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Ebihara, Kenichi; Saito, Kei*; Takai, Kenichi*
Proceedings of 2016 International Hydrogen Conference (IHC 2016); Materials Performance in Hydrogen Environments, p.470 - 477, 2017/00
For understanding hydrogen (H) embrittlement of steels, it is necessary to infer the state that defects trap H in the steels. Thermal desorption spectra of H obtained by the thermal desorption spectrometry (TDS) are used for inferring such a state. Because the thermal desorption spectra include the influence of experimental conditions and hydrogen diffusion as well as information of the defects trapping H, it is necessary to interpret the spectra using the numerical simulation. In the presentation, we determined the detrapping and the trapping rate constants which are necessary for the simulation from the experimental spectra obtained for plate specimens which is so small that H diffusion is ignorable. Then we confirmed that the model using the obtained rate constants can simulate the spectra of larger cylindrical specimens, so that it was found that the rate constant for small specimens can be used for the simulation of the spectra for specimens of different shape or size.
Ebihara, Kenichi; Saito, Kei*; Takai, Kenichi*
"Suiso Zeika No Kihon Yoin To Tokusei Hyoka Kenkyukai Chukan Hokokukai" Shimposium Yokoshu (USB Flash Drive), p.30 - 35, 2016/09
no abstracts in English
Ebihara, Kenichi; Saito, Kei*; Takai, Kenichi*
"Suiso Zeika No Kihon Yoin, Kaiseki To Hyoka" Shimposium Yokoshu (USB Flash Drive), p.27 - 33, 2015/09
The thermal desorption spectra which reflect the H segregation state can be obtained by heating a specimen including H at a constant rate. However, the simulation of spectra needs to extract information of the H segregation state because spectra is affected by experimental conditions and H diffusion. The detrapping activation energy E
and the pre-exponential factor of detraping rate constant which are simulation parameters are fixed from the data previously reported or by fitting experimental spectra. Instead, we evaluated both of them from the experimental spectra of the specimen in which the H diffusion effect can be ignored, and simulated the spectra using them. As a result, in the case of iron, we could simulate spectra better than by the previous parameters. In the case of tempered martensitic steel, we could simulate spectra by the value obtained by adjusting the evaluated p
along with the evaluated E.
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dual phase steels using numerical simulationEbihara, Kenichi; Sekine, Daiki*; Takai, Kenichi*
no journal, ,
no abstracts in English
Ebihara, Kenichi; Yamaguchi, Masatake; Tsuru, Tomohito; Itakura, Mitsuhiro
no journal, ,
no abstracts in English
