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Yamamoto, Masahiro; Soma, Yasutaka; Igarashi, Takahiro; Ueno, Fumiyoshi
Proceedings of Annual Congress of the European Federation of Corrosion (EUROCORR 2018) (USB Flash Drive), 7 Pages, 2018/09
In order to clarify the SCC behavior of SUS316L under BWR environment, mass transfer inside crevice of SUS316L in high temperature water using various crevice gap samples was investigated. The samples were prepared by put together two SUS316L sheets. Crevice gap differs from 0.005 mm to 0.1 mm. Corrosion tests were conducted in 8 ppm dissolved oxygen (DO) conditions. Surface oxide film was analysed by laser Raman spectroscopy (LRS) after immersion. Numerical simulations were also conducted by using COMSOL Maltiphysics. Diffusion process of DO and the other chemical species were calculated with connected to electrochemical process. Electrical conductivities inside the crevice were 100 times larger than these of outer water. The reason of high conductivity is existence of Fe
ions at the DO depletion crevice.
Nemoto, Yoshiyuki; Kaji, Yoshiyuki; Onizawa, Takashi*; Kanazawa, Toru*; Nakashima, Kazuo*; Tojo, Masayuki*
Proceedings of Annual Congress of the European Federation of Corrosion (EUROCORR 2018) (USB Flash Drive), 8 Pages, 2018/09
The authors proposed oxidation models based on oxidation data which previously obtained in high temperature oxidation tests on small sample of Zircalloy-2 (Zry2) cladding in dry air and in air/steam mixture environment. The oxidation models were implemented in computational fluid dynamics (CFD) code to analyse oxidation behavior of long cladding sample in hypothetical spent fuel pool (SFP) accident conditions. The oxidation tests were conducted using Zry2 cladding sample 500 mm in length. The oxide layer growth in dry air was well reproduced in the calculation using the oxidation model, meanwhile which in air/steam mixture was overestimated atmosphere composition change anticipated in the spent fuel rack during the accident, and its influence on the oxidation behaviour of the cladding were discussed in consideration of the oxidation model improvement.