Harjo, S.; Kubota, Satoru*; Gong, W.*; Kawasaki, Takuro; Gao, S.*
Acta Materialia, 196, p.584 - 594, 2020/09
Hattori, Takanori; Sano, Asami; Machida, Shinichi*; Ouchi, Keiichi*; Kira, Hiroshi*; Abe, Jun*; Funakoshi, Kenichi*
High Pressure Research, 40(3), p.325 - 338, 2020/09
To understand the practical effects of pressure-transmitting media (PTM) on neutron diffraction using Paris-Edinburgh presses, diffraction patterns of MgO were collected to approximately 20 GPa using PTMs of Pb, AgCl, 4:1 methano-ethanol (ME) mixture with and without heating, N, and Ar. Hydrostaticity in the sample chamber estimated from the MgO 220 peak width improves in the order of Pb, AgCl, Ar, ME mixture, N, and the heated ME mixture. Unlike previous results using a diamond anvil cell, the unheated ME mixture is superior to Ar even after freezing, probably due to the cup on the anvil face. Considering these results and the sizable coherent scattering of Ne, which would show good hydrostaticity, we conclude that the ME mixture (preferably the heated one) is the best PTM in neutron experiments up to 20 GPa, while Ar can be substituted when a sample is reactive to alcohols.
Nagashima, Mariko*; Armbruster, T.*; Akasaka, Masahide*; Sano, Asami; Nishio-Hamane, Daisuke*; Malsy, A.*; Imaoka, Teruyoshi*; Nakashima, Kazuo*
Physics and Chemistry of Minerals, 47(6), p.29_1 - 29_18, 2020/06
Three non-metamict chevkinite-subgroup minerals, from Cape Ashizuri, Japan, Tangir Valley, Diamar District, Pakistan and Haramosh Mts., Skardu district, Pakistan, were studied by crystal chemical techniques. Powder X-ray diffraction and transmission electron microscopic observations confirmed well crystalline samples. Electron-microprobe analyses indicated the general composition known for chevkinite-(Ce). Site scattering values determined by single-crystal X-ray structure refinements suggested assignment of subordinate Nb to the octahedral M3 and M4 sites, minor Th to M1 for the Ashizuri sample and minor Mg to M1 for both samples from Pakistan. Neutron time-of-flight powder diffraction studies were applied to determine the Ti/Fe distribution among octahedral sites for all samples and Mossbauer spectroscopy served for the Fe valence assignment at the four octahedral sites. The dominant iron valence at M1 of the Haramosh sample is ferric whereas for samples Nos. 1 and 2 iron is ferrous.
Saito, Hiroyuki*; Machida, Akihiko*; Iizuka, Riko*; Hattori, Takanori; Sano, Asami; Funakoshi, Kenichi*; Sato, Toyoto*; Orimo, Shinichi*; Aoki, Katsutoshi*
Scientific Reports (Internet), 10, p.9934_1 - 9934_8, 2020/06
Neutron powder diffraction profiles were collected for iron deuteride (FeDx) while the temperature decreased from 1023 to 300 K for a pressure range of 4-6 GPa. The ' deuteride with a double hexagonal close-packed (dhcp) structure, which coexisted with other stable or metastable deutrides at each temperature and pressure condition, formed solid solutions with a composition of FeD at 673 K and 6.1 GPa and FeD at 603 K and 4.8 GPa. Upon stepwise cooling to 300 K, the D-content x increased to a stoichiometric value of 1.0 to form monodeuteride FeD. In the dhcp FeD at 300 K and 4.2 GPa, dissolved D atoms fully occupied the octahedral interstitial sites, slightly displaced from the octahedral centers in the dhcp metal lattice, and the dhcp sequence of close-packed Fe planes contained hcp-stacking faults at 12%. Magnetic moments with 2.11 0.06 B/Fe-atom aligned ferromagnetically in parallel on the Fe planes.
Abe, Nobuyuki*; Shiozawa, Shunsuke*; Matsuura, Keisuke*; Sagayama, Hajime*; Nakao, Akiko*; Ohara, Takashi; Tokunaga, Yusuke*; Arima, Takahisa*
Physical Review B, 101(18), p.180407_1 - 180407_5, 2020/05
Hozengaku, 19(1), p.29 - 34, 2020/04
no abstracts in English
Hozengaku, 19(1), p.24 - 28, 2020/04
no abstracts in English
Xu, P. G.; Ikeda, Yoshimasa*; Hakoyama, Tomoyuki*; Takamura, Masato*; Otake, Yoshie*; Suzuki, Hiroshi
Journal of Applied Crystallography, 53(2), p.444 - 454, 2020/04
Harjo, S.; Aizawa, Kazuya; Gong, W.*; Kawasaki, Takuro
Materials Transactions, 61(5), p.828 - 832, 2020/04
Nakazato, Seiya*; Iwasa, Kazuaki*; Hashimoto, Daisuke*; Shiozawa, Mami*; Kuwahara, Keitaro*; Nakao, Hironori*; Sagayama, Hajime*; Ishikado, Motoyuki*; Ohara, Takashi; Nakao, Akiko*; et al.
JPS Conference Proceedings (Internet), 30, p.011128_1 - 011128_6, 2020/03
Komabuchi, Mai*; Urushihara, Daisuke*; Asaka, Toru*; Fukuda, Koichiro*; Ohara, Takashi; Munakata, Koji*; Ishikawa, Yoshihisa*
Journal of the Physical Society of Japan, 89(3), p.034601_1 - 034601_5, 2020/03
Komatsu, Kazuki*; Klotz, S.*; Machida, Shinichi*; Sano, Asami; Hattori, Takanori; Kagi, Hiroyuki*
Proceedings of the National Academy of Sciences of the United States of America, 117(12), p.6356 - 6361, 2020/03
Above 2 GPa the phase diagram of water simplifies considerably and exhibits only two solid phases up to 60 GPa, ice VII and ice VIII. The two phases are related to each other by hydrogen ordering, with the oxygen sub-lattice being essentially the same. Here we present neutron diffraction data to 15 GPa which reveal that the rate of hydrogen-ordering at the ice VII-VIII transition decreases strongly with pressure to reach time scales of minutes at 10 GPa. Surprisingly, the ordering process becomes more rapid again upon further compression. We show that such an unusual change in transition rate can be explained by a slowing-down of the rotational dynamics of water molecules with a simultaneous increase of translational motion of hydrogen under pressure, as previously suspected. The observed crossover in the hydrogen dynamics in ice is likely the origin of various hitherto unexplained anomalies of ice VII in the 10-15 GPa range reported by Raman spectroscopy, X-ray diffraction, and proton conductivity.
Takahashi, Osamu*; Shibui, Yohei*; Xu, P. G.; Harjo, S.; Suzuki, Tetsuya*; Tomota, Yo*
Quantum Beam Science (Internet), 4(1), p.16_1 - 16_15, 2020/03
Cho, K.*; Morioka, Ryota*; Harjo, S.; Kawasaki, Takuro; Yasuda, Hiroyuki*
Scripta Materialia, 177, p.106 - 111, 2020/03
Wang, Y.*; Tomota, Yo*; Omura, Takahito*; Morooka, Satoshi; Gong, W.*; Harjo, S.
Acta Materialia, 184, p.30 - 40, 2020/02
Komatsu, Kazuki*; Machida, Shinichi*; Noritake, Fumiya*; Hattori, Takanori; Sano, Asami; Yamane, Ryo*; Yamashita, Keishiro*; Kagi, Hiroyuki*
Nature Communications (Internet), 11(1), p.464_1 - 464_5, 2020/02
Water freezes below 0C at ambient pressure ordinarily to ice I, with hexagonal stacking sequence. Under certain conditions, ice with a cubic stacking sequence can also be formed, but ideal ice I without stacking-disorder has never been formed until recently. Here we demonstrate a route to obtain ice I without stacking-disorder by degassing hydrogen from the high-pressure form of hydrogen hydrate, C, which has a host framework isostructural with ice I. The stacking-disorder free ice I is formed from C via an intermediate amorphous or nano-crystalline form under decompression, unlike the direct transformations occurring in ice XVI from neon hydrate, or ice XVII from hydrogen hydrate. The obtained ice I shows remarkable thermal stability, until the phase transition to ice I at 250 K, originating from the lack of dislocations. This discovery of ideal ice I will promote understanding of the role of stacking-disorder on the physical properties of ice as a counter end-member of ice I.
Klotz, S.*; Komatsu, Kazuki*; Polian, A.*; Machida, Shinichi*; Sano, Asami; Iti, J.-P.*; Hattori, Takanori
Physical Review B, 101(6), p.064105_1 - 064105_6, 2020/02
Manganese oxide (MnO) is a prototype of an antiferromagnetic Mott-insulator. Here we investigate the interplay of magnetic ordering and lattice distortion across the Nel temperature under pressure using neutron and X-ray diffraction. We find an increase of with a rate of = +4.5(5) K/GPa, an increase of the rhombohedral distortion by = +0.018/GPa, as well as a volume striction which is insensitive to pressure. These results allow to retrieve the dependence of the coupling constants and on interatomic distances and compare it to first-principles predictions. Antiferromagnetic diffuse scattering was observed up to 1.2 , and long-range magnetic order appears at room temperature at 42 GPa.
Urakawa, Satoru*; Inoue, Toru*; Hattori, Takanori; Sano, Asami; Kohara, Shinji*; Wakabayashi, Daisuke*; Sato, Tomoko*; Funamori, Nobumasa*; Funakoshi, Kenichi*
Minerals (Internet), 10(1), p.84_1 - 84_13, 2020/01
The structure of hydrous amorphous SiO is fundamental to investigate the effects of water on the physicochemical properties of oxide glasses and magma. The hydrous SiO glass with 13 wt.% DO was synthesized under high-pressure and high-temperature conditions and its structure was investigated by small angle X-ray scattering, X-ray diffraction, and neutron diffraction experiments at pressures of up to 10 GPa and room temperature. This hydrous glass is separated into a SiO rich major phase and a DO rich minor phase. Medium-range order of the hydrous glass shrinks compared to the anhydrous SiO glass due to disruption of SiO linkage by formation of Si-OD deuterioxyl, while the pressure response is similar. Most of DO molecules are in the small domains and hardly penetrate into SiO major phase.
Woo, W.*; Jeong, J. S.*; Kim, D.-K.*; Lee, C. M.*; Choi, S.-H.*; Suh, J.-Y.*; Lee, S. Y.*; Harjo, S.; Kawasaki, Takuro
Scientific Reports (Internet), 10(1), p.1350_1 - 1350_15, 2020/01
Yamashita, Keishiro*; Komatsu, Kazuki*; Hattori, Takanori; Machida, Shinichi*; Kagi, Hiroyuki*
Acta Crystallographica Section C; Structural Chemistry (Internet), 75(12), p.1605 - 1612, 2019/12
A crystal structure of a high-pressure phase of magnesium chloride hexahydrate (MgCl 6HO-II) and its deuterated counterpart (MgCl 6DO-II) have been identified for the first time by in-situ single-crystal X-ray and powder neutron diffraction. The crystal structure was analyzed by the Rietveld method for the neutron diffraction pattern based on the initial structure determined by single-crystal X-ray diffraction. This high-pressure phase has a similar framework to that in the known ambient-pressure phase, but exhibits some structural changes with symmetry reduction caused by a subtle modification in the hydrogen-bond network around the Mg(HO) octahedra. These structural features reflect the strain in the high-pressure phases of MgCl hydrates.