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Soma, Yasutaka; Komatsu, Atsushi; Kaji, Yoshiyuki; Yamamoto, Masahiro*; Igarashi, Takahiro
Corrosion Science, 251, p.112897_1 - 112897_15, 2025/07
Times Cited Count：1 Percentile：0.00(Materials Science, Multidisciplinary)Experimental and modeling studies of the oxygen ingression at the crevices of stainless steels were conducted in high-temperature water (288
C). The limiting distance of oxygen ingression, 
, was defined as the point beyond which the primary surface oxide changed (hematite 
magnetite), regardless of crevice gap, oxygen concentration, and time. In situ measurements revealed increased electrical conductivity around the position indicating ion enrichment due to a differential oxygen concentration cell. increased with increasing crevice gap, oxygen concentration, and immersion time. Modeling study suggested that oxide layer growth reduced anodic dissolution and slowed oxygen consumption, allowing oxygen ingression with time.
Sato, Tomonori; Hata, Kuniki; Kato, Chiaki; Igarashi, Takahiro
Zairyo To Kankyo, 73(4), p.102 - 109, 2024/04
To evaluate the effects of dissolved oxygen concentration to water quality within SCC crack and the distribution of water quality in the depth direction under irradiation, immersion tests of stainless steel specimens given a gap and water radiolysis calculations for the water quality in the crevice gap were performed. As a result, it was confirmed that Fe
O
was formed in the entire area within the crevice regardless of the dissolved oxygen concentration. It was also estimated that under irradiation, the oxidant species produced directly by radiolysis in the crack are consumed by the oxide growth, and anion enrichment occurs in the crack even in the irradiation conditions.
Tang, J.*; Wang, Y.*; Fujihara, Hiro*; Shimizu, Kazuyuki*; Hirayama, Kyosuke*; Ebihara, Kenichi; Takeuchi, Akihisa*; Uesugi, Masayuki*; Toda, Hiroyuki*
Scripta Materialia, 239, p.115804_1 - 115804_5, 2024/01
Times Cited Count：11 Percentile：80.41(Nanoscience & Nanotechnology)Stress corrosion cracking (SCC) behaviors induced by the combination of external and internal hydrogen (H) in an Al-Zn-Mg-Cu alloy were systematically investigated via in situ 3D characterization techniques. SCC of the Al-Zn-Mg-Cu alloy could initiate and propagate in the potential crack region where the H concentration exceeded a critical value, in which the nanoscopic H-induced decohesion of 
-MgZn
precipitates resulted in macroscopic cracking. External H that penetrated the alloy from the environment played a crucial role during the SCC of the Al-Zn-Mg-Cu alloy by generating gradient-distributed H-affected zones near the crack tips, which made Al alloys in water environment more sensitive to SCC. Additionally, the pre-existing internal H was driven toward the crack tips during plastic deformation. It was involved in the SCC and made contributions to both the cracks initiation and propagation.
Soma, Yasutaka; Igarashi, Takahiro
Dai-70-Kai Zairyo To Kankyo Toronkai Koenshu (CD-ROM), p.199 - 202, 2023/10
Since an acidic corrosive environment (crevice environment) is formed inside the stress corrosion cracking (SCC) of stainless steel in high temperature water, it is important to understand the corrosion behavior in the crevice environment for the better understanding of crack growth behavior. In the previous study, the authors measured the electrical conductivity inside the crevice and obtained values of 380 
S/cm and 1600 S/cm for the crevice with and without intergranular corrosion, respectively. In this study, we defined the crevice environment I (pH
=4.41) and II (pH=3.13) corresponding the above conductivity values, and the corrosion behavior of Fe-xCr-20Ni (x=16.9, 19.8, 22.9, 24.3, 25.9) in each crevice environment was investigated. In the simulated crevice environment-I, the all alloys showed passive behavior, while in the environment-II, severe corrosion with intergranular cracking was observed for x = 16.9 and 19.8, and a thick oxide film was formed. On the other hand, above x=22.9, oxide film growth was suppressed and a clear passive region appeared on the polarization curve.
Yamaguchi, Yoshihito; Mano, Akihiro; Li, Y.
Proceedings of ASME 2022 Pressure Vessels and Piping Conference (PVP 2022) (Internet), 10 Pages, 2022/07
The steam generator (SG) tube is one of the important components in pressurized water reactors. Flaws such as wall-thinning or stress corrosion cracking have been reported in SG tubes. The burst pressure where both the internal and external pressures from the primary and secondary coolant systems are considered must be predicted to assess the structural integrity of SG tubes. Burst tests were performed by various organizations. On the basis of the test results, failure estimation methods were proposed. In this study, previous burst test data and existing failure estimation methods for SG tubes with wall-thinning or crack were investigated. As a result, the coefficient of the existing estimation method for SG tube with uniform wall-thinning was updated. In addition, failure estimation methods that are suitable for SG tubes with crack or local wall-thinning were proposed by considering the effects of the flaw shape and size on the burst pressure. The applicability of the failure estimation methods was confirmed by comparing the predicted results with the burst test data in actual SG tubes.
Soma, Yasutaka; Komatsu, Atsushi; Ueno, Fumiyoshi
Corrosion, 78(6), p.503 - 515, 2022/06
Times Cited Count：1 Percentile：7.22(Materials Science, Multidisciplinary)The effects of electrochemical potential (ECP) on water chemistry within a crevice are of critical importance for understanding stress corrosion cracking (SCC) of Fe-Cr-Ni alloys in high temperature water. In this study, the effects of ECP on the electrical conductivity of a solution within a Type-316L stainless steel crevice (
) have been studied in 288C and 8 MPa water containing 10 ppb Cl
as major anionic species. In situ measurements of in a rectangular crevice with a gap of 15 m and a depth of 23 mm have been conducted using small sensors installed at different crevice depths. An increase in ECP from -0.49 V (vs. standard hydrogen electrode) to -0.12 V resulted in an increase in from 12 Scm
to 160 Scm at a distance of 21 mm from the crevice mouth. The increase in reached a maximum at about 0.15 V (about 300 Scm) and then tended to decrease with increasing potential. Finite element model analysis taking into account the electrochemical reaction quantitatively reproduced this behavior. It is considered that Cl is the major anionic species transported into the crevice at relatively low potentials, and that increases monotonically with increasing ECP. On the other hand, when ECP exceeds around 0 V, a sufficient amount of HCrO
generated by transpassive dissolution also transported into the gap. Since this chemical species is highly oxidizing, unlike Cl, it is assumed that it reacts with metal cations to oxidize and precipitate them, thereby lowering conductivity.
Tsukada, Takashi; Soma, Yasutaka
Hozengaku, 19(4), p.37 - 44, 2021/01
Corrosion Cracking phenomena in JPDR (Japan Power Demonstration Reactor) the first Japanese Light Water Reactor is reviewed. This review describes two major cracking failure. The first was found during inspection in 1966 as the cracking failure on weld-overlay cladding at the inner wall of the top head. A series of analysis showed that some of the cracks reached the base metal across the weld boundaries and further penetrated into the vessel wall. Significant depletion of ferrite content was detected in manually welded part considered to assisted the cracking. These inspection result in improvement of the welding procedure and no similar failures have been reported in Japanese reactor. This mode of failure gave rise to a new research field studying the corrosion fatigue behavior of low alloy steel because of importance to assess pressure boundary of the reactor. The experiment of JPDR also contributed to the establishment of international cooperation for studying EAC (environmentally assisted cracking). The second failure was found in 1972 near the welded part between stainless piping and safe end. The extensive research concluded that this failure was caused by Stress Corrosion Cracking.
Fujimoto, Shinji*; Tsuchiya, Hiroaki*; Ogawa, Soma*; Iida, Yoshihisa; Taniguchi, Naoki
Materials and Corrosion, 72(1-2), p.333 - 338, 2021/01
Times Cited Count：3 Percentile：13.68(Materials Science, Multidisciplinary)The stress corrosion cracking (SCC) of pure copper in bentonite was examined by a slow strain rate test (SSRT). The bentonite was swollen with pure water or aqueous solutions containing NH of 0.05 M and 0.1 M. The thick corrosion films and particulate deposits were formed on copper surface after SSRT. Typical tarnish rupture type SCC occurred on pure copper in swollen bentonite with and without NH. Crack propagation rate was enhanced by NH. It is confirmed thick oxide layer is formed on copper during plastic deformation which resulting in the tarnish crack type SCC. The many particulate deposits observed on the surface might be formed as a results of rapid dissolution of Cu
to form porous CuO at locallized deformed sites.
Ogawa, Yusuke*; Suzuki, Satoru*; Taniguchi, Naoki; Kawasaki, Manabu*; Suzuki, Hiroyuki*; Takahashi, Rieko*
Materials and Corrosion, 72(1-2), p.52 - 66, 2021/01
Times Cited Count：2 Percentile：8.90(Materials Science, Multidisciplinary)Cast steel is one of the promising alternative to forged steel that is the current reference material for carbon steel overpack. In this study, the full-scale cast steel overpack was produced experimentally and the distribution of casting defects were investigated. The corrosion test regarding corrosion rate and stress corrosion cracking (SCC) susceptibility were also conducted using samples taken from the full-scale cast steel overpack and the corrosion resistance of cast steel was compared with that of forged steel. From above two corrosion tests, it can be said that the corrosion resistance of cast steel is mostly the same as that of forged steel.
Hashikura, Yasuaki*; Ishijima, Yasuhiro; Nakahara, Masaumi; Sano, Yuichi; Ueno, Fumiyoshi; Abe, Hitoshi
Hozengaku, 19(3), p.95 - 102, 2020/10
A plutonium concentrator was selected, and constant load tensile tests with controlled applied potentials and electrochemical tests were conducted in nitric acid and sodium nitrate solutions. From the results, a map which shows the effect of nitric acid concentration to crack initiation potential was drawn. And, it was pointed out that not only the nitric acid but also the nitrate ion coordinated to the nitrate must be considered in evaluating the possibility of stress corrosion cracking.
Ueno, Fumiyoshi
Zairyo To Kankyo, 68(1), p.2 - 8, 2019/01
It is important to control the cooling water of light water reactors (boiling water reactor and pressurized water reactor) to suitable quality in order to reduce corrosion of structural materials and generation of radioactive corrosion products. For that purpose, monitoring of water quality using electrochemical measurement method is necessary. In this article, the application of ECP measurement to BWR is mainly focused, I describe the water quality of light water reactors and the necessity of electrochemical measurement.
Soma, Yasutaka; Ueno, Fumiyoshi
Zairyo To Kankyo, 67(5), p.222 - 228, 2018/05
Localized corrosion in crevice of SUS316 stainless steel after immersion in 288C high purity water with dissolved oxygen concentration of 32 ppm for 100 h was analyzed. Two different types of localized corrosion initiated on grain boundary and inclusions. The former initiated on grain boundary and oxide grown into grain matrix. The oxidized area showed duplex structure composed of microcrystalline FeCrO and island-shaped residual metals. The latter initiated on inclusions containing Ca and S and microcrystalline FeCrO grown into metal matrix. These localized corrosion occurred selectively in oxygen depleted area indicated formation of macroscopic corrosion cell with the corroded area as anode and surrounding oxygenated area as cathode.
Soma, Yasutaka; Kato, Chiaki; Ueno, Fumiyoshi
Proceedings of the 18th International Conference on Environmental Degradation of Materials in Nuclear Power Systems - Water Reactors, Vol.2, p.509 - 521, 2018/00
In-situ electrochemical measurement within crevice of stainless steel in 288C water has been conducted to analyze crevice water chemistry. Small sensors (
250m) measured local solution electrical conductivity, 
, polarization resistance, and electrochemical corrosion potential. Real-time response of the as functions of bulk water conductivity, dissolved oxygen (DO) concentration has been quantitatively analyzed. The effect of geometrical factors on the crevice environment was also studied. The differ more than an order of magnitude depending on the oxygen potential inside the crevice. The increased by small amount of bulk DO (e.g. 30 ppb). Maximum was observed with DO of 32000 ppb and became more than 100 times higher than that of bulk water. Crevice geometry affected significantly on the water chemistry inside.
Pokor, C.*; Herbelin, A.*; Couvant, T.*; Kaji, Yoshiyuki
NEA/NSC/R(2016)5 (Internet), p.317 - 360, 2017/05
In aged BWR plants, certain locations in the mid-plane of the core shroud experience fluence levels at which the materials become susceptible to irradiation assisted stress corrosion cracking (IASCC). BWRVIP (Boiling Water Reactor Vessel Internals Program) has developed crack growth disposition methodologies for evaluating intergranular stress corrosion cracking (IGSCC) in the internal components of BWRs and the Japan Nuclear Energy Safety organization (JNES) has been conducting a project related to IASCC crack growth rate data as a part of safety research and development study for the aging management and maintenance of the nuclear power plants. Although many investigators proposed prediction models for SCC and IASCC growth rates for austenitic stainless steels and Ni alloys, even more improvements of models are necessary as compared with the detailed experimental results, because these models are still preliminary models.
Soma, Yasutaka; Kato, Chiaki; Ueno, Fumiyoshi
Fushoku Boshoku Kyokai Dai-63-Kai Zairyo To Kankyo Toronkai Koenshu (CD-ROM), p.253 - 256, 2016/10
Contribution of corrosion to advance of stress corrosion cracking (SCC) of stainless steel in high temperature water must be assessed because serious corrosion can be found within SCC of light water reactors. The corrosion took the form of both intergranular and grain-matrix attack indicate aggressive corrosion condition was formed in the crevice of the SCC. We have investigated the crevice environment electrochemically and found that local electrical conductivity of the crevice solution at satisfactory narrow crevice gap having more than 100 times higher than that of bulk solution. In this research we assessed effect of cyclic deaerated and aerated bulk solution to the crevice environment. The result showed that electrical conductivity of the crevice solution under the deaerated bulk solution increased more than 10times by injection of pure oxygen suggest that the dissolved oxygen caused aggressive corrosion condition within the crevice.
Nagai, Masaki*; Lu, K.; Kamaya, Masayuki*
Nihon Kikai Gakkai M&M 2016 Zairyo Rikigaku Kanfuarensu Koen Rombunshu (Internet), p.481 - 483, 2016/10
In nuclear power plants, a number of cracks attributed to stress corrosion cracking (SCC) have been detected in welds made with nickel alloy weld metals. One of the characteristics of these cracks is that crack aspect ratio 
is greater than 0.5, where a is the crack depth and 
is the crack length. When a crack is detected in components of nuclear power plants during in-service inspection, flaw evaluation is conducted according to the requirement of codes such as JSME Rules on Fitness-for-Service for Nuclear Power Plants. Here, the stress intensity factor plays an important role for predicting crack growth behavior due to fatigue and/or SCC. Although several solutions of the stress intensity factor are already given in the JSME code, no solutions are available for the cracks with 
0.5. According to the current code, surface cracks with 0.5 are characterized as semi-circular shape 
. To evaluate these cracks in a rational manner, several solutions have been proposed for cracks with 0.5. In this paper, comprehensive comparison was made between solutions for cracks 0.5, and benchmark analysis on SCC crack growth was performed.
Kaji, Yoshiyuki; Miwa, Yukio; Tsukada, Takashi; Hayakawa, Masao*; Nagashima, Nobuo*; Matsuoka, Saburo*
JAERI-Research 2005-029, 156 Pages, 2005/09
JAERI-Research-2005-029.pdf:57.24MB
This report describes a result of the research conducted under contract with JNES that was concerned with a multi-scale analysis of plastic deformation behavior at the crack tip of SCC. The research was carried out to evaluate the validity of the SCC growth data acquired in the IGSCC project based on a mechanistic understanding of SCC. For the purpose, in this research, analyses of the plastic deformation behavior and microstructure around the crack tip were performed in a nano-order scale. The hardness measured in nano, meso and macro scales was employed as a common index of the strength, and the essential data necessary to understand the SCC propagation behavior were acquired and analyzed that are mainly a size of plastic deformation region and a microstructural information in the region, e.g. data of crystallografy, microscopic deformation and dislocations at the inside of grains and grain boundaries.
Ito, Hiroto*; Onizawa, Kunio; Shibata, Katsuyuki*
JAERI-Data/Code 2005-007, 118 Pages, 2005/09
JAERI-Data-Code-2005-007.pdf:5.23MB
As a part of the aging and structual integrity research for LWR components, new PFM (Probabilistic Fracture Mechanics) codes PASCAL-SC and PASCAL-EQ have been developed. These codes evaluate the failure probability of an aged welded joint by Monte Carlo method. PASCAL-SC treats Stress Corrosion Cracking (SCC) in piping, while PASCAL-EQ takes fatigue crack growth by seismic load into account. The development of these codes has been aimed to improve the accuracy and reliability of analysis by introducing new analysis and methodologies and algorithms considering the recent development in the fracture machanics methodologies and computer performance. The crack growth by an irregular stress due to seismic load in detail is considered in these codes. They also involves recent stress intensity factors and fracture criteria. In addition, a user's friendly operation of a GUI (Graphical User Interface) which generates input data, supports calculations and plots results is introduced. This report provides the user's manual and theoretical background of these codes.
Itakura, Mitsuhiro; Kaburaki, Hideo; Arakawa, Chuichi
Physical Review E, 71(5), p.055102_1 - 055102_4, 2005/05
Times Cited Count：9 Percentile：41.36(Physics, Fluids & Plasmas)The process of slow intergranular crack propagation was investigated by the finite element method model and it was found that branching is induced by partial arresting of a crack front owing to the geometrical randomness of grain boundaries. A possible scenario for the branching instability of crack propagation in a disordered continuous medium is also discussed.
Morisaki, Norihiro; Hayashi, Koji; Inagaki, Yoshiyuki; Kato, Michio; Fujisaki, Katsuo*; Maeda, Yukimasa; Mizuno, Sadao*
JAERI-Tech 2005-009, 37 Pages, 2005/03
JAERI-Tech-2005-009.pdf:14.33MB
The breakage of the catalyst dust filter was found at the nozzle flange, which was welded onto the end plate of the filter, by the bubbling test using nitrogen gas of the mock-up model test facility. We investigated the cause of breakage and devised a repairing method. The cause of the breakage was the stress corrosion cracking (SCC) generated from the inside of the filter. The filter was repaired based on the following countermeasures such as reduction of condensed water in the filter, tensile stress and sensitization at welding joints. Furthermore, the inspection was carried out to investigate the structural integrity of the welding joints in the test facility of which structure, material and operating condition were similar to the filter. As the results, it was confirmed that the structural integrity was maintained.
