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Machida, Akihiko*; Saito, Hiroyuki*; Aoki, Katsutoshi*; Komatsu, Kazuki*; Hattori, Takanori; Sano, Asami; Funakoshi, Kenichi*; Machida, Shinichi*; Sato, Toyoto*; Orimo, Shinichi*
Physical Review B, 111(22), p.224413_1 - 224413_6, 2025/06
The crystal and magnetic structures of antiferromagnetic Mn deuterides formed by hydrogenating Mn metal at high temperature and high pressure, fcc -MnDx and hcp
-MnDx, were investigated by in-situ neutron powder diffraction. Deuterium atoms partially occupied the octahedral interstitial positions of the fcc and hcp metal lattices. The site occupancies increased rapidly with decreasing temperature from
700 to
450 K and remained down to 300 K. N
el temperature of 543(10) K was determined for
-MnD
. For
-MnD
, saturation magnetic moment and N
el temperature were determined to be 0.82(1)
and 347(3) K, respectively. The N
el temperatures determined for
-MnD
and
-MnD
are consistent with those predicted by the respective Slater-Pauling curves proposed in previous studies. The updated N
el temperatures provide insights into the development of more accurate Slater-Pauling curves based on electronic band structure calculations.
He, X.*; Kagi, Hiroyuki*; Komatsu, Kazuki*; Iizuka, Riko*; Okajima, Hajime*; Hattori, Takanori; Sano, Asami; Machida, Shinichi*; Abe, Jun*; Goto, Hirotada*; et al.
Journal of Molecular Structure, 1310, p.138271_1 - 138271_8, 2024/08
Times Cited Count:0 Percentile:0.00(Chemistry, Physical)High-pressure responses of the O-DF hydrogen bonds in deuterated magnesium hydroxyfluoride were investigated using neutron powder diffraction and Raman spectroscopy. The Rietveld analysis at ambient conditions revealed a chemical formula of Mg(OD)
F
and hydroxyl group/fluorine disorder (OD/F disorder) in the crystal structure, which gave rise to two hydrogen-bonding configurations. The Rietveld analysis showed the hydrogen-bonding geometries remains up to 9.8 GPa, indicating no pressure-induced strengthening of hydrogen bonds. The Raman spectra at ambient conditions showed three hydroxyl stretching bands at 2613, 2694, and 2718 cm
. The high frequencies of the O-D stretching modes indicated that the hydroxyls should be involved in weak or none hydrogen-bonding interactions. Up to 20.2 GPa, the mode initially centered at 2694 cm
displayed a pressure-induced blue shift, revealing no strengthening of hydrogen bonds under compression. We discuss the existence of hydrogen bonds and the causes of the blue-shifting hydroxyls at ambient and at high pressures.
Huang, M.*; Kinjo, Tetsuya*; Yasumura, Shunsaku*; Toyao, Takashi*; Matsumura, Daiju; Saito, Hiroyuki*; Shimizu, Kenichi*; Namiki, Norikazu*; Maeno, Zen*
Catalysis Science & Technology, 13(23), p.6832 - 6838, 2023/12
Times Cited Count:0 Percentile:0.00(Chemistry, Physical)Shito, Chikara*; Kagi, Hiroyuki*; Kakizawa, Sho*; Aoki, Katsutoshi*; Komatsu, Kazuki*; Iizuka, Riko*; Abe, Jun*; Saito, Hiroyuki*; Sano, Asami; Hattori, Takanori
American Mineralogist, 108(4), p.659 - 666, 2023/04
Times Cited Count:5 Percentile:71.52(Geochemistry & Geophysics)The phase relation and crystal structure of FeNi
H
(D
) at high pressures and temperatures up to 12 GPa and 1000 K were clarified by in-situ X-ray and neutron diffraction measurements. Under
conditions of the present study, no deuterium atoms occupied tetragonal (
) sites of face-centered cubic (fcc) Fe
Ni
D
unlike fcc FeH
(D
). The deuterium-induced volume expansion per deuterium
was determined as 2.45(4)
and 3.31(6)
for fcc and hcp phases, respectively, which were significantly larger than the corresponding values for FeD
. The
value slightly increased with increasing temperature. This study suggests that only 10% of nickel in iron drastically changes the behaviors of hydrogen in metal. Assuming that
is constant regardless of pressure, the maximum hydrogen content in the Earth's inner core is estimated to be one to two times the amount of hydrogen in the oceans.
Micheau, C.; Ueda, Yuki; Akutsu, Kazuhiro*; Bourgeois, D.*; Motokawa, Ryuhei
Solvent Extraction and Ion Exchange, 41(2), p.221 - 240, 2023/02
Times Cited Count:4 Percentile:43.72(Chemistry, Multidisciplinary)Sakaki, Koji*; Kim, H.*; Majzoub, E. H.*; Machida, Akihiko*; Watanuki, Tetsu*; Ikeda, Kazutaka*; Otomo, Toshiya*; Mizuno, Masataka*; Matsumura, Daiju; Nakamura, Yumiko*
Acta Materialia, 234, p.118055_1 - 118055_10, 2022/08
Times Cited Count:20 Percentile:84.24(Materials Science, Multidisciplinary)Komatsu, Yuya*; Shimizu, Ryota*; Sato, Ryuhei*; Wilde, M.*; Nishio, Kazunori*; Katase, Takayoshi*; Matsumura, Daiju; Saito, Hiroyuki*; Miyauchi, Masahiro*; Adelman, J. R.*; et al.
Chemistry of Materials, 34(8), p.3616 - 3623, 2022/04
Times Cited Count:17 Percentile:76.57(Chemistry, Physical)Kumazoe, Hiroyuki*; Igarashi, Yasuhiko*; Iesari, F.*; Shimizu, Ryota*; Komatsu, Yuya*; Hitosugi, Taro*; Matsumura, Daiju; Saito, Hiroyuki*; Iwamitsu, Kazunori*; Okajima, Toshihiko*; et al.
AIP Advances (Internet), 11(12), p.125013_1 - 125013_5, 2021/12
Times Cited Count:4 Percentile:24.33(Nanoscience & Nanotechnology)Mori, Yuichiro*; Kagi, Hiroyuki*; Kakizawa, Sho*; Komatsu, Kazuki*; Shito, Chikara*; Iizuka, Riko*; Aoki, Katsutoshi*; Hattori, Takanori; Sano, Asami; Funakoshi, Kenichi*; et al.
Journal of Mineralogical and Petrological Sciences, 116(6), p.309 - 313, 2021/00
Times Cited Count:2 Percentile:10.84(Mineralogy)The Earth's core is believed to contain some light elements because it is 10% less dense than pure Fe under the corresponding pressure and temperature conditions. Hydrogen, a promising candidate among light elements, has phase relations and physical properties that have been investigated mainly for the Fe-H system. This study specifically examined an Fe-Si-H system using in-situ neutron diffraction experiments to investigate the site occupancy of deuterium of hcp-FezSi
hydride at 14.7 GPa and 800 K. Results of Rietveld refinement indicate hcp-Fe
Si
hydride as having deuterium (D) occupancy of 0.24(2) exclusively at the interstitial octahedral site in the hcp lattice. The effect on the site occupancy of D by addition of 2.6 wt% Si into Fe (Fe
Si
) was negligible compared to results obtained from an earlier study of an Fe-D system (Machida et al., 2019).
Kawaguchi, Munemichi
Proceedings of 2020 International Conference on Nuclear Engineering (ICONE 2020) (Internet), 6 Pages, 2020/08
In decommissioning sodium-cooled fast reactors, the operators can be exposed to radiation during dismantling of the cold trap equipment (C/T). The C/T has higher dose equipment because the C/T trapped the tritium of the fission product during the operation to purify the sodium coolant. In this research, the thermal decomposition temperature and rate of sodium hydride were measured as the fundamental research for improvement of the thermorlysis method prior to the dismantling. We measured the thermal decomposition temperature and rate using sodium hydride powder (95.3%, Sigma-Aldrich) in AlO
crucible with TG-DTA (STA2500, NETASCH Japan). The heating rates were set to
= 2.0, 5.0, 10.0, 20.0 K/min, and the weight decrease was measured. The thermal decomposition temperature and rate were obtained from the temperature of the onset of the weigh decrease and the Kissinger plot, respectively. Furthermore, we set to the thermal decomposition temperature of around 600 K, and the weight decreasing rates were measured. The change of the chemical composition of the sodium hydride with heating (from NaH to Na) was measured with X-Ray Diffraction (XRD) analysis. As a result, the thermal decomposition occurred at around 600 K, and the almost all hydrogen in the sodium hydride released within 1 h. The thermal decomposition rate strongly depended on the heating temperature.
Saito, Hiroyuki*; Machida, Akihiko*; Iizuka, Riko*; Hattori, Takanori; Sano, Asami; Funakoshi, Kenichi*; Sato, Toyoto*; Orimo, Shinichi*; Aoki, Katsutoshi*
Scientific Reports (Internet), 10, p.9934_1 - 9934_8, 2020/06
Times Cited Count:5 Percentile:19.41(Multidisciplinary Sciences)Neutron powder diffraction profiles were collected for iron deuteride (FeDx) while the temperature decreased from 1023 to 300 K for a pressure range of 4-6 GPa. The ' deuteride with a double hexagonal close-packed (dhcp) structure, which coexisted with other stable or metastable deutrides at each temperature and pressure condition, formed solid solutions with a composition of FeD
at 673 K and 6.1 GPa and FeD
at 603 K and 4.8 GPa. Upon stepwise cooling to 300 K, the D-content x increased to a stoichiometric value of 1.0 to form monodeuteride FeD
. In the dhcp FeD
at 300 K and 4.2 GPa, dissolved D atoms fully occupied the octahedral interstitial sites, slightly displaced from the octahedral centers in the dhcp metal lattice, and the dhcp sequence of close-packed Fe planes contained hcp-stacking faults at 12%. Magnetic moments with 2.11
0.06 B/Fe-atom aligned ferromagnetically in parallel on the Fe planes.
Machida, Akihiko*; Saito, Hiroyuki*; Hattori, Takanori; Sano, Asami; Funakoshi, Kenichi*; Sato, Toyoto*; Orimo, Shinichi*; Aoki, Katsutoshi*
Scientific Reports (Internet), 9(1), p.12290_1 - 12290_9, 2019/08
Times Cited Count:31 Percentile:83.40(Multidisciplinary Sciences)Hexagonal close-packed iron hydride, hcp FeHx, is absent from the conventional phase diagram of the Fe-H system, although hcp metallic Fe exists stably over extensive temperature () and pressure (
) conditions, including those corresponding to the Earth's inner core.
X-ray and neutron diffraction measurements at temperatures ranging from 298 to 1073 K and H pressures ranging from 4 to 7 GPa revealed that the hcp hydride was formed for FeH
compositions when
. Hydrogen atoms occupied the octahedral interstitial sites of the host metal lattice both partially and randomly. The hcp hydride exhibited a H-induced volume expansion of 2.48(5)
/H-atom, which was larger than that of the face-centered cubic (fcc) hydride. The hcp hydride showed an increase in
with
, whereas the fcc hydride showed a corresponding decrease. The present study provides guidance for further investigations of the Fe-H system over an extensive
-
-
region.
Klotz, S.*; Casula, M.*; Komatsu, Kazuki*; Machida, Shinichi*; Hattori, Takanori
Physical Review B, 100(2), p.020101_1 - 020101_5, 2019/07
Times Cited Count:15 Percentile:54.32(Materials Science, Multidisciplinary)Ytterbium dihydride (YbH) shows a well-known transition at
16 GPa from a CaH
-type structure to a high-pressure (high-
) phase with Yb at hcp sites and unknown H-positions. Here, we report its complete structure determination by neutron diffraction at 34 GPa. Hydrogen(deuterium) is located at 2
and 2
positions of space group
, thus forming a high-symmetry "collapsed" close-packed lattice. The transition is sluggish and can be seen as a transfer of 1/2 of the hydrogen atoms from strongly corrugated H-layers to interstitial sites of the Yb-lattice. We demonstrate by first-principles calculations that the transition is related to a change from a completely filled
-electron configuration to a fractional
-hole (
0.25 h) occupation in the high-
phase. The
charge transfer closes the gap at the transition and leads to a metallic ground state with sizeable electron-phonon interaction involving out-of-plane vibrational modes of interstitial hydrogen.
Yamauchi, Akihiro*; Amaya, Masaki
Proceedings of Annual Topical Meeting on Reactor Fuel Performance (TopFuel 2018) (Internet), 7 Pages, 2018/10
Differential scanning calorimetry (DSC) measurements on pre-hydrided cold worked, stress relieved and recrystallized Zry-4 cladding were performed in a temperature range between 50 and 600C in order to elucidate the effect of final heat treatment at fabrication of Zircaloy-4 (Zry-4) cladding on the terminal solid solubility during the dissolution of zirconium hydrides at heating up (TSSD). Obtained DSC curves and Metallography indicate that the initial state of hydrides affects the dissolution behavior of hydride. The Arrhenius plots of the TSSD temperatures and hydrogen contents obtained from this study revealed that cold worked samples exhibited the largest TSSD and followed by stress relieved and recrystallized samples. The results of this study indicated that the difference in microstructure due to final heat treatment at fabrication of Zry-4 cladding affects the dissolution behavior of hydrides.
Akutsu, Kazuhiro*; Adachi, Motoyasu*; Kawakita, Yukinobu
JAEA-Review 2018-002, 36 Pages, 2018/03
Since J-PARC started operation for user programs with high-intensity pulsed neutron beams, many material and life science studies have been carried out at J-PARC. Since partial or complete deuteration of organic compounds for contrast variation in the scattering length densities of materials is one of the most effective techniques in the application of neutron scattering analysis, deuterated materials have led to significant progress in our understanding of the structure of novel organic materials. Aiming at accelerating development of deuteration activities in our country, an international workshop "Deuterated Materials Enhancing Neutron Science for Structure Function Applications" was held as a J-PARC Workshop at Ibaraki Quantum Beam Research Center from 19th October to 20th October in 2017. In this workshop, the chemical/biological deuteration activities and recent scientific results of deuterated materials enhancing neutron study in Japan and other countries were discussed by domestic/foreign deuteration and neutron scientists. This is a report of the workshop summarized by organizers.
Iizuka, Riko*; Yagi, Takehiko*; Goto, Hirotada*; Okuchi, Takuo*; Hattori, Takanori; Sano, Asami
Hamon, 27(3), p.104 - 108, 2017/08
Hydrogen is the most abundant element in the solar system and is considered to be one of the promising candidates of the light elements in the Earth's core. However, the amount of hydrogen dissolved in the core and its process are still unknown because hydrogen cannot be detected by X ray and easily escapes from iron at ambient conditions. In this study, we have conducted high-pressure and high-temperature in-situ neutron diffraction experiments on the iron-hydrous mineral system using PLANET in J-PARC. We observed that the water, which was dissociated from a hydrous mineral, reacted with iron to form both iron oxide and iron hydride at about 4 GPa. Iron hydride remained stable after further increase in temperature. This formation occurred at 1000K, where no materials melted. This suggests that hydrogen dissolved into iron before any other light elements dissolved in the very early stage of the Earth's evolution.
Takagi, Shigeyuki*; Iijima, Yuki*; Sato, Toyoto*; Saito, Hiroyuki; Ikeda, Kazutaka*; Otomo, Toshiya*; Miwa, Kazutoshi*; Ikeshoji, Tamio*; Aoki, Katsutoshi*; Orimo, Shinichi*
Angewandte Chemie; International Edition, 54(19), p.5650 - 5653, 2015/05
Times Cited Count:36 Percentile:69.33(Chemistry, Multidisciplinary)Aoki, Katsutoshi*; Machida, Akihiko*; Saito, Hiroyuki*; Hattori, Takanori; Sano, Asami
Hamon, 25(1), p.26 - 31, 2015/02
The deuterization process of fcc Fe to form solid1solution fcc FeD was investigated by
neutron diffraction measurements at high temperature and high pressure. In a completely deuterized specimen at 988 K and 6.3 GPa, deuterium atoms occupy the octahedral and tetrahedral interstitial sites with an occupancy of 0.532(9) and 0.056(5), respectively, giving a deuterium composition
of 0.64(1). During deuterization, the metal-lattice expands approximately linearly with deuterium composition at a rate of 2.21
per deuterium atom. The minor occupation of tetrahedral site is likely driven by the intersite movement of deuterium atoms along the
111
direction in the fcc metal lattice. These results provide implications for the light elements in the Earth's core and the mechanism of hydrogen embrittlement of ferrous metals.
Abe, Hiroshi; Morimoto, Ryo*; Sato, Fumiatsu*; Azuma, Yorito*; Uchida, Hirohisa*
Journal of Alloys and Compounds, 408-412, p.348 - 350, 2006/02
Times Cited Count:10 Percentile:53.78(Chemistry, Physical)Mm(misch metal) based hydrogen storage alloys are applied to the negative electrode of the Ni-H battery and other hydrogen storage systems. In such pratical applications, various surface processes of hydrogen molecules often become rate contolling. Therefore, the improvement of the alloy surface is of great importance to promote the initial activation and hydriding rate. We have reported that the alkaline pretreatment of an alloy surfece exhibits a high durability against CO attack. Since low energy ion irradiation is quite useful for surface modification of materials, the hydriding proerties of a Mm is expected on electrochemical hydriding rate of the alloy. As a result, the ion irradiation Mm was found to induce a higher hydriding rate than that of the un-irradiation one.
Fukada, Satoshi*; Hayashi, Takumi
Nihon Genshiryoku Gakkai-Shi, 47(9), p.623 - 629, 2005/09
no abstracts in English