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論文

Sorption behavior of niobium onto clay minerals in the presence of Ca

大平 早希; 飯田 芳久

Proceedings of Waste Management Symposia 2023 (WM2023) (Internet), 10 Pages, 2023/02

ニオブ-94(Nb-94)の鉱物への収着分配係数(${it K}$d)は、放射性廃棄物処分の安全評価において重要なパラメータの一つである。先行研究で、アルカリ条件下におけるNbの${it K}$dは、Caの存在下で、Naの存在下よりも2桁高い値が報告されていた。本研究では、粘土鉱物へのNb収着に対するCaの影響を再検討するためにNb収着実験を行い、沈殿生成の有無を確認するためにブランクテストを行った。その結果、モンモリロナイトとイライトへのNb収着は、Ca濃度には依存せず、Ca存在下で得られた${it K}$d値はCa非存在下での値と同じであることが分かった。鉱物表面での錯形成による収着を仮定した収着モデルを構築し、地球化学計算コードを用いて計算を行った。その結果、表面種X_ONb(OH)$$_{4}$$とX_ONb(OH)$$_{5}$$$$^{-}$$を用いたモデルにより、得られたデータの傾向を再現可能なことを確認した。

論文

LASSO reconstruction scheme to predict radioactive source distributions inside reactor building rooms; Theory & demonstration

Shi, W.*; 町田 昌彦; 山田 進; 吉田 亨*; 長谷川 幸弘*; 岡本 孝司*

Proceedings of Waste Management Symposia 2023 (WM2023) (Internet), 8 Pages, 2023/02

Clarifying hot spots of radioactive sources inside reactor building rooms based on monitoring air dose rates is one of the most essential steps in decommissioning of nuclear power plants. However, the attempt is regarded as a rather difficult task, because information obtained by air dose rate measurements is generally not enough to inversely estimate contaminated distribution among a tremendous number of potential distributions inside complex reactor building rooms as far as one uses the conventional ways. Then, in order to successfully perform the inverse estimations on source distributions even in such ill-posed circumstances, we suggest that a machine learning method, least absolute shrinkage and selection operator (LASSO) is a promising scheme. Subsequently, we construct a simple room model and employ Monte Carlo simulation code, Particle and Heavy Ion Transport Systems (PHITS) to numerically test feasibility of LASSO inverse estimation scheme. Consequently, we confirm high reconstruction performance of the LASSO scheme in successfully predicting radioactive source distributions. In addition, we carry out uncertainty analysis for the inverse estimation and derive an error function describing uncertainty of the inverse estimation as a useful error estimator. Finally, we find that additional use of spectral information in the measurements can significantly decrease the number of measurement points for the present inverse estimation. In conclusion, LASSO scheme is a quite useful way to explore radioactive hot spots toward the future decommissioning of nuclear power plants.

論文

LASSO reconstruction scheme to predict radioactive source distributions inside reactor building rooms; Practical applications

町田 昌彦; Shi, W.*; 山田 進; 宮村 浩子; 吉田 亨*; 長谷川 幸弘*; 岡本 孝司; 青木 勇斗; 伊藤 倫太郎; 山口 隆司; et al.

Proceedings of Waste Management Symposia 2023 (WM2023) (Internet), 11 Pages, 2023/02

In order to find radioactive hot spots inside reactor building rooms from structural data together with air dose rate measurement data, Least Absolute Shrinkage and Selection Operator (LASSO) has been recently suggested as a promising scheme. The scheme has been examined in simplified room models and its high estimation feasibility has been confirmed by employing Particle and Heavy Ion Transport code System (PHITS) as a radiation simulation code. In this paper, we apply the scheme to complex room models inside real reactor buildings. The target rooms are pool canal circulation system room and main circulation system room in Japan Materials Testing Reactor (JMTR) at Oarai area, Japan Atomic Energy Agency (JAEA). In these real rooms, we create STL format structural data based on Computer Aided Design (CAD) models made directly from their point group data measured by laser scanning devices, and we notice that the total number of their surface meshes in these real rooms reaches to the order of 1 million. Then, this order of the mesh number clearly indicates that one needs a simplified radiation simulation code considering only direct transmission of gamma ray as a radiation calculation instead of PHITS demanding high computational costs. By developing such a simplified code and customizing it to perform LASSO scheme, we consequently confirm that LASSO scheme driven by the simplified simulation can also successfully predict unknown radioactive hot spots on real structural models.

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