Saito, Shigeru; Okubo, Nariaki; Obayashi, Hironari; Wan, T.; Sugawara, Takanori; Sasa, Toshinobu; Maekawa, Fujio
JPS Conference Proceedings (Internet), 28, p.071003_1 - 071003_6, 2020/02
Japan Atomic Energy Agency (JAEA) proposes transmutation of minor actinides (MA) by accelerator-driven systems (ADS). The ADS designed by JAEA is a system composed by LBE (Lead-Bismuth Eutectic) spallation target and a subcritical core. In the ADS, a beam window (BW) is exposed in complex field of heavy irradiation by proton/neutron and corrosion by flowing LBE. To develop ADS structural materials, it is of critical importance to investigate materials used in such environment. Thus, JAEA plans to construct a proton irradiation facility at the J-PARC to prepare an irradiation database for candidate ADS structural materials and to investigate irradiation effects in flowing LBE environment. In this paper, giving a whole scope of the JAEA ADS development, some results of experimental measurements and the specific program for planed R&D will be presented.
Ishikawa, Norito; Taguchi, Tomitsugu*; Kitamura, Akane; Szenes, G.*; Toimil-Molares, M. E.*; Trautmann, C.*
Journal of Applied Physics, 127(5), p.055902_1 - 055902_7, 2020/02
Hillock formation is one of the important aspects of radiation-induced modification of solid material. To our knowledge this is first result showing that the hillock formation in ceramics is affected by the velocity effect. The present result include Se-dependences of hillock dimensions based on precise measurement using TEM (transmission electron microscopy). The paper should be published to make researchers aware that hillock size is actually comparable to ion-track size in wide Se range. In addition, the results include important insight about the hillock formation mechanism of ceramics irradiated with swift heavy ions.
Ebihara, Kenichi; Suzudo, Tomoaki
TMS 2020; 149th Annual Meeting & Exhibition Supplemental Proceedings, p.995 - 1002, 2020/02
Phosphorus (P) is known as an element which causes grain boundary (GB) embrittlement in steels. In addition, GB P segregation is promoted by the increase of vacancies and self interstitial atoms due to irradiation. Thus, the diffusion rate theory model for estimating irradiation-induced GB P segregation has been developed based on the atomic processes. Since the present model does not include the trapping and de-trapping processes at GBs, however, it cannot calculate the value which is directly compared with experimental results. In this study, we simulated the migration of a P atom in the 3(111) symmetrical tilt GB. In addition, by tracking the migration of the P atom, the diffusion barrier energy was evaluated. As a result, the diffusion barrier energy was almost the same as the P segregation energy of an interstitial site in the GB, and it was found that P atoms migrate via interstitial sites in the GB.
Nagai, Takayuki; Kobayashi, Hidekazu; Okamoto, Yoshihiro; Akiyama, Daisuke*; Sato, Nobuaki*; Uehara, Akihiro*; Fujii, Toshiyuki*; Sekimoto, Shun*
KURNS Progress Report 2018, P. 105, 2019/08
To understand this structural change of a borosilicate glass by a neutron irradiation in detail, the irradiation test was carried out in KUR in 2017FY. The glass structure was estimated by using Raman spectrometry in 2018FY. Comparing with the Raman spectra of glass samples before and after irradiation, it could be observed the change of peak height of Si-O bridging structure by the irradiation.
Kasahara, Shigeki; Chimi, Yasuhiro; Hata, Kuniki; Fukuya, Koji*; Fujii, Katsuhiko*
Proceedings of 19th International Conference on Environmental Degradation of Materials in Nuclear Power Systems - Water Reactors (Internet), p.1345 - 1355, 2019/08
This paper describes empirical equation development of crack growth rates (CGR) in consideration of IASCC of neutron irradiated stainless steel to contribute to structural integrity assessment of BWR reactor internals. Empirical equations of CGR (da/dt) were developed based on a formula of da/dt = MK, assuming that "M" and "n" tend to be saturated with increasing neutron fluence. To obtain the empirical equations for normal water chemistry (NWC) and hydrogen water chemistry (HWC) of BWR, a data fitting with least square method was applied to the datasets consisting of F, K and CGR from post irradiation examinations of neutron irradiated stainless steel under simulated NWC and HWC conditions from open literature. As a result, calculated results by the equation for NWC showed good agreement with measured CGR data, meanwhile those for HWC did not. The above difference was seemed to be attributed that CGR data obtained under HWC conditions were scattered extensively.
Fukuya, Koji*; Fujii, Katsuhiko*; Chimi, Yasuhiro; Hata, Kuniki
Proceedings of 19th International Conference on Environmental Degradation of Materials in Nuclear Power Systems - Water Reactors (Internet), p.523 - 531, 2019/08
For structural integrity assessment on reactor internals of light water reactors, empirical equations of tensile properties as a function of neutron dose, and trend curves of stress-strain relations of neutron-irradiated austenitic stainless steels was proposed by fitting to recently developed database. The data in the database were obtained from reports of national projects in Japan and open literature, which was summarized in the form of data sheets. The empirical equations for tensile properties were formulated by using a saturation-type formulae. The equations were for CW 316 and SA 304/316 stainless steels in the temperature range of 280-350C and the dose range up to 80 dpa. Stress-strain relation curves were reproduced based on the Swift model. Obtained calculated results by the empirical equations and stress-strain relations were reasonably well fitted to experimental data. The effects of composition and cold-working, etc. on tensile properties were discussed.
Takamizawa, Hisashi; Katsuyama, Jinya; Ha, Yoosung; Tobita, Toru; Nishiyama, Yutaka; Onizawa, Kunio
Proceedings of 2019 ASME Pressure Vessels and Piping Conference (PVP 2019) (Internet), 8 Pages, 2019/07
no abstracts in English
Ikusawa, Yoshihisa; Morimoto, Kyoichi; Kato, Masato; Saito, Kosuke; Uno, Masayoshi*
Nuclear Technology, 205(3), p.474 - 485, 2019/03
This study evaluated the effects of plutonium content and self-irradiation on the thermal conductivity of mixed-oxide (MOX) fuel. Samples of UO fuel and various MOX fuels were tested. The MOX fuels had a range of plutonium contents, and some samples were stored for 20 years. The thermal conductivity of these samples was determined from thermal diffusivity measurements taken via laser flash analysis. Although the thermal conductivity decreased with increasing plutonium content, this effect was slight. The effect of self-irradiation was investigated using the stored samples. The reduction in thermal conductivity caused by self-irradiation depended on the plutonium content, its isotopic composition, and storage time. The reduction in thermal conductivity over 20 years' storage can be predicted from the change of lattice parameter. In addition, the decrease in thermal conductivity caused by self-irradiation was recovered with heat treatment, and recovered almost completely at temperatures over 1200 K. From these evaluation results, we formulated an equation for thermal conductivity that is based on the classical phonon-transport model. This equation can predict the thermal conductivity of MOX fuel thermal conductivity by accounting for the influences of plutonium content and self-irradiation.
Inoue, Toshihiko; Sekio, Yoshihiro; Watanabe, Hideo*
Materia, 58(2), P. 92, 2019/02
For the evaluation of irradiated segregation behavior, Austenite-based stainless steel for the fast reactor, during irradiation was evaluated by utilizing TIARA facility (Irradiate temperature: 600 C, Dose: 100 dpa) was observed by analytical electron microscope (JEM-ARM20FC). As a result of observation, the large-size void is observed in irradiation area, and MX segregation (containing Niobium) is not observed. In un-irradiation area the MX segregation is observed. And it is observed conspicuously that Nickel is segregation on the void surface. By the latest high-performance TEM utilization, these phenomenon are able to visualize. It is expected for the clarification of the irradiation damage and mechanism of void swelling, by the analyzing these phenomenon utilization with the latest high-performance TEM utilization.
Kasahara, Shigeki; Fukuya, Koji*; Fujimoto, Koji*; Fujii, Katsuhiko*; Chimi, Yasuhiro
JAEA-Review 2018-013, 171 Pages, 2019/01
For structural integrity assessment of reactor internals of light water reactors, it is important to evaluate and predict the property changes of structural materials, based on existing data obtained from austenitic stainless steel irradiated with neutrons. Compilation of the data into tables is valuable for discussing the representative or the most probable values of the properties applied to the assessment. When the data compilation, the data must be distinguished clearly in consideration of different service conditions of core internals of pressurized water reactors (PWR) and boiling water reactors. Main objective of this work is to provide material property tables of irradiated austenitic stainless steel which will be applicable for assessment of structural integrity of core internals of PWRs. To compile the table, published literature reporting irradiated stainless steel data were surveyed and screened by considering the service conditions of PWRs. In addition to the data, various parameters for the data evaluation, e.g. chemical compositions and pre-treatments of the materials, irradiation and examination conditions, were extracted from the literature, and listed into tables.
Kakitani, Kenta*; Kimata, Tetsuya*; Yamaki, Tetsuya*; Yamamoto, Shunya*; Matsumura, Daiju; Taguchi, Tomitsugu*; Terai, Takayuki*
Radiation Physics and Chemistry, 153, p.152 - 155, 2018/12
Kasahara, Shigeki; Fukuya, Koji*; Koshiishi, Masato*; Fujii, Katsuhiko*; Chimi, Yasuhiro
JAEA-Review 2018-012, 180 Pages, 2018/11
For structural integrity assessment of reactor internals of light water reactors, it is important to evaluate and predict the property changes of structural materials, based on existing data obtained from austenitic stainless steel irradiated with neutrons. Compilation of the data into tables is valuable for discussing the representative or the most probable values of the properties applied to the assessment. In the process of the data compilation, the data must be distinguished clearly in consideration of different service conditions of core internals of boiling water reactors (BWR) and pressurized water reactors. Main objective of this work is to provide material property tables of irradiated austenitic stainless steel which will be applicable for assessment of structural integrity of core internals of BWRs. To compile the table, published literature reporting irradiated stainless steel data were surveyed and screened by considering the service conditions of BWRs. In addition to the data, various parameters for the data evaluation, e.g. chemical compositions and pre-treatments of the materials, irradiation and examination conditions, were extracted from the literature, and listed into the tables.
Yamaki, Tetsuya*; Nuryanthi, N.*; Kitamura, Akane; Koshikawa, Hiroshi*; Sawada, Shinichi*; Voss, K.-O.*; Severin, D.*; Tautmann, C.*
Nuclear Instruments and Methods in Physics Research B, 435, p.162 - 168, 2018/11
We used individual single-ion tracks in fluoropolymers with diameters of tens to hundreds of nanometers; chemical etching and ion-track grafting enabled us to develop ion-track and proton-conductive membranes, respectively. In the ion-track membranes of PVDF, strongly-LET-dependent etching was found, so the pore shape as well as the size was exclusively controlled by the track structures. We performed the ion-track grafting of styrene into ETFE to develop nanostructure-controlled proton exchange membranes (PEMs) for applications in PEM fuel cells. Our ion beam technology to develop fluoropolymer-based nanostructures has the potential to apply in the field of filtration processes and fuel cell devices. This would make it possible to provide new microfiltration technology for water treatment, sterilization, petroleum refining and dairy processing.
Li, R.*; Pang, C.*; Amekura, Hiroshi*; Ren, F.*; Hbner, R.*; Zhou, S.*; Ishikawa, Norito; Okubo, Nariaki; Chen, F.*
Nanotechnology, 29(42), p.424001_1 - 424001_8, 2018/10
We report on the fabrication of reshaped Ag nanoparticles (NPs) embedded in a Nd:YAG crystal by combining Ag ion implantation and swift heavy Xe ion irradiation. The localized surface plasmon resonance (LSPR) effect is proved to be efficiently modulated according to the phenomenon of polarization-dependent absorption. The LSPR peak located at 448 nm shows red shift and blue shift at 0 degree and 90 degree polarization, respectively, which is in good agreement with calculation by discrete dipole approximation. Based on the near-field intensity distribution, the interaction between reshaped NPs shows a non-ignorable effect on the optical absorption. Furthermore, the polarization-dependence of the photoluminescence (PL) intensity is analyzed, which is positively related to the modulated LSPR absorption. It demonstrates the potential of the enhancement of PL intensity by embedded plasmonic Ag NPs.
Amekura, Hiroshi*; Kluth, P.*; Mota-Santiago, P.*; Sahlberg, I.*; Jantunen, V.*; Leino, A. A.*; Vazquez, H.*; Nordlund, K.*; Djurabekova, F.*; Okubo, Nariaki; et al.
Physical Review Materials (Internet), 2(9), p.096001_1 - 096001_10, 2018/09
When a swift heavy ion (SHI) penetrates amorphous SiO, a core/shell (C/S) ion track is formed due to vaporization, where the ion track consists of a lower-density core and a higher-density shell. Here we reexamine this hypothesis. The MD simulations indicate that the vaporization is not induced under 50-MeV Si irradiation ( = 3 keV/nm), but the C/S tracks and the ion shaping of nanoparticles are nevertheless induced. Thus, the vaporization is not a prerequisite for the C/S tracks and the ion shaping.
Nagai, Takayuki; Uehara, Akihiro*; Fujii, Toshiyuki*
KURRI Progress Report 2017, P. 128, 2018/08
In this study, to understand the structural change of a borosilicate glass by a neutron irradiation in detail, the neutron irradiation test was carried out for 50 min in the Pn-2 of the Kyoto University Research Reactor (KUR). The structural change of glass sample after the irradiation will be estimated in 2018FY. Before the irradiation test, the glass composition was selected to estimate a structural change accurately by Raman spectrometry and 2 kinds of Li free borosilicate glass for the irradiation test samples were prepared.
Suzudo, Tomoaki; Tsuru, Tomohito; Hasegawa, Akira*
Journal of Nuclear Materials, 505, p.15 - 21, 2018/07
Tungsten (W) is considered as a promising candidate for plasma-facing materials for future nuclear fusion devices, and selecting optimal alloying constituents is a critical issue to improve radiation resistance of the W alloys as well as to improve their mechanical properties. We conducted in the current study a series of first-principles calculations for investigating solvent-solute mixed dumbbells in W crystals. The results suggested that titanium (Ti), vanadium (V), and chromium (Cr) are favorable as solutes for W alloys from irradiation-effect perspectives because these elements are expected to promote vacancy-interstitial recombination without causing radiation-induced precipitation that reduces ductility of irradiated materials.
Kikuchi, Takeo; Tada, Kenichi; Sakino, Takao; Suyama, Kenya
JAEA-Research 2017-021, 56 Pages, 2018/03
The criticality management of the fuel debris is one of the most important research issues in Japan. The current criticality management adopts the fresh fuel assumption. The adoption of the fresh fuel assumption for the criticality control of the fuel debris is difficult because the k of the fuel debris could exceed 1.0 in most of cases which the fuel debris contains water and does not contain neutron absorbers such as gadolinium. Therefore, the adoption of the burnup credit is considered. The prediction accuracy of the isotopic composition of used nuclear fuel must be required to adopt the burnup credit for the treatment of the fuel debris. JAEA developed a burnup calculation code SWAT4.0 to obtain reference calculation results of the isotopic composition of the used nuclear fuel. This code is used to evaluate the composition of fuel debris. In order to investigate the prediction accuracy of SWAT4.0, we analyzed the PIE of BWR obtained from 2F2DN23.
Katsuyama, Jinya; Masaki, Koichi; Miyamoto, Yuhei*; Li, Y.
JAEA-Data/Code 2017-015, 229 Pages, 2018/03
As a part of the structural integrity research for aging light water reactor components, a probabilistic fracture mechanics (PFM) analysis code PASCAL has been developed in JAEA. The PASCAL code can evaluate the conditional failure probabilities and failure frequencies for core region in reactor pressure vessels under the pressurized thermal shock events. In this study, we improved many functions such as the stress intensity factor solutions, the fracture toughness models, or confidence level evaluation function by considering epistemic and aleatory uncertainties related to influence parameters in the structural integrity assessment. We also developed the analysis module PASCAL-Manager which calculates the failure frequency for the entire core region taking into consideration the failure probabilities obtained from PACAL-RV. Based on these improvements, the new analysis code is upgraded to PASCAL Ver.4. This report provides the user's manual and theoretical background of PASCAL Ver.4.
Yamaki, Tetsuya*; Goto, Mitsuaki*; Sawada, Shinichi*; Koshikawa, Hiroshi*; Kitamura, Akane; Higa, Mitsuru*
QST-M-8; QST Takasaki Annual Report 2016, P. 35, 2018/03
We prepared ion exchange membranes by a heavy-ion-track grafting method, and then used them for seawater concentration process. Both the water uptake and resistance were lower for our ion-track grafted membranes than for the conventional -ray-grafted membranes. The results would be because local and high-density energy deposition due to the ion beam enabled us to control the membrane structure in a nanometer scale. We demonstrate our membranes are suitable for this application.