solutions were investigated with multiple extractants used for uranium, plutonium, minor actinides, and rare earthelements separation processes from high-level liquid waste. During the processes, Se remained in the residual aqueous solutions, as all extractants showed distributionratios 1. In contrast, Se showed distribution ratios
1 with
-phenylenediamine in dilute nitric acid (
2 M HNO
), octanol as the organic phase, and concentrated nitric acid (8 M HNO
) for back extraction, suggesting a potential new single separation process and recovery of Se.
Kimura, Yoshiki; Matsumoto, Tetsuya*; Yamaguchi, Tomoki
Journal of Radioanalytical and Nuclear Chemistry, 333(7), p.3541 - 3551, 2024/07
Times Cited Count:0 Percentile:0.00(Chemistry, Analytical)Ninomiya, Kazuhiko*; Kubo, Kenya*; Inagaki, Makoto*; Yoshida, Go*; Takeshita, Soshi*; Tampo, Motonobu*; Shimomura, Koichiro*; Kawamura, Naritoshi*; Strasser, P.*; Miyake, Yasuhiro*; et al.
Journal of Radioanalytical and Nuclear Chemistry, 333(7), p.3445 - 3450, 2024/07
Times Cited Count:1 Percentile:62.55(Chemistry, Analytical)Arai, Yoichi; Hasegawa, Kenta; Watanabe, So; Watanabe, Masayuki; Minowa, Kazuki*; Matsuura, Haruaki*; Hagura, Naoto*; Katsuki, Kenta*; Arai, Tsuyoshi*; Konishi, Yasuhiro*
Journal of Radioanalytical and Nuclear Chemistry, 333(7), p.3585 - 3593, 2024/07
Times Cited Count:1 Percentile:27.70(Chemistry, Analytical)Hu, X.*; Fujita, Yoshitaka; Tsuchiya, Kunihiko; Fukutani, Satoshi*; Hori, Junichi*; Suzuki, Tatsuya*
Journal of Radioanalytical and Nuclear Chemistry, 333(11), p.6057 - 6063, 2024/05
Times Cited Count:0 Percentile:0.00(Chemistry, Analytical)no abstracts in English
Tatsuno, Takahiro*; Yoshimura, Kazuya; Nihei, Naoto*
Journal of Radioanalytical and Nuclear Chemistry, 333(3), p.1089 - 1096, 2024/03
Times Cited Count:0 Percentile:0.00(Chemistry, Analytical)Sasaki, Yuto; Maeda, Shigetaka
Journal of Radioanalytical and Nuclear Chemistry, 333, p.5987 - 5996, 2024/02
Times Cited Count:0 Percentile:0.00(Chemistry, Analytical)Researchers are seeking alternative Ac production methods because of the scarcity of
Ac for targeted alpha therapy. Although
Ra from waste sources has been considered, obtaining
Ra is challenging. Therefore, the authors focused on the contamination of minerals with
Th-derived
Ra while investigating methods to recover
Ra from uranium ores. The effect of 228Ra contamination on
Ac production by
Ra transmutation using fast reactors was evaluated. Consequently, toxic
Ac contaminates
Ac. However, using the different half-lives of
Ac and
Ac, pure
Ac can be obtained from the chemical separation of actinium after cooling for 5-8 days.
Quach, N. M.*; Ngo, M. C.*; Yang, Y.*; Nguyen, T. B.*; Nguyen, V. T.*; Fujita, Yoshitaka; Do, T. M. D.*; Nakayama, Tadachika*; Suzuki, Tatsuya*; Suematsu, Hisayuki*
Journal of Radioanalytical and Nuclear Chemistry, 332(10), p.4057 - 4064, 2023/10
Times Cited Count:3 Percentile:65.16(Chemistry, Analytical)Technetium-99m (Tc) is the most widely used medical radioisotope in the world and is produced from molybdenum-99 (
Mo). Production of
Mo via the neutron capture method draws attention as an alternative to fission-derived
Mo due to non-proliferation issues, but the specific radioactivity of
Mo is extremely low. In this work, a porous
-MoO
wire was prepared as an irradiation target in order to improve the specific activity by extracting
Mo. Porous
-MoO
wire is synthesized from Mo metal wire by a two-step heating procedure. The hot atom effect of
Mo was confirmed by activity and isotope measurements of the porous
-MoO
wire after neutron irradiation and the water used for extraction. In term of the extraction effectiveness, the effectiveness of
Mo extraction in the porous
-MoO
wire was comparable to that of commercial
-MoO
powder.
Maeda, Makoto; Segawa, Mariko; Toh, Yosuke; Endo, Shunsuke; Nakamura, Shoji; Kimura, Atsushi
Journal of Radioanalytical and Nuclear Chemistry, 332(8), p.2995 - 2999, 2023/08
Times Cited Count:0 Percentile:0.00(Chemistry, Analytical)Tatsuno, Takahiro*; Nihei, Naoto*; Yoshimura, Kazuya; Ote, Nobuhito*
Journal of Radioanalytical and Nuclear Chemistry, 332(6), p.1677 - 1686, 2023/06
Times Cited Count:1 Percentile:27.70(Chemistry, Analytical)Hidaka, Akihide
Journal of Radioanalytical and Nuclear Chemistry, 332(6), p.1607 - 1623, 2023/03
Times Cited Count:0 Percentile:0.00(Chemistry, Analytical)no abstracts in English
Kinoshita, Norikazu*; Noto, Takuma*; Nakajima, Hitoshi*; Kosako, Kazuaki*; Kato, Takahiro*; Kuroiwa, Yoichi*; Kurabe, Misako*; Sasaki, Yuki*; Torii, Kazuyuki*; Maeda, Makoto; et al.
Journal of Radioanalytical and Nuclear Chemistry, 332(2), p.479 - 486, 2023/02
Times Cited Count:2 Percentile:27.70(Chemistry, Analytical)Hayashi, Hirokazu; Shibata, Hiroki; Sato, Takumi; Otobe, Haruyoshi
Journal of Radioanalytical and Nuclear Chemistry, 332(2), p.503 - 510, 2023/02
Times Cited Count:0 Percentile:0.00(Chemistry, Analytical)The formation of MPd (M = Gd, Np) by the reaction of MN with Pd at 1323 K in Ar gas flow was observed. Cubic AuCu
-type GdPd
(
= 0.4081
0.0001 nm) and NpPd
(
= 0.4081
0.0001 nm) were identified, respectively. The product obtained from the reaction of NpN with Pd contained additional phases including the hexagonal TiNi
-type NpPd
. Chlorination of the MPd
(M = Gd, Np) samples was accomplished by the solid-state reaction using cadmium chloride at 673 K in a dynamic vacuum. Pd-rich solid solution phase saturated with Cd and an intermetallic compound PdCd were obtained as by-products of MCl
formation.
Do, V. K.; Furuse, Takahiro; Ota, Yuki; Iwahashi, Hiroyuki; Hirosawa, Takashi; Watanabe, Masahisa; Sato, Soichi
Journal of Radioanalytical and Nuclear Chemistry, 331(12), p.5631 - 5640, 2022/12
Times Cited Count:4 Percentile:54.60(Chemistry, Analytical)Sn is one of the long-lived fission products that might have been released into the environment after the Fukushima nuclear accident in Japan in 2011. The presence of radionuclides must be monitored for the proper treatment of wastes obtained from decommissioning accident-related nuclear facilities and the surrounding environment. In the work, we propose a reliable method for verifying the presence of
Sn in construction materials by combining the HCl-free solid phase extraction on TEVA resin and a selective measurement by inductively coupled plasma tandem mass spectrometry (ICP-MS/MS). The method has been optimized and characterized step by step. More than 95% of chemical recovery was achieved for Sn from typical concrete matrixes. The interference caused by an isobar
Te and possible polyatomic interferences from matrixes were effectively suppressed by the developed chemical separation and the tandem MS/MS configuration. The total decontamination factor for the Te interference was of the order of 10
. The estimated method detection limit for
Sn in concrete as measured at m/z = 160 was 12.1 pg g
, which is equivalent to 6.1 mBq g
.
Akuzawa, Tadashi*; Kim, S.-Y.*; Kubota, Masahiko*; Wu, H.*; Watanabe, So; Sano, Yuichi; Takeuchi, Masayuki; Arai, Tsuyoshi*
Journal of Radioanalytical and Nuclear Chemistry, 331(12), p.5851 - 5858, 2022/12
Times Cited Count:5 Percentile:63.07(Chemistry, Analytical)Hagiwara, Hiroki; Kondo, Keietsu; Hidaka, Akihide
Journal of Radioanalytical and Nuclear Chemistry, 331(12), p.5905 - 5914, 2022/12
Times Cited Count:3 Percentile:44.16(Chemistry, Analytical)Liu, J.; Dotsuta, Yuma; Sumita, Takehiro; Kitagaki, Toru; Onuki, Toshihiko; Kozai, Naofumi
Journal of Radioanalytical and Nuclear Chemistry, 331(6), p.2785 - 2794, 2022/06
Times Cited Count:4 Percentile:54.60(Chemistry, Analytical)Remnant nuclear fuel debris in the damaged nuclear reactors at the Fukushima Daiichi Nuclear Power Plant (FDNPP) has contacted the groundwater containing microorganisms for over ten years. Herein, we report the possibility of bacterial alteration of fuel debris. We investigated the physical and chemical changes of fuel debris simulants (FDS) in the powder and pellet forms via exposure to two ubiquitous bacteria, Pseudomonas fluorescens and Bacillus subtilis. In the experiments using FDS composed of the powders of Fe(0), solid solution of CeO and ZrO
, and SiO
, Ce, Zr, and Si were hardly dissolved, while Fe was dissolved, a fraction of the dissolved Fe was present in the liquid phase as Fe(II) and Fe(III), and the rest was precipitated as the nano-sized particles of iron (hydr)oxides. In the experiment using P. fluorescens and FDS pellet pieces prepared by melting the Fe(0) particles and solid solution of CeO
and ZrO
, the bacteria selectively gathered on the Fe(0) particle surface and made corrosion pits. These results suggest that bacteria in groundwater corrode the iron in fuel debris at FDNPP, change fuel debris into porous one, releasing the nano-sized iron (hydr)oxide particles into the water.
Nomizu, Daiki; Sasaki, Yuji; Kaneko, Masashi; Matsumiya, Masahiko*; Katsuta, Shoichi*
Journal of Radioanalytical and Nuclear Chemistry, 331(3), p.1483 - 1493, 2022/03
Times Cited Count:7 Percentile:75.64(Chemistry, Analytical)We studied the successive formation of water soluble DGA (diglycolamide) and DOODA (dioxaoctanediamide) for the mutual separation of Ln in this extraction system. TODGA (tetraoctyl-diglycolamide) and DOODA(C8) (tetraoctyl-dioxaoctanediamide) have the opposite trend to extract light and heavy Ln through Ln-patterns. Metal-complexes of two folding Ln ions with water-soluble DOODA and three folding with DGA are found and their observed formation constants are calculated. The suitable separation condition (aqueous phase: 30 mM DOODA(C2) in 1 M nitric acid, organic phase: 0.1 M TODGA in n-dodecane) of multi-stage extraction (10 10) is conducted. From the present work, it is clear that La, Pr and Nd are mainly present in aqueous phase, instead Sm-Dy exist in the organic phase.