Mass transfer inside narrow crevice of SUS316L in high temperature water

Yamamoto, Masahiro; Soma, Yasutaka; Igarashi, Takahiro; Ueno, Fumiyoshi

Proceedings of Annual Congress of the European Federation of Corrosion (EUROCORR 2018) (USB Flash Drive), 7 Pages, 2018/09

In order to clarify the SCC behavior of SUS316L under BWR environment, mass transfer inside crevice of SUS316L in high temperature water using various crevice gap samples was investigated. The samples were prepared by put together two SUS316L sheets. Crevice gap differs from 0.005 mm to 0.1 mm. Corrosion tests were conducted in 8 ppm dissolved oxygen (DO) conditions. Surface oxide film was analysed by laser Raman spectroscopy (LRS) after immersion. Numerical simulations were also conducted by using COMSOL Maltiphysics. Diffusion process of DO and the other chemical species were calculated with connected to electrochemical process. Electrical conductivities inside the crevice were 100 times larger than these of outer water. The reason of high conductivity is existence of Fe ions at the DO depletion crevice.

Intergranular oxidation within crevice of austenitic stainless steel in high temperature water

Soma, Yasutaka; Kato, Chiaki; Ueno, Fumiyoshi

Proceedings of 23rd International Conference on Nuclear Engineering (ICONE-23) (DVD-ROM), 8 Pages, 2015/05

Intergranular oxidation (corrosion) occurred within crevice of austenitic low-carbon stainless steel (solution treated, almost no applied stress) after immersion in high temperature water (288C, 8.5 MPa, dissolved oxygen conc. 32 ppm, electrical conductivity: 1.20.2S (measured value at 25C)) for 500 h. The intergranular oxidation occurred at specific position within the crevice that is relatively distant from the crevice mouth with relatively low crevice gap. Both the grain boundary and grain matrix were oxidized. In the oxidized area, Fe and Ni were depleted and Cr was enriched compared to the matrix. Maximum penetration depth of the oxidation was approximately 50 m after 500 h. In order to understand potential-pH condition within the crevice, surface oxide layer was microscopically and thermodynamically investigated. Thermodynamic properties of the surface oxides near the intergranular oxidized area indicated lowered pH of approximately 3.2 to 3.4. In-situ measurement of local solution electrical conductivity was carried out using small electrodes (dia. 800 m) imbedded into the crevice former plate. The solution pH was estimated using theoretically calculated pH vs. electrical conductivity relationship. In the area where the intergranular oxidation occurred, the solution electrical conductivity was nearly 100 times higher than that of bulk water and which indicated lowered pH of approximately 3.5. The above results suggested that, in the high temperature and relatively high purity water, acidification occurs within crevice of stainless steels and such aggressive corrosion condition result in the intergranular oxidation.

Evaluation of susceptibility on crevice corrosion for ITER vacuum vessel

Nakahira, Masataka

JAERI-Tech 2003-083, 79 Pages, 2003/11

JAERI-Tech-2003-083.pdf:10.29MB

The ITER Vacuum Vessel has a double-walled structure and cooling water is filled in between inner and outer shells. It is planned to apply T-welded joints with partial penetration at the connection between outer shell and rib. The length and gap of non-penetrated part are controlled and limited to less than 5mm and 0.5mm respectively. Although it can be considered to be low susceptibility, crevice corrosion can possibly occur, because the water is stagnant in the crevice and impurities will condense. In this report, the corrosion-crevice repassivation potential, E, was experimentally measured under the several density of NaCl solution, and compared to the steady-state corrosion potential in the pertinent environment, to evaluate the susceptibility. Simulated conditions are normal operating condition with water temperature of 150C, baking operation with water temperature of 200C and impurity condense by cyclic wet and dry condition.

Main features of ITER vacuum vessel and approach to code application

Nakahira, Masataka; Takeda, Nobukazu; Hada, Kazuhiko; Tada, Eisuke; Miya, Kenzo*; Asada, Yasuhide*

Proceedings of 10th International Conference on Nuclear Engineering (ICONE 10) (CD-ROM), 7 Pages, 2002/04

The special features of Vacuum Vessel (VV) of International Thermonuclear Experimental Reactor (ITER) are complicated structure and electromagnetic load. The VV is torus shaped, double-walled structure with ribs. The electromagnetic force is not uniform. Thus the rules for axisymmetric structures and loading are not effective for ITER VV. The double ミwalled structure requires one-sided welding joints with no possibility of access from the other side. Every joints between outer wall and rib and field joints are this type. The joint between outer wall and rib is special T-joint with partial penetration. To cover these special issues on ITER VV, a new code is under development. Supporting R&Ds are planned to be material tests to obtain joint efficiency and fatigue reduction factor, UT sensitivity tests, sensitivity tests on crevice corrosion and examination-free welding for application to field joints. This paper describes the special features of ITER VV from code stand point, concept of new code and R&Ds to apply the new code to ITER VV.