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Wada, Yuki; Mitomo, Hiroshi*; Kasuya, Kenichi*; Nagasawa, Naotsugu; Seko, Noriaki; Katakai, Akio; Tamada, Masao
Journal of Applied Polymer Science, 101(6), p.3856 - 3861, 2006/09
Times Cited Count:21 Percentile:53.53(Polymer Science)Radiation-induced graft polymerization of acrylic acid (AAc) on the surface of poly(3-hydroxybutyric acid) (PHB) film was carried out by applying pre-irradiation techniques. The PHB films grafted with AAc (PHB-g-AAc) possessed a degree of grafting higher than 5% have completely lost the enzymatic degradability. The enzymatic degradability of the grafted film was recovered by remolding. And the highest enzymatic degradation rate was observed to grafted films with AAc 10% of degree. Difference of enzymatic degradability of PHB-g-AAc film was caused by decrement of amount of enzyme contact and decrement of crystallinity of PHB by remolding.
Inoue, Yutaka; Kobayashi, Kazuhiro; Yamaki, Tetsuya; Asano, Masaharu; Kubota, Hitoshi*; Yoshida, Masaru
Dai-2-Kai 21-Seiki Rengo Shimpojiumu; Kagaku Gijutsu To Ningen Rombunshu, p.257 - 260, 2003/00
We prepared crosslinked fluoropolymer electrolyte membranes for use in fuel cells and then investigated their structural properties by X-ray diffraction (XRD) analysis. The radiation-induced grafting of styrene into crosslinked polytetrafluoroethylene (PTFE) films and subsequent sulfonation enabled us to obtain the electrolyte membrane with a sufficient ion exchange capacity, which exceeds that of the commercially-available film, Nafion. As the crosslinking and styrene grafting reactions proceeded, the size of the PTFE crystallites in the film became smaller, thereby decreasing the film crystallinity. Interestingly, in contrast to Nafion, the resulting sulfonated membranes were found to have high crystallinity.
*; *; *; Yagi, Toshiaki; Morita, Yosuke
Denki Gakkai; Yuden, Zetsuen Zairyo Kenkyukai Shiryo DEI-97-147155, p.13 - 18, 1997/12
no abstracts in English
Yoshii, Fumio; G.Meligi*; Sasaki, T.; Makuuchi, Keizo; A.M.Rabie*; *
Polym. Degrad. Stab., 49, p.315 - 321, 1995/00
Times Cited Count:36 Percentile:82.06(Polymer Science)no abstracts in English
Mitomo, Hiroshi*; Morishita, Norio; *
Polymer, 36(13), p.2573 - 2578, 1995/00
Times Cited Count:49 Percentile:87.44(Polymer Science)no abstracts in English
; ;
Ika Kikaigaku, 57(2), p.59 - 64, 1987/02
no abstracts in English
Y.S.Soebianto*; ; ;
Angewandte Makromolekulare Chemie, 149(2413), p.87 - 99, 1987/00
Times Cited Count:11 Percentile:54.07(Polymer Science)no abstracts in English
; ;
Polym.Commun., 28, p.278 - 280, 1987/00
no abstracts in English
*; ; *
Journal of Applied Physics, 54(8), p.4433 - 4438, 1983/00
Times Cited Count:5 Percentile:34.44(Physics, Applied)no abstracts in English
; Kuriyama, Isamu; *; *
IEEE Transactions on Electrical Insulation, 17(4), p.306 - 313, 1982/00
no abstracts in English
; Kuriyama, Isamu; *; *
J.Mater.Sci., 17, p.3052 - 3056, 1982/00
Times Cited Count:0 Percentile:0.01(Materials Science, Multidisciplinary)no abstracts in English
; Takehisa, Masaaki; Machi, Sueo
JAERI-M 5577, 19 Pages, 1974/03
no abstracts in English