Effects of hydrophilic groups of polymer on change in hydrogen-bonding structure of water in hydrogels during dehydration

Sugiyama, Hitoshi*; Kato, Kenichi*; Sekine, Naoko*; Sekine, Yurina; Watanabe, Tomoaki*; Fukazawa, Tomoko*

Chemical Physics Letters, 856, p.141655_1 - 141655_8, 2024/12

https://doi.org/10.1016/j.cplett.2024.141655

To investigate the effects of polymer hydrophilicity on structures of water in hydrogels, differential scanning calorimetry and X-ray diffraction measurements were performed. The results show that the amount of intermediate water in polyacrylamide (PAA) hydrogel is about 12% smaller than that in poly--dimethylacrylamide (PDMAA) hydrogel. Furthermore, it was found that the bound water in PAA hydrogel primarily exists around the surface of the polymer bundles, whereas that in PDMAA hydrogel acts as a crosslinker factor for dehydration and water absorption in hydrogels.

Electric field-induced nonreciprocal spin current due to chiral phonons in chiral-structure superconductors

Yao, D.*; Matsuo, Mamoru; Yokoyama, Takehito*

Applied Physics Letters, 124(16), p.162603_1 - 162603_5, 2024/04

https://doi.org/10.1063/5.0207915

Inelastic neutron scattering study of magnon excitation by ultrasound injection in yttrium iron garnet

Shamoto, Shinichi; Akatsu, Mitsuhiro*; Chang, L.-J.*; Nemoto, Yuichi*; Ieda, Junichi

Applied Physics Letters, 124(11), p.112402_1 - 112402_5, 2024/03

https://doi.org/10.1063/5.0189768

The magnon excitation by ultrasound injection in YFeO is studied by inelastic neutron scattering. Both longitudinal and transverse ultrasound injections enhanced the inelastic neutron scattering intensity.

Revealing the role of high-valence elementary substitution in the hydrogen-induced Mottronic transitions of vanadium dioxide

Zhou, X.*; Fukutani, Katsuyuki; 9 of others*

Applied Physics Letters, 124(8), p.082103_1 - 082103_7, 2024/02

https://doi.org/10.1063/5.0189271

Elucidation of solid particle interfacial phenomena in liquid sodium; Magnetic interactions on liquid metal and solid atoms at the solid interface

Tei, C.; Otaka, Masahiko; Kuwahara, Daisuke*

Chemical Physics Letters, 829, p.140755_1 - 140755_6, 2023/10

https://doi.org/10.1016/j.cplett.2023.140755

We were able to detect the nuclear magnetic resonance (NMR) signal of a liquid sodium clinging to the interface of solid metal particles for the first time. In this study, we confirmed the difference in the relaxation times due to the difference in the interactions between liquid sodium and metal particles suspended in the liquid sodium. It was found that the surface of the micro titanium particles and liquid metallic sodium interact physically, not chemically.

Step unbunching phenomenon on 4H-SiC (0001) surface during hydrogen etching

Sakakibara, Ryotaro*; Bao, J.*; Yuhara, Keisuke*; Matsuda, Keita*; Terasawa, Tomoo; Kusunoki, Michiko*; Norimatsu, Wataru*

Applied Physics Letters, 123(3), p.031603_1 - 031603_4, 2023/07

https://doi.org/10.1063/5.0153565

We here report a step unbunching phenomenon, which is the inverse of the phenomenon of step bunching. When a 4H-SiC (0001) surface is annealed at a high temperature, step bunching arises due to the different velocities of the step motion in adjacent steps, resulting in steps with a height of more than several nanometers. We found that the bunched steps, thus, obtained by hydrogen etching in an Ar/H atmosphere were "unbunched" into lower height steps when annealed subsequently at lower temperatures. This unbunching phenomenon can be well explained by the consequence of the competition between energetics and kinetics. Our findings provide another approach for the surface smoothing of SiC by hydrogen etching and may give significant insight into the application of SiC power devices and two-dimensional materials growth techniques in general.

Work function lowering of LaB by monolayer hexagonal boron nitride coating for improved photo- and thermionic-cathodes

Yamaguchi, Hisato*; Yusa, Ryunosuke*; Wang, G.*; Pettes, M. T.*; Liu, F.*; Tsuda, Yasutaka; Yoshigoe, Akitaka; Abukawa, Tadashi*; Moody, N. A.*; Ogawa, Shuichi*

Applied Physics Letters, 122(14), p.141901_1 - 141901_7, 2023/04

https://doi.org/10.1063/5.0142591

A lowering of work function for LaB by monolayer hexagonal BN coating is reported. Photoemission electron microcopy (PEEM) and thermionic emission electron microscopy (TEEM) both revealed that the hBN coated region of a LaB(100) single crystal has lower work function compared to the bare (i.e., non-coated) and graphene coated regions. A larger decrease of work function for the hBN coated LaB(100) compared to graphene coated LaB(100) was qualitatively supported by our density functional theory (DFT) calculations. Adding an oxide layer in the calculations improved consistency between the calculation and experimental results. We followed up our calculations with synchrotron-radiation X-ray photoelectron spectroscopy (SR-XPS) and confirmed the presence of an oxide layer on our LaB.

Thermal stability of non-collinear antiferromagnetic MnSn nanodot

Sato, Yuma*; Takeuchi, Yutaro*; Yamane, Yuta*; Yoon, J.-Y.*; Kanai, Shun*; Ieda, Junichi; Ohno, Hideo*; Fukami, Shunsuke*

Applied Physics Letters, 122(12), p.122404_1 - 122404_5, 2023/03

https://doi.org/10.1063/5.0135709

Spin motive force induced by parametric excitation

Hoshi, Kojiro*; Hioki, Tomosato*; Saito, Eiji

Applied Physics Letters, 121(21), p.212404_1 - 212404_6, 2022/11

https://doi.org/10.1063/5.0129466

Laser-fluence dependence of resonance-enhanced multiphoton reduction of trivalent europium

Matsuda, Shohei; Nakashima, Nobuaki*; Yokoyama, Keiichi; Taniguchi, Seiji*; Chosrowjan, H.*; Somekawa, Toshihiro*; Yatsuhashi, Tomoyuki*

Chemical Physics Letters, 802, p.139759_1 - 139759_6, 2022/09

https://doi.org/10.1016/j.cplett.2022.139759

no abstracts in English