JAEA
  • help
  • PC | SP
  • JP | EN
          
Refine your search：     
Report No.
 - 
Clear All
Search Results: Records 1-4 displayed on this page of 4
  • 1

Presentation/Publication Type

Initialising ...

Refine

Journal/Book Title

Initialising ...

Meeting title

Initialising ...

First Author

Initialising ...

Keyword

Initialising ...

Language

Initialising ...

Publication Year

Initialising ...

Held year of conference

Initialising ...

Save select records

Journal Articles

Ion-pairing extraction and their reaction modeling of anionic M-Cl species with cationic NTAamide(C6) extractant and comparison with density functional theory calculations

Kinoshita, Ryoma; Sasaki, Yuji; Kaneko, Masashi; Matsumiya, Masahiko*; Shinoku, Kota*; Shiroishi, Hidenobu*

Hydrometallurgy, 222, p.106159_1 - 106159_12, 2023/10

https://doi.org/10.1016/j.hydromet.2023.106159
 Times Cited Count：2 Percentile：17.21(Metallurgy & Metallurgical Engineering)

Solvent extraction is conducted using a total of 20 metals revealing high stability constants with Cl and hexahexyl-nitrilotriacetamide (NTAamide(C6)) extractant. The metals used here may behave as anions at high Cl concentrations, and NTAamide(C6), which contains a tertiary N atom, is protonated under acidic conditions. Most of the metal ions in this study display higher distribution ratios (D(M)) from HCl than those from HNO$$_{3}$$, and exhibit 1:1 stoichiometries with NTAamide. Following the experimental results, the association constants and distribution coefficients of the group 12 elements are calculated via ion-pair extraction modeling using density functional theory calculations, and the simulations of D yield calculated values with the same trend as that of the measured values.

Journal Articles

Rust and corrosion mechanism of carbon steel in dilute chloride solution at low dose rates

Motooka, Takafumi

QST-M-8; QST Takasaki Annual Report 2016, P. 73, 2018/03

https://repo.qst.go.jp/records/73811

Previous corrosion test of carbon steel in dilute artificial seawater under Co-60 $$gamma$$-ray irradiation has indicated that corrosion rate was enhanced at absorbed dose rates: $$>$$100 Gy/h and rust color was changed from black to dark brown. In the present study, the corrosion mechanism of carbon steel under Co-60 $$gamma$$-ray irradiation was investigated by identification of rust. $$gamma$$ rays enhanced oxidation of iron ions from di-valent to tri-valent. Rust formed under irradiation had higher oxidation state.

Journal Articles

Thermal and radiation oxidations of benzene to phenol in aqueous solutions containing metal ions of at elevated temperatures, 1; The thermal behavior of iron sulfate and chloride in aqeous solutions without benzene

;

Bulletin of the Chemical Society of Japan, 36(6), p.717 - 721, 1963/00

https://doi.org/10.1246/bcsj.36.717
 Times Cited Count：16

no abstracts in English

Journal Articles

Thermal and radiation oxidations of benzene to phenol in aqueous solutions containing metal ions of at elevated temperatures, 2; The effect of iron sulfate and chloride on phenol yield

; ; ; Terakawa, Akira*

Bulletin of the Chemical Society of Japan, 36(6), p.721 - 727, 1963/00

https://doi.org/10.1246/bcsj.36.721
 Times Cited Count：20

no abstracts in English

4 (Records 1-4 displayed on this page)
  • 1