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JAEA Reports

Background aerial monitoring and UAV radiation monitoring technology development for emergency response and preparedness in the fiscal year 2024 (Contract research)

Futemma, Akira; Ochi, Kotaro; Sasaki, Miyuki; Nakama, Shigeo; Kawasaki, Yoshiharu*; Iwai, Takeyuki*; Hiraga, Shogo*; Haginoya, Masashi*; Matsunaga, Yuki*; Sanada, Yukihisa; et al.

JAEA-Technology 2025-015, 171 Pages, 2026/03

JAEA-Technology-2025-015.pdf:11.43MB

On March 11, 2011, the 2011 off the Pacific coast of Tohoku Earthquake and tsunami caused the Fukushima Daiichi Nuclear Power Station accident, releasing radioactive material. Since then, Aerial Radiation Monitoring (ARM) with manned helicopters has been used to assess radiation distribution quickly. In FY2024, the Japan Atomic Energy Agency (JAEA), under commission from the Nuclear Regulation Authority, conducted ARM around the Shimane Nuclear Power Station, producing background dose rate maps validated against ground and other data. During a nuclear emergency drill, UAV training flights complemented manned monitoring, confirming the effectiveness of real-time communication and rapid mapping. The UAV data system was developed and demonstrated for real-time analysis and multi-platform use. Skill training for multicopters was also conducted to strengthen operational capability. Additionally, joint monitoring with the U.S., France, South Korea, and Canada provided insights into international technologies and practices, emphasizing the value of information sharing. This report summarizes the results and technical challenges from these FY2024 activities, contributing to the advancement of emergency radiation monitoring.

JAEA Reports

Introduction of classification considered as waste package for dismantling waste in JRTF

Nakajima, Ryota; Sakai, Tatsuya; Tani, Riku; Handa, Yuichi; Sunaoshi, Mizuho*; Inoue, Hidetaka*; Yamada, Satoshi; Shimizu, Osamu

JAEA-Technology 2025-012, 39 Pages, 2026/01

JAEA-Technology-2025-012.pdf:2.31MB

JAERI's Reprocessing Test Facility (JRTF) has transition to decommissioning since 1996 and inside the facility dismantled equipment and instrument. In the dismantling and removal work of glove boxes and other equipment, starting in October 2022, we prepared a "Manual for Separation of Dismantled Materials of JRTF" and carried out sorting and separation of the generated dismantled waste with the aim of producing waste package that meets the technical standards required for disposal to a landfill facility. This report describes the results and findings of sorting and separating the dismantled waste generated during the dismantling and removal work of glove boxes and other equipment in accordance with the "Manual for Separation of Dismantled Materials of JRTF".

JAEA Reports

Study on water stopping, repair and stabilization of lower PCV by geopolymer, etc. (Contract research); FY2023 Nuclear Energy Science & Technology and Human Resource Development Project

Collaborative Laboratories for Advanced Decommissioning Science; The University of Tokyo*

JAEA-Review 2025-008, 134 Pages, 2025/09

JAEA-Review-2025-008.pdf:10.0MB

The Collaborative Laboratories for Advanced Decommissioning Science (CLADS), Japan Atomic Energy Agency (JAEA), had been conducting the Nuclear Energy Science & Technology and Human Resource Development Project (hereafter referred to "the Project") in FY2023. The Project aims to contribute to solving problems in the nuclear energy field represented by the decommissioning of the Fukushima Daiichi Nuclear Power Station, Tokyo Electric Power Company Holdings, Inc. (TEPCO). For this purpose, intelligence was collected from all over the world, and basic research and human resource development were promoted by closely integrating/collaborating knowledge and experiences in various fields beyond the barrier of conventional organizations and research fields. The sponsor of the Project was moved from the Ministry of Education, Culture, Sports, Science and Technology to JAEA since the newly adopted proposals in FY2018. On this occasion, JAEA constructed a new research system where JAEA-academia collaboration is reinforced and medium-to-long term research/development and human resource development contributing to the decommissioning are stably and consecutively implemented. Among the adopted proposals in FY2021, this report summarizes the research results of the "Study on water stopping, repair and stabilization of lower PCV by geopolymer, etc." conducted from FY2021 to FY2023. Since the final year of this proposal was FY2023, the results for 3 fiscal years were summarized. In order to retrieve fuel debris, it is necessary to shut off the water at the bottom of the dry well and repair it in order to control the PCV water level. Therefore, in this study, we evaluated a construction method of stopping the water of the jet deflector with an improved geopolymer and repairing the lower part of the dry well by experiments and simulations. In addition, after understanding the properties of the fuel debris coated with the geopolymer, the long-term life of the waste body was evaluated. As a result, it was predicted that by utilizing geopolymers, it is possible to stop water and repair the lower part of the PCV in consideration of steps from construction to waste management.

Journal Articles

A Simple process simulation method for radiation stability evaluation of minor actinides separation

Toigawa, Tomohiro; Tsubata, Yasuhiro; Kumagai, Yuta; Ban, Yasutoshi

Progress in Nuclear Science and Technology (Internet), 8, p.286 - 290, 2025/09

We propose a simple process simulation methodology that uses readily available information about radiation impact. A process simulation was conducted for a minor actinides (MA) separation process while considering the degradation of extraction ability by radiolysis. The simulation provided a processing limit of MA and enabled the evaluation of radiation stability.

Journal Articles

Extraction, separation and isolation of MA from Ln using two extractants (TODGA and ADAAM) and a masking agent (DTBA)

Sasaki, Yuji; Kaneko, Masashi; Kumagai, Yuta; Ban, Yasutoshi

Progress in Nuclear Science and Technology (Internet), 8, p.202 - 204, 2025/09

Two extractants and a masking agent of TODGA (TetraOctyl-DiGlycolAmide), ADAAM (AlkylDiAmideAMine), and DTBA (DiethyleneTriamine-triacetic-BisAmide) were developed in JAEA. TODGA can extract both trivalent actinides (An) and lanthanides (Ln), DTBA may separate An from Ln, and ADAAM has high separation factor (SF: 6) for Am/Cm. The suitable conditions for the extraction, separation and isolations of An from Ln are investigated using these reagents. In this work, we show the basic information on extraction behavior of An and Ln using TODGA, DTBA and ADAAM and propose the suitable aqueous and the organic conditions for An+Ln extraction, An/Ln separation and Am/Cm separation.

Journal Articles

Separation of Am from lanthanides and Cm using the ADAAM(EH)-DTBA extraction system and elucidation of its complexation with DTBA through DFT calculations

Sasaki, Yuji; Kaneko, Masashi; Kumagai, Yuta; Ban, Yasutoshi

Solvent Extraction and Ion Exchange, 43(5-6), p.768 - 784, 2025/06

 Times Cited Count:0 Percentile:0.00(Chemistry, Multidisciplinary)

We developed a method called the alkyl-diamide amine (ADAAM(EH))-diethylenetriamine-triacetic acid-bis(diethylacetamide) (DTBA) technique for separating actinide (An) and lanthanide (Ln) elements from high-level liquid waste. ADAAM(EH) exhibits a high separation factor (SF) not only for Am/Cm but also for light/heavy Ln under acidic conditions (1.5 M HNO$$_{3}$$). Consequently, Am can be separated from Cm as well as from middle Ln (Sm, Eu, and Gd) using ADAAM(EH) as an extractant. DTBA enables the stripping of Am and potentially separates it from Ln in the organic phase at low pH ($$<$$ 2). The lowest SF among the light Ln, observed for Nd/Am, exceeded 10, indicating that Am can be separated from light Ln by stripping using DTBA from the ADAAM(EH) extraction solvent. The density functional theory calculations for understanding the coordination bond properties of metal-DTBA complexes are performed, which supported higher affinity of DTBA toward Am than Nd.

JAEA Reports

Background aerial monitoring and UAV radiation monitoring technology development for emergency response and preparedness in fiscal year 2023 (Contract research)

Futemma, Akira; Sanada, Yukihisa; Nakama, Shigeo; Sasaki, Miyuki; Ochi, Kotaro; Sawahata, Yoshiro*; Kawasaki, Yoshiharu*; Iwai, Takeyuki*; Hiraga, Shogo*; Haginoya, Masashi*; et al.

JAEA-Technology 2024-022, 170 Pages, 2025/03

JAEA-Technology-2024-022.pdf:15.09MB

On March 11, 2011, the 2011 off the Pacific coast of Tohoku Earthquake caused a tsunami that led to the Fukushima Daiichi Nuclear Power Station accident, releasing radioactive material into the environment. Since then, Aerial Radiation Monitoring (ARM) using manned helicopters has been employed to measure radiation distribution. As a commissioned project from the Nuclear Regulation Authority, the Japan Atomic Energy Agency (JAEA) utilizes this technology for emergency monitoring during nuclear facility accidents, aiming to provide prompt results by pre-arranging information on background radiation, topography, and control airspaces around nuclear power plants nationwide. In fiscal year 2023, the commissioned project included conducting ARM around the Sendai Nuclear Power Station and preparing related information. To enhance effectiveness during emergencies, ARM and the first domestic training flight of Unmanned Aerial Vehicles (UAVs) were conducted during the FY2023 Nuclear Energy Disaster Prevention Drill. Furthermore, UAVs radiation monitoring technology was advanced by selecting UAVs and investigating their performance. This report summarizes the results and technical issues identified providing insights to improve emergency preparedness.

Journal Articles

Development of corrosion-stable dual-Si-layered membranes for hydrogen production via thermochemical iodine-sulfur process

Myagmarjav, O.; Tanaka, Nobuyuki; Noguchi, Hiroki; Kamiji, Yu; Ono, Masato; Nomura, Mikihiro*; Takegami, Hiroaki

Progress in Nuclear Science and Technology (Internet), 7, p.235 - 242, 2025/03

JAEA Reports

Study on water stopping, repair and stabilization of lower PCV by geopolymer, etc. (Contract research); FY2022 Nuclear Energy Science & Technology and Human Resource Development Project

Collaborative Laboratories for Advanced Decommissioning Science; The University of Tokyo*

JAEA-Review 2024-021, 126 Pages, 2024/11

JAEA-Review-2024-021.pdf:6.51MB

The Collaborative Laboratories for Advanced Decommissioning Science (CLADS), Japan Atomic Energy Agency (JAEA), had been conducting the Nuclear Energy Science & Technology and Human Resource Development Project (hereafter referred to "the Project") in FY2022. The Project aims to contribute to solving problems in the nuclear energy field represented by the decommissioning of the Fukushima Daiichi Nuclear Power Station, Tokyo Electric Power Company Holdings, Inc. (TEPCO). For this purpose, intelligence was collected from all over the world, and basic research and human resource development were promoted by closely integrating/collaborating knowledge and experiences in various fields beyond the barrier of conventional organizations and research fields. The sponsor of the Project was moved from the Ministry of Education, Culture, Sports, Science and Technology to JAEA since the newly adopted proposals in FY2018. On this occasion, JAEA constructed a new research system where JAEA-academia collaboration is reinforced and medium-to-long term research/development and human resource development contributing to the decommissioning are stably and consecutively implemented. Among the adopted proposals in FY2021, this report summarizes the research results of the "Study on water stopping, repair and stabilization of lower PCV by geopolymer, etc" conducted in FY2022. The present study aims to propose a construction method to stop jet deflectors by improved geopolymer and ultra-heavy muddy water, and to repair the lower part of the dry well. In addition, in order to increase the options for on-site construction in unknown situations such as deposition conditions, we will examine a wide range of construction outside the pedestal, and evaluate the feasibility of the construction method by the latest thermal flow simulation method.

Journal Articles

Improved extraction efficiency of radioactive copper produced via accelerator neutrons method through phosphate buffer-enhanced column pre-treatment

Mikhail, M. A. G.*; Kin, Tadahiro*; Eto, Taisei*; Tsukada, Kazuaki

Scientific Reports (Internet), 14, p.27132_1 - 27132_10, 2024/11

 Times Cited Count:0 Percentile:0.00(Multidisciplinary Sciences)

We have studied a straightforward and robust single-step cation exchange separation method to isolate medical copper radioisotopes $$^{64}$$Cu and $$^{67}$$Cu produced in the $$^{nat}$$Zn(n, x) reaction with an accelerator neutrons technique. This study revealed the key role of a phosphate buffer pre-treatment of the cation exchange column in the separation process. It was found that incorporating the phosphate buffer into the column pre-treatment markedly enhances the retention of copper isotopes within the column throughout the separation procedure. This approach yields a high-purity radioactive copper sample with a high extraction efficiency of 94.4% of the initially produced copper, all within a relatively short experimental time frame of approximately 5 h for 100 g of starting material.

Journal Articles

Uranium-plutonium-oxygen phase diagram; Investigating the solvus of fluorite's exsolution

Vauchy, R.; Hirooka, Shun; Horii, Yuta; Ogasawara, Masahiro*; Sunaoshi, Takeo*; Yamada, Tadahisa*; Tamura, Tetsuya*; Murakami, Tatsutoshi

Journal of Nuclear Materials, 599, p.155233_1 - 155233_11, 2024/10

 Times Cited Count:2 Percentile:49.81(Materials Science, Multidisciplinary)

The fluorite exsolution/recombination in U$$_{1-y}$$Pu$$_{y}$$O$$_{2-x}$$ (y = 0.30 and 0.45) and PuO$$_{2-x}$$ was investigated using differential scanning calorimetry. The results are in relatively good agreement with the literature data, except for plutonia. Our values indicate that the critical temperature of the miscibility gap in Pu-O is 30$$sim$$50 K lower than previously reported. Finally, the systematic experimental procedure allowed us refining the locus of the solvus existing in hypostoichiometric U$$_{0.70}$$0Pu$$_{0.30}$$O$$_{2-x}$$, U$$_{0.55}$$Pu$$_{0.45}$$O$$_{2-x}$$, and PuO$$_{2-x}$$ dioxides.

Journal Articles

Mutual separation of Am and Cm using ADAAM (alkyl DiAmide AMine) and reduction of volumes for liquid waste generated via batch-wise multistage extractions

Sasaki, Yuji; Kaneko, Masashi; Ban, Yasutoshi; Suzuki, Hideya*

Journal of Nuclear Science and Technology, 61(7), p.883 - 893, 2024/07

 Times Cited Count:5 Percentile:66.06(Nuclear Science & Technology)

The mutual separation of Am and Cm is conducted using an alkyl-diamide amine (ADAAM) extractant. ADAAM exhibits extremely high separation factor with respect to Am and Cm separation (5.9) in a nitric acid-$$n$$-dodecane system. The batch-wise multistage extractions are performed using a system containing 0.2 M ADAAM and 1.5 M nitric acid. In this multistage extraction, an organic solvent give 96.5% and 1.06% yields of Am and Cm. After the mutual separation of Am and Cm, an additional extraction step is included to reduce the volumes of these aqueous and organic phases. Taking these steps, Am and Cm can be recovered in just two or three stages in the aqueous phases.

JAEA Reports

Background radiation monitoring via manned helicopter and development of technology for radiation monitoring via unmanned airplane for application of nuclear emergency response technique in the fiscal year 2022 (Contract research)

Futemma, Akira; Sanada, Yukihisa; Sasaki, Miyuki; Kawasaki, Yoshiharu*; Iwai, Takeyuki*; Hiraga, Shogo*; Haginoya, Masashi*; Matsunaga, Yuki*; Akutsu, Yuichiro*; Arai, Yoshinori*; et al.

JAEA-Technology 2023-026, 161 Pages, 2024/03

JAEA-Technology-2023-026.pdf:14.66MB

By the accident at Tokyo Electric Power Company's (TEPCO's) Fukushima Daiichi Nuclear Power Station (FDNPS), caused by tsunami triggered by the 2011 off the Pacific coast of Tohoku Earthquake, a large amount of radioactive material was released into the surrounding environment. After the accident, Airborne Radiation Monitoring (ARM) via manned helicopter has been utilized as a method to quickly and extensively measure radiation distribution surrounding FDNPS. In order to utilize ARM and to promptly provide the results during a nuclear emergency, information on background radiation levels, topographical features, and controlled airspace surrounding nationwide nuclear facilities have been prepared in advance. In the fiscal year 2022, we conducted ARM around the Mihama Nuclear Power Station of Kansai Electric Power Company (KEPCO), the Tsuruga Power Station of Japan Atomic Power Company (JAPC), and the Ikata Power Station of Shikoku Electric Power Company (YONDEN), and prepared information on background radiation doses and controlled airspace. In addition, we have developed an aerial radiation detection system via unmanned airplane, which is expected to be an alternative to ARM, during a nuclear emergency. This report summarizes the results and technical issues identified.

JAEA Reports

Survey and proposal for Japanese-English bilingual translation of technical terms focusing on nuclear disaster prevention

Togawa, Orihiko; Okuno, Hiroshi

JAEA-Review 2023-043, 94 Pages, 2024/03

JAEA-Review-2023-043.pdf:1.53MB

In order to translate nuclear disaster prevention documents written in Japanese into English, the Basic Act on Disaster Management, the Act on Special Measures Concerning Nuclear Emergency Preparedness, and the Convention on Nuclear Safety were surveyed for corresponding terms in Japanese and English. The survey results were integrated and unified English translations were selected. As a result, a Japanese-English correspondence table of technical terms in the field of nuclear disaster prevention was prepared and proposed.

JAEA Reports

Analysis of the radioactivity concentrations in radioactive waste generated from JRR-3, JRR-4 and JRTF facilities, 2

Tobita, Minoru*; Goto, Katsunori*; Omori, Takeshi*; Osone, Osamu*; Haraga, Tomoko; Aono, Ryuji; Konda, Miki; Tsuchida, Daiki; Mitsukai, Akina; Ishimori, Kenichiro

JAEA-Data/Code 2023-011, 32 Pages, 2023/11

JAEA-Data-Code-2023-011.pdf:0.93MB

Radioactive wastes generated from nuclear research facilities in Japan Atomic Energy Agency are planning to be buried in the near surface disposal field as trench and pit. Therefore, it is required to establish the method to evaluate the radioactivity concentrations of radioactive wastes until the beginning of disposal. In order to contribute to the study of radioactivity concentration evaluation methods for radioactive wastes generated from nuclear research facilities, we collected and analyzed concrete samples generated from JRR-3, JRR-4 and JAERI Reprocessing Test Facility. In this report, we summarized the radioactivity concentrations of 23 radionuclides ($$^{3}$$H, $$^{14}$$C, $$^{36}$$Cl, $$^{41}$$Ca, $$^{60}$$Co, $$^{63}$$Ni, $$^{90}$$Sr, $$^{94}$$Nb, $$^{rm 108m}$$Ag, $$^{137}$$Cs, $$^{133}$$Ba, $$^{152}$$Eu, $$^{154}$$Eu, $$^{rm 166m}$$Ho, $$^{234}$$U, $$^{235}$$U, $$^{238}$$U, $$^{238}$$Pu, $$^{239}$$Pu, $$^{240}$$Pu, $$^{241}$$Am, $$^{243}$$Am, $$^{244}$$Cm) which were obtained from radiochemical analysis of the samples in fiscal years 2021-2022.

Journal Articles

Status on the development of the fabrication and analysis equipment of the pseudo fuel debris

Kobayashi, Fuyumi; Fukaya, Hiroyuki; Izawa, Kazuhiko; Kida, Takashi; Sono, Hiroki; Suyama, Kenya

Proceedings of 12th International Conference on Nuclear Criticality Safety (ICNC2023) (Internet), 7 Pages, 2023/10

In the criticality experiment in the new STACY, pseudo fuel debris samples are used to acquire data for validation of the system used for 1F debris criticality safety assessment. The pseudo fuel debris is a pellet with a diameter of 8 mm and a height of 10 mm containing uranium oxide and structural materials (iron, silicon, zirconium, etc.). The pellets are made by mixing, pressing and sintering uranium dioxide powder and structural materials powder. The UO$$_{2}$$ powder uses the same composition of uranium as the STACY driver fuel rods, in order to reduce the errors in fuel composition. The pseudo fuel debris fabrication devices and analysis equipment are installed at the BECKY in order to evaluate the critical properties of fuel debris with high accuracy in dimension and analysis. This equipment is located in the same laboratory and can quickly respond to experimental needs such as preparation of the pseudo fuel debris and analysis before and after irradiation.

JAEA Reports

Introduce of friction model into fuel pin bundle deformation analysis code "BAMBOO"

Uwaba, Tomoyuki; Ito, Masahiro*; Ishitani, Ikuo*

JAEA-Technology 2023-006, 36 Pages, 2023/05

JAEA-Technology-2023-006.pdf:3.45MB

The BAMBOO code developed by the Japan Atomic Energy Agency is a computer code to analyze fuel pin bundle deformation in a fast reactor wire-spaced type fuel pin bundle subassembly. In this study we developed an analysis model to consider friction at the contact points between adjacent fuel pins, and at these between outermost fuel pins and a duct that are due to bundle-duct interaction. This model deals with friction forces at contact points in the contact and separation analysis of the code, and employs a convergent calculation where contact forces are gradually determined to avoid numerical instability when the friction occurs. Analyses of BAMBOO with the model showed very slight effects on the onset of contact between outer most pins and a duct, and on directions of pin displacements, within the range of practical friction coefficients.

JAEA Reports

Analysis of the radioactivity concentrations in radioactive waste generated from JRR-2, JRR-3 and Hot laboratory

Aono, Ryuji; Mitsukai, Akina; Tsuchida, Daiki; Konda, Miki; Haraga, Tomoko; Ishimori, Kenichiro; Kameo, Yutaka

JAEA-Data/Code 2023-002, 81 Pages, 2023/05

JAEA-Data-Code-2023-002.pdf:3.0MB

Radioactive wastes generated from nuclear research facilities in Japan Atomic Energy Agency are planning to be buried in the near surface disposal field as trench and pit. Therefore, it is required to establish the method to evaluate the radioactivity concentrations of radioactive wastes until the beginning of disposal. In order to contribute to this work, we collected and analyzed the samples generated from JRR-2, JRR-3 and Hot laboratory facilities. In this report, we summarized the radioactivity concentrations of 20 radionuclides ($$^{3}$$H, $$^{14}$$C, $$^{36}$$Cl, $$^{60}$$Co, $$^{63}$$Ni, $$^{90}$$Sr, $$^{94}$$Nb, $$^{99}$$Tc, $$^{rm 108m}$$Ag, $$^{129}$$I, $$^{137}$$Cs, $$^{152}$$Eu, $$^{154}$$Eu, $$^{234}$$U, $$^{238}$$U, $$^{238}$$Pu, $$^{239}$$Pu, $$^{240}$$Pu, $$^{241}$$Am, $$^{244}$$Cm) which were obtained from radiochemical analysis of the samples in fiscal year 2020.

JAEA Reports

Study on water stopping, repair and stabilization of lower PCV by geopolymer, etc. (Contract research); FY2021 Nuclear Energy Science & Technology and Human Resource Development Project

Collaborative Laboratories for Advanced Decommissioning Science; The University of Tokyo*

JAEA-Review 2022-062, 121 Pages, 2023/03

JAEA-Review-2022-062.pdf:4.78MB

The Collaborative Laboratories for Advanced Decommissioning Science (CLADS), Japan Atomic Energy Agency (JAEA), had been conducting the Nuclear Energy Science & Technology and Human Resource Development Project (hereafter referred to "the Project") in FY2021. The Project aims to contribute to solving problems in the nuclear energy field represented by the decommissioning of the Fukushima Daiichi Nuclear Power Station, Tokyo Electric Power Company Holdings, Inc. (TEPCO). For this purpose, intelligence was collected from all over the world, and basic research and human resource development were promoted by closely integrating/collaborating knowledge and experiences in various fields beyond the barrier of conventional organizations and research fields. The sponsor of the Project was moved from the Ministry of Education, Culture, Sports, Science and Technology to JAEA since the newly adopted proposals in FY2018. On this occasion, JAEA constructed a new research system where JAEA-academia collaboration is reinforced and medium-to-long term research/development and human resource development contributing to the decommissioning are stably and consecutively implemented. Among the adopted proposals in FY2021, this report summarizes the research results of the "Study on water stopping, repair and stabilization of lower PCV by geopolymer, etc." conducted in FY2021. The present study aims to propose a construction method to stop jet deflectors by improved geopolymer and ultra-heavy muddy water, and to repair the lower part of the dry well. In addition, in order to increase the options for on-site construction in unknown situations such as deposition conditions, we will examine a wide range of construction outside the pedestal, and evaluate the feasibility of the construction method by the latest thermal flow simulation method. When widely constructed, fuel debris and deposits discharged out of the pedestal are coated with water stop and repair materials and become waste ...

Journal Articles

Americium(III)/curium(III) complete separation and sensitive fluorescence detection by capillary and gel electrophoresis using emissive hexadentate/octadentate polyaminocarboxylate ligands

Saito, Shingo*; Haraga, Tomoko; Marumo, Kazuki*; Sato, Yoshiyuki; Nakano, Yuta*; Tasaki-Handa, Yuiko*; Shibukawa, Masami*

Bulletin of the Chemical Society of Japan, 96(3), p.223 - 225, 2023/03

 Times Cited Count:3 Percentile:21.52(Chemistry, Multidisciplinary)

Highly efficient and effective separation between americium (Am$$^{3+}$$) and curium ion (Cm$$^{3+}$$) was achieved by two simple electrophoresis-based techniques. Am$$^{3+}$$ and Cm$$^{3+}$$ ions were complexed with fluorophore-modified acyclic hexadentate and octadentate polyaminocarboxylates and then were electrophoretically separated and fluorescently detected in free solution with ternary complexation or in gel medium.

396 (Records 1-20 displayed on this page)