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Journal Articles

A New simultaneous measurement system of wide Q-range small angle neutron scattering combined with polarized Fourier transform infrared spectroscopy

Kaneko, Fumitoshi*; Kawaguchi, Tatsuya*; Radulescu, A.*; Iwase, Hiroki*; Morikawa, Toshiaki*; Takata, Shinichi; Nishiura, Masayoshi*; Hou, Z.*

Review of Scientific Instruments, 90(9), p.093906_1 - 093906_6, 2019/09

 Times Cited Count:3 Percentile:17.23(Instruments & Instrumentation)

Journal Articles

FT-IR study on interaction of irradiated deuteron with defects in Li$$_{2}$$O

Tanigawa, Hisashi; Tanaka, Satoru*; Enoeda, Mikio; Akiba, Masato

Journal of Nuclear Materials, 329-333(2), p.1291 - 1294, 2004/08

 Times Cited Count:4 Percentile:29.17(Materials Science, Multidisciplinary)

In order to elucidate the interaction of hydrogen isotopes with irradiation defects, infrared absorption spectroscopy was conducted for a single crystal of Li$$_{2}$$O. Using FT-IR, O-D stretching vibration from the bulk Li$$_{2}$$O was observed under deutron irradiation. Under and after the irradiation, several peaks were observed in the O-D stretching vibration region and these peaks had different dependence on conditions of the irradiation. From the observed behaviour of the peaks, it was suggested that most of the irradiated deutron existed in Li$$_{2}$$O without O-D bonding because of interaction with the defects.

Journal Articles

Characterizations of heavy ion irradiated PET membranes

Takahashi, Shuichi*; Yoshida, Masaru; Asano, Masaharu; Notomi, Mitsuo*; Nakagawa,Tsutomu*

Nuclear Instruments and Methods in Physics Research B, 217(3), p.435 - 441, 2004/05

 Times Cited Count:15 Percentile:68.07(Instruments & Instrumentation)

Various characterization were used to study the effect of heavy ion irradiation on a poly(ethylen terephthalate)(PET) membrane. My study was followed using some dynamic and thermal measurements with the aim to undestand the chemical change in the material by heavy ion irradiation. The anyalyese included DMA, tensile measurement, DSC and micro-FT-IR. The overall structure change in the PET polymer was investigated as a function of the Xe ion fluence in the range from 3$$times$$10$$^{3}$$ to 3$$times$$10$$^{9}$$ions/cm$$^{2}$$. Based on some mechanical measurements such as the tensile analysis and dynamic test, the heavy ion irradiated PET membranes exhibited a significant change in cross-linking. I believe that the secondary electron induced by collision between the irradiated ion and the constituent atoms of the membrane material form the cross-linking. The polymer chain scission and structure degradations are expected to result at higher ion fluence. Also, a slight change in the structure such as amorphization has been shown by DSC and the micro-FT-IR test.

Journal Articles

Volume phase transitions of pyly(acryloyl-L-proline methyl ester) gels in response to water-alcohol composition

Hiroki, Akihiro*; Maekawa, Yasunari; Yoshida, Masaru; Kubota, Kenji*; Katakai, Ryoichi*

Polymer, 42(5), p.1863 - 1867, 2000/12

 Times Cited Count:41 Percentile:79.48(Polymer Science)

no abstracts in English

Journal Articles

Distribution of products in polymer materials induced by ion-beam irradiation

Sugimoto, Masaki; Kudo, Hisaaki; Sasuga, Tsuneo; Seguchi, Tadao; Hama, Yoshimasa*; Hamanaka, Kenichi*; Matsumoto, Hideya*

JAERI-Conf 97-003, p.269 - 272, 1997/03

no abstracts in English

Journal Articles

A Study on irradiation-induced structural change of lithium orthosilicate by infrared spectroscopy analysis with MNDO calculation

; Yamaki, Daiju; Noda, Kenji

Journal of Nuclear Materials, 248, p.121 - 127, 1997/00

 Times Cited Count:9 Percentile:59.68(Materials Science, Multidisciplinary)

no abstracts in English

Journal Articles

Journal Articles

Micro profile of the chemical structure in ion-beam irradiation effects for some polyolefins

Hama, Yoshimasa*; ; Hamanaka, Kenichi*; Matsumoto, Hideya*; Kudo, Hisaaki; Sasuga, Tsuneo; Seguchi, Tadao;

Proceedings of of the Yayoi Symposium on Ion-Beam Radiation Chemistry; NIRS-M-101, HIMAC-007, 0, p.9 - 12, 1994/00

no abstracts in English

Journal Articles

Detection of radiation degradation of polymer by micro-area FT-IR spectrometer

Matsumoto, Hideya*; ; Hama, Yoshimasa*; Kudo, Hisaaki; Sasuga, Tsuneo; Seguchi, Tadao

DEI-93-153, 0(0), p.1 - 8, 1993/12

no abstracts in English

Journal Articles

Speciation of uranium in aqueous solutions and in precipitates by photoacoustic spectroscopy

Kimura, Takaumi; J.G.Serrano*; ; ; Takeishi, Hideyo

Radiochimica Acta, 58-59, p.173 - 178, 1992/00

no abstracts in English

Journal Articles

Applications of photoacoustic spectroscopy to speciation of lanthanide elements in aqueous solutions and of solid phase

; Kimura, Takaumi

Journal of Nuclear Science and Technology, 28(8), p.780 - 783, 1991/08

no abstracts in English

Journal Articles

Development of photoacoustic spectroscopy for speciation of actinide elements in aqueous solution and in solid phase

Kimura, Takaumi;

3rd Int. Symp. on Advanced Nuclear Energy Research; Global Environment and Nuclear Energy, 6 Pages, 1991/00

no abstracts in English

Journal Articles

Comparison of 80keV D$$^{+}$$ ion implantation with thermal D$$_{2}$$ doping in silica by FTIR and ESR spectroscopy

Saeki, Masakatsu; Ono, Shinichi; Tachikawa, Enzo; ; ;

J.Am.Ceram.Soc., 68(3), p.151 - 155, 1985/00

 Times Cited Count:8 Percentile:61.05(Materials Science, Ceramics)

no abstracts in English

Oral presentation

Fundamental research on thermal decomposition behavior of sodium hydride

Kawaguchi, Munemichi

no journal, , 

This study presents the fundamental research on the thermal decomposition behavior of sodium hydride (NaH) in FY2021. This study on the thermal decomposition behavior of NaH was carried out using TG-DTA and FT-IR for the decommissioning of the cold trap in Monju. Due to the weak ionic bonding of Na-H in NaH, the hydrogen is enable to move easily at close to 565K. Upon further heating, the hydrogen desorbs by the thermal decomposition. A simple model using each kinetic rate equations ($$k_1$$, $$k_2$$, $$k_3$$) can give us the quantitative evaluation of the thermal decomposition behavior of NaH, which tended to overestimated the Na evaporation.

Oral presentation

Development of halide salt stabilization technology

Takahatake, Yoko; Watanabe, So; Nakamura, Masahiro

no journal, , 

Contaminated bath salts, such as LiCl-KCl and NaCl-2CsCl, are generated by pyroprocessing. The halide salts should be decontaminated in advance with disposal. Since Cl cause corrosion of equipment, pipes and containers, Cl in the wastes has to be chemically stabilized. In this study, we focused on chlorapatite which is natural mineral containing Cl, and synthesis of the chlorapatite and verification Cl stability in the products were conducted. Regents as Ca and P sources, and CsCl were mixed, and then heated with various temperature conditions. Leaching test on the products with pure water was carried out. A part of Cl in the products was remained after the test. FT-IR analysis on the product suggested formation of P-Cl bonds, and the formation must be one of the encapsulation mechanisms of Cl inside the natural ore.

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