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Yoshida, Zenko; Kihara, Sorin*; Fujinaga, Taichiro*
Bunseki Kagaku, 53(4), p.195 - 205, 2004/04
Times Cited Count:1 Percentile:1.01(Chemistry, Analytical)A quantitative electrolysis of an electro-active species in a sample solution can be achieved very rapidly when the solution is allowed to flow through and be electrolyzed at a column electrode. Complete electrolysis of the species is attained with a small over-voltage, even if the electrode reaction is slow. The electrolytic method using the column electrode is suitable for automated or remote-controlled operation. Because of unmatched advantages, the column-electrode electrolysis method has been widely applied to the coulometric determination of species in a flowing sample solution and to liquid chromatography as a coulometric detector. This technique is especially favorable for elucidating mechanism of such complicated reactions as that involving unstable intermediates. In the present article, a principle and a feature of the column-electrode electrolysis are presented and the advantages of these methods are reviewed based on recent works on its application to flow-injection analysis and to a study of the redox reaction of actinide ions or the reaction of short-lived radicals.
Sasaki, Yuji
Electrochimica Acta, 42(12), p.1915 - 1920, 1997/00
Times Cited Count:2 Percentile:12.15(Electrochemistry)no abstracts in English
Sasaki, Yuji
Analytical Sciences, 11, p.1005 - 1008, 1995/12
Times Cited Count:1 Percentile:7.46(Chemistry, Analytical)no abstracts in English
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Anal. Chem., 52(11), p.1601 - 1606, 1980/00
Times Cited Count:18 Percentile:37.58(Chemistry, Analytical)no abstracts in English