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transitionsYang, Q.*; Yang, X.*; Wang, Y.*; Fei, Y.*; Li, F.*; Zheng, H.*; Li, K.*; Han, Y.*; Hattori, Takanori; Zhu, P.*; et al.
Nature Communications (Internet), 15, p.7778_1 - 7778_9, 2024/09
Times Cited Count：16 Percentile：91.89(Multidisciplinary Sciences)Luminescent materials that simultaneously embody bright singlet and triplet excitons hold great potential in optoelectronics, signage, and information encryption. However, achieving high-performance white-light emission is severely hampered by their inherent unbalanced contribution of fluorescence and phosphorescence. Herein, we address this challenge by pressure treatment engineering via hydrogen bonding cooperativity effect to realize the mixture of n-- transitions, where the triplet state emission was boosted from 7% to 40% in isophthalic acid (IPA). A superior white-light emission based on hybrid fluorescence and phosphorescence was harvested in pressure-treated IPA, and the photoluminescence quantum yield was increased to 75% from the initial 19% (blue-light emission). In-situ high-pressure IR spectra, X ray diffraction, and neutron diffraction reveal continuous strengthening of the hydrogen bonds with the increase of pressure. Furthermore, this enhanced hydrogen bond is retained down to the ambient conditions after pressure treatment, awarding the targeted IPA efficient intersystem crossing for balanced singlet/triplet excitons population and resulting in efficient white-light emission. This work not only proposes a route for brightening triplet states in organic small molecule, but also regulates the ratio of singlet and triplet excitons to construct high-performance white-light emission.
Kunieda, Satoshi; Ichihara, Akira
JAERI-Data/Code 2005-005, 33 Pages, 2005/09
JAERI-Data-Code-2005-005.pdf:1.5MB
The computer code, POD-P, was developed to calculate energy spectra and angular distributions of emitted particles for the neutron-induced preequiliblium nuclear reactions. The energy-differential cross sections are computed with the classical one-component exciton model for the nucleon and composite-particle emissions. Along with this, the semi-empirical exciton models are also used for the composite-particle emissions. The double-differential cross sections are derived from those model calculations plus the angular-distribution systematics. The computational method and explanation of input parameters are given with some output examples.
JAERI-M 92-122, 34 Pages, 1992/08
no abstracts in English
Baba, Yuji; G.Dujardin*; P.Feulner*; D.Menzel*
Hyomen Kagaku, 13(5), p.244 - 248, 1992/07
no abstracts in English
