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論文

Expansion control for cementation of incinerated ash

中山 卓也; 鈴木 眞司; 花田 圭司; 富岡 修; 佐藤 淳也; 入澤 啓太; 加藤 潤; 川戸 喜実; 目黒 義弘

Proceedings of 2nd International Symposium on Cement-based Materials for Nuclear Wastes (NUWCEM 2014) (CD-ROM), 12 Pages, 2014/06

A method, in which incinerated ash is solidified with a cement material, has been developed to dispose of radioactive incinerated ash waste. A small amount of metallic Al, which was not oxidized in the incineration, existed in the ash. When such ash was kneaded with a cement material and water, H$$_{2}$$ generation began immediately just after the kneading, H$$_{2}$$ bubbles pushed up the kneaded muddy material and an expanded solidified form was obtained. In this study, we tried to control H$$_{2}$$ generation by means of following two methods, one was a method to let metallic Al react prior to the cementation and the other was a method to add an expansion inhibitor that made an oxide film on the surface of metallic Al. The solidified forms prepared using the pre-treated ash and lithium nitrite were not expanded.

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