Zairyo To Kankyo, 70(12), p.468 - 473, 2021/12
In order to estimate corrosive environment in the contaminated water at Fukushima Daiichi Nuclear Power Station, effects of oxidants, such as HO, which were generated from water radiolysis, should be taken into account due to the irradiation field in the reactor building. The process of water radiolysis and the amounts of these oxidants can change depending on the conditions of water and types of radiation. After the accident, a variety of factors, which can affect water radiolysis, such as seawater constituents, surface of oxides, and -radionuclides, had been discussed. In this paper, these effects on radiolysis are reviewed for the better understanding of the corrosive environment in the contaminated water.
Ishijima, Yasuhiro; Ueno, Fumiyoshi; Abe, Hitoshi
Zairyo To Kankyo, 70(6), p.192 - 198, 2021/06
The time dependence of corrosion behavior on tantalum used in nuclear fuel reprocessing equipment in sodium hydroxide solution was investigated by immersion corrosion tests, and the mechanism of aging change was discussed from surface observations and electrochemical measurements. The immersion tests were carried out at room temperature with NaOH concentrations ranging from 1 to 7 mol/L and immersion times ranging from 24 to 168 hr, respectively. The corrosion rate increased with NaOH concentration, but peaked with immersion time and then decreased. The time to peak of corrosion rate was shorter with higher NaOH concentration. The SEM observations and Raman analysis at the surface of the specimens that were cleaned and weighed after the immersion test did not show any film formation. On the other hand, the polarization resistance showed a constant value or an increase after a decrease immediately after immersion. It is suggested that the change in corrosion rate is affected by the formation of film by immersion, since the value of polarization resistance is almost the same as the sum of film resistance and charge transfer resistance. The film was considered to be mainly NaTaO formed by the dissolution of Ta.
Sato, Junya; Shiota, Kenji*; Takaoka, Masaki*
Zairyo, 70(5), p.406 - 411, 2021/05
An aluminosilicate solid is an inorganic material that has the property of immobilizing heavy metals or radionuclides in the matrix. In this study, aluminosilicates with a Si/Al molar ratio of 0.5 was synthesized from a chemical reagent in order to produce aluminosilicate solids with a low Si/Al molar ratio, which were expected to improve the immobilization of heavy metals and radionuclides contained in the matrix. The synthesized Si-Al gel with a Si/Al molar ratio of 0.5 had little impurity content and was in an amorphous phase. In addition, the compressive strength of the aluminosilicate solid produced by the synthesized Si-Al gel showed a 5 MPa or more, confirming that it can be used as a raw material for aluminosilicate solids. The aluminosilicate solid with a Si/Al molar ratio of 1.25 had a dense surface structure from the result of BSE images and had the highest compressive strength among all samples.
Hirota, Noriaki; Takeda, Kiyoko*; Tachibana, Yukio; Masaki, Yasuhiro*
Zairyo To Kankyo, 70(3), p.68 - 76, 2021/03
Corrosion resistance of stainless steels and Ni-based alloys were evaluated in a sulfuric acid decomposition gas at high temperature. The evaluation were carried out in an environment simulated in the sulfuric acid decomposition reaction vessel for thermochemical hydrogen production process (IS process). Their corrosion films were also analyzed for better understanding of the corrosion behavior. As a result, after 100 hour corrosion test, Ni-based alloy containing 2.4% Si showed good corrosion resistance. Ferritic stainless steel containing 3% Al (3Al-Ferrite) showed better corrosion resistance. Its corrosion rate was lower than that of SiC (0.1mm/year), which is a candidate material for the sulfuric acid decomposition reaction vessel. On the other hand, Ni-based alloy pre-filmed with AlO is prepared as the relative corrosion film of 3Al-Ferrite. Its corrosion rate was significantly higher than that of 3Al-Ferrite. As the result of EPMA analysis of these oxide films, Ni-based alloy containing 2.4% Si formed Si oxide film which had some cracks after the long term corrosion test. Therefore S penetrated into grain boundaries of the matrix through the oxide film. 3Al-Ferrite formed a thin and uniform AlO film, and the penetration of S into the grain boundaries was not observed. AlO pre-film of Ni-based alloy also showed S penetration in the matrix because the AlO pre-film had many small defects originally. The corrosion oxide film of 3Al-Ferrite consisted of only -AlO, while the AlO pre-film consist of -AlO and -AlO. Those results suggest that the better corrosion resistance of 3Al-Ferrite is due to the uniform formation of dense -AlO film at the early stage of the corrosion.
Otani, Kyohei; Tsukada, Takashi; Ueno, Fumiyoshi; Kato, Chiaki
Zairyo To Kankyo, 69(9), p.246 - 252, 2020/09
The purpose of this study was to investigate the effect of artificial sea water concentration on the corrosion rate of carbon steel under air/solution alternating condition, and to clarify the corrosion mechanism of carbon steel that changes with artificial seawater concentration. Mass measurements showed that the corrosion rate of carbon steel in the alternating condition accelerates with increasing concentration in the concentration region between deionized water to 200 times diluted artificial seawater (ASW), and the corrosion rate decreases with increasing concentration in the concentration region between 20 times diluted ASW to undiluted ASW. It can be considered that the reason why the carbon steel corrosion was suppressed in highly concentrated artificial seawater would Mg ions and Ca ions in the artificial seawater precipitate and cover on the surface due to the increase in pH near the surface by oxygen reduction reaction.
Zairyo To Kankyo 2020 Koenshu (CD-ROM), p.9 - 16, 2020/05
The author has been continuing research and development for corrosion science for about forty years. One of the main targets of his research is applying computational science techniques on corrosion problems. The results are briefly introduced in this article. Also, the author organized some workshop for corrosion problems of 1F decommissioning procedure for several years. Such activities are evaluated for receiving the society award in JSCE.
Shobu, Takahisa; Shiro, Ayumi*; Yoshida, Yutaka*
Zairyo, 69(4), p.343 - 347, 2020/04
Dislocation density is a very important physical quantity in the evaluation of fatigue of metallic materials. Generally, the dislocation density is evaluated by a scanning electron microscope. Recently, a method generated the dislocation density from the width of the X-ray diffraction profile has been proposed. In this study, we report the application of this technology to synchrotron radiation. Five diffraction profiles were obtained with a two-dimensional detector during tensile loading of the austenitic stainless steel SUS316L, and the dislocation density was calculated from the line profile analysis. As a result, the dislocation density increased sharply after plastic deformation, and the value was in good agreement with the result separately measured with a scanning electron microscope. In the future, it is expected that the line profile analysis will contribute to the elucidation of the mechanism of fatigue fracture by measuring the dislocation density from the local area in materials.
Miyakawa, Susumu*; Ito, Toshimasa*; Iwahori, Keisuke*; Aoyama, Yoshihiko*; Kubo, Ryosuke*; Murata, Shinji*; Shobu, Takahisa; Shiro, Ayumi*; Kajiwara, Kentaro*
Zairyo, 69(4), p.308 - 314, 2020/04
White etching area which looks white with nital corrosive liquid may be recognized at the flaking part of a rolling bearing on which high contact stress of several GPa is applied repeatedly. Up to now, studies of white etching area of a ball have been less than studies of white etching area of inner and outer rings. In this study, as part of the flaking mechanism explication with white etching area of a ball, internal residual stress distributions of ball by using high energy white X-ray of SPring-8 (A method) and laboratorial X-ray measurement equipment (B method) were investigated. The former was modified by surface residual stress according to B method. The latter was modified by releasing stress in the form of electrolytic polishing. The results showed modified residual stress distributions almost agree qualitatively.
Omori, Atsushi*; Akiyama, Eiji*; Abe, Hiroshi*; Hata, Kuniki; Sato, Tomonori; Kaji, Yoshiyuki; Inoue, Hiroyuki*; Taguchi, Mitsumasa*; Seito, Hajime*; Tada, Eiji*; et al.
Zairyo To Kankyo, 69(4), p.107 - 111, 2020/04
To evaluate the effect of oxidants, which are formed by radiolysis of water under gamma ray irradiation, on the corrosion of a carbon steel in humid environment, ozone was introduced as a model oxidant in to humidity-controlled air at 50C in a thermo-hygrostat chamber. Corrosion monitoring was performed by using an Atmospheric Corrosion Monitor-type (ACM) sensor consisting of a carbon steel anode and an Ag cathode. The output current of the ACM sensor was increased with the increase in relative humidity and it was obviously increased with the increase in the introduced ozone concentration at each relative humidity. The results indicate that ozone accelerates the corrosion of the carbon steel. The effect of ozone on the corrosion acceleration is attributed to the fast reduction reaction and fast dissolution reaction in to water compared to that of oxygen.
Kino Zairyo, 40(1), p.60 - 71, 2020/01
no abstracts in English
Machida, Hideo*; Koizumi, Yu*; Wakai, Takashi; Takahashi, Koji*
Nihon Kikai Gakkai M&M 2019 Zairyo Rikigaku Kanfarensu Koen Rombunshu (Internet), p.OS1307_1 - OS1307_5, 2019/11
This paper describes the fracture test and fracture analysis of a pipe under displacement control load. In order to grasp the fracture behavior of the circumferential through-wall cracked pipe, which is important in evaluating the feasibility of leak before break (LBB) in sodium cooled reactor piping, a fracture test in case of a circumferential throughwall crack in the weld line between an elbow and a straight pipe was carried out. From this test, it was found that no pipe fracture occurs in the displacement control loading condition even if a large circumferential through-wall crack (180) was assumed. The fracture analysis of the pipe was carried out using Gurson's parameters set based on the tensile test results of the tested pipe material. The analytic results agree well with the test results, and it was found that it will be possible to predict the fracture behavior of sodium cooled reactor piping.
Kasahara, Shigeki; Chimi, Yasuhiro; Hata, Kuniki; Hanawa, Satoshi
Zairyo To Kankyo, 68(9), p.240 - 247, 2019/09
In order to study environment assisted cracking mechanism of stainless steel under BWR primary coolant condition, effects of applied load on oxidation in the vicinity of crack tips of CT specimens were evaluated. Loaded CT specimens were immersed in an aqueous condition at 290C as a simulated BWR coolant condition, and microstructural observation on oxide near the tips of pre-cracks was carried out. Oxide inner layers, which consisted of fine grain magnetite containing Fe and Cr were formed, and oxide outer layers consisting of large grains of FeO were observed to cover the inner layers. FEM analysis of stress and strain in the loaded CT specimen suggests that both of dislocations due to localized plastic deformation and elastic strain could play important roles to accelerate inner oxide formation in the vicinity of the crack tip of the specimens.
Otani, Kyohei; Tsukada, Takashi; Ueno, Fumiyoshi
Zairyo To Kankyo, 68(8), p.205 - 211, 2019/08
In the present study, the iron rust layer formed on the low ally steel in air-solution alternating condition was investigated by cross-sectional observation and analysis, and the mechanism of accelerated corrosion of the steel in the alternating condition was clarified. Observation and analysis showed that the multi-layered iron rust layer composed of red rust layer (FeOOH), rust crust layer (FeO), inner crystal (FeO), and inner rust layer was formed on the low alloy steel. It can be considered that the multi-layered iron rust layer accelerated the cathodic reaction rate of the steel in the alternating condition. This acceleration would be the reason why the corrosion rate of the low alloy steel in the alternating condition was accelerated.
Hirota, Noriaki; Kasahara, Seiji; Iwatsuki, Jin; Imai, Yoshiyuki; Ohashi, Hirofumi; Yan, X.; Tachibana, Yukio
Zairyo To Kankyo, 68(6), p.137 - 142, 2019/06
New corrosion test equipment for high temperature gas of decomposed sulfuric acid was manufactured in order to ascertain flow rate of sulfuric acid in the piping, occurrence of sulfuric acid decomposition reaction in the equipment, and temperature distribution inside the furnace tube. The flow rate of the sulfuric acid solution was constantly measured using an ultrasonic flowmeter. The SO concentration at the inlet of the test equipment was almost the same as that at the inlet of the sulfuric acid decomposer in the hydrogen production plant assuming a high-temperature gas cooled reactor hydrogen-power cogeneration system (GTHTR300C). On the other hand, during a test, leakage of sulfuric acid occurred from the fitting part at the outlet side. Hence the temperature distribution of the fitting part at the outlet side was investigated using fluid analysis. As a result, it was found that the temperature at the fitting was low enough to use fluorine joint grease when the distance was 0.05 m or more away from the outlet side pipe. An improved furnace tube was manufactured and the temperature was measured again at fitting part of the outlet side. The temperature was lower that the temperature limit of the joint grease and almost the same as the temperature distribution in the fluid analysis, and leakage of sulfuric acid has not occurred to date.
Kanayama, Hideyuki*; Hiyoshi, Noritake*; Ogawa, Fumio*; Kawabata, Mie*; Ito, Takamoto*; Wakai, Takashi
Zairyo, 68(5), p.421 - 428, 2019/05
This study presents creep damage assessment method for Mod. 9Cr-1Mo steel by sampling creep testing with thin plate specimen. Tensile creep rupture tests were performed using three different sizes of specimen under two different test environments to verify the creep testing with the thin plate specimen. Time to rupture of Mod. 9Cr-1Mo steel using three different sizes were almost same. In addition, there was no effect of environment on time to rupture. Pre-damaged thin plate specimens were machined from a bulk specimen's gage section that pre-damage test was performed with. Pre-damage based on life fraction rule were 8%, 16% and 25%. No effect of the process of machining pre-damaged specimen on time to rupture was confirmed by verification tests in same test condition as pre-damage test. Stress acceleration creep rupture tests were performed to estimate creep damage assessment. Creep damage assessment by stress acceleration creep rupture tests was sufficiently accurate estimate. Creep damage assessments by Vickers hardness and lath width were compared with the assessment by stress acceleration creep rupture tests to study applicability of these methods.
Suiso No Seizo, Yuso, Chozo Gijutsu To Zairyo Kaihatsu Jireishu, p.59 - 65, 2019/04
This report describes the outline of the thermochemical hydrogen production process by water splitting related to technologies on production, transport and storage of hydrogen. The report explains the principle of thermochemical process as well as the research and development status on Iodine-Sulfur (IS) process performed in JAEA. As energy for IS process, the outline and the domestic and abroad development status of a high temperature gas-cooled reactor is described.
Suzuki, Kenji*; Shobu, Takahisa; Shiro, Ayumi*
Zairyo, 68(4), p.312 - 317, 2019/04
Materials after thermal processing such as welding often have coarse grains. To understand the residual stress after processing is very important from the viewpoint of the soundness of the structure. In this study, we proposed a double exposure method that combines a two-dimensional detector and high-energy synchrotron radiation as an X-ray stress measurement method for materials with coarse grains, and confirmed its practicality. As a result of measuring the residual stress of the plastic bending specimen and the indentation specimen of the aluminum alloy (A5052), the effectiveness of this measurement method was clarified because the residual stress distribution was in good agreement with the finite element analysis.
Zairyo To Kankyo, 68(1), p.2 - 8, 2019/01
It is important to control the cooling water of light water reactors (boiling water reactor and pressurized water reactor) to suitable quality in order to reduce corrosion of structural materials and generation of radioactive corrosion products. For that purpose, monitoring of water quality using electrochemical measurement method is necessary. In this article, the application of ECP measurement to BWR is mainly focused, I describe the water quality of light water reactors and the necessity of electrochemical measurement.
Taniguchi, Naoki; Nakayama, Masashi
Zairyo To Kankyo, 67(12), p.487 - 494, 2018/12
This article describes the current status of corrosion monitoring methods and examples of the measurement under deep underground environments for carbon steel overpacks for high-level radioactive waste disposal. Based on the studies on corrosion monitoring using AC Impedance technique, some of the typical measurement systems such as the electrodes arrangement are introduced. In-situ corrosion monitoring in engineering scale test is also being attempted using a deep underground research facility, and the measurement method and results are presented in this article.
Mizuta, Naoki; Sumita, Junya; Shibata, Taiju; Osaki, Takashi*; Kato, Hideki*; Izawa, Shoichi*; Muto, Takenori*; Gizatulin, S.*; Sakaba, Nariaki
Tanso Zairyo Kagaku No Shinten; Nihon Gakutsu Shinkokai Dai-117-Iinkai 70-Shunen Kinen-Shi, p.161 - 166, 2018/10
To enhance oxidation resistance of graphite material for in-core components of HTGR, JAEA and four Japanese graphite companies; Toyo Tanso, IBIDEN, Tokai Carbon and Nippon Techno-Carbon, are carrying out for development of oxidation-resistant graphite by CVD-SiC coating. This paper describes the outline of neutron irradiation test about the oxidation-resistant graphite by WWR-K reactor of INP, Kazakhstan through an ISTC partner project. Prior to the irradiation test, the oxidation-resistant graphite by CVD-SiC coating of all specimens showed enough oxidation resistance under un-irradiation condition. The neutron irradiation test was already completed and out-of-pile oxidation test will be carried out at the hot-laboratory of WWR-K.