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Journal Articles

Pressure-induced polar phases in multiferroic delafossite CuFeO$$_{2}$$

Terada, Noriki*; Khalyavin, D. D.*; Manuel, P.*; Osakabe, Toyotaka; Radaelli, P. G.*; Kitazawa, Hideaki*

Physical Review B, 89(22), p.220403_1 - 220403_6, 2014/06

AA2014-0251.pdf:1.02MB

 Times Cited Count:30 Percentile:72.57(Materials Science, Multidisciplinary)

We have studied the pressure effect on the magnetic orderings in the strongly frustrated antiferromagnet CuFeO$$_{2}$$, by using neutron diffraction experiments under hydrostatic pressure. The main result is elucidation of the pressure-temperature magnetic phase diagram, consisting of the fourmagnetic phases including two polar ones. In particular, in the 3 GPa $$<$$ P $$<$$ 4 GPa pressure range, the ICM2 phase with the proper screw magnetic ordering stabilized. This polar phase is almost identical to the ferroelectric incommensurate (FEIC) phase induced by either a magnetic field or chemical doping. Furthermore, above 4 GPa, a new low-symmetry phase ICM3 is realized. This is unique for the family of delafossite multiferroics and implies an admixture of both cycloidal and proper screw spin configurations. The sequence of the observed magnetic phases with changing pressure might be attributed to pressure suppression of the monoclinic lattice distortions responsible for releasing the spin frustration in the system.

Journal Articles

Structure analysis of cation selective Cr-goethite as protective rust of weathering steel

Konishi, Hiroyuki; Yamashita, Masato*; Uchida, Hitoshi*; Mizuki, Junichiro

Materials Transactions, 46(2), p.337 - 341, 2005/02

 Times Cited Count:11 Percentile:60.23(Materials Science, Multidisciplinary)

We have performed extended X-ray absorption fine structure (EXAFS) analysis for artificial Cr-goethite to elucidate the local structure around Cr in Cr-goethite. The spectra were obtained using synchrotron radiation X-rays at the Photon Factory in Tsukuba. The first shell contributions were isolated by Fourier filtering the EXAFS data, and the inverse Fourier transformed single-shell data were analyzed using curve fitting method. The results show that Cr is coordinated with (7$$pm$$1) O$$^{2-}$$ ions. The protective character of Cr-goethite protective rust layer on weathering steel can be interpreted in terms of the O$$^{2-}$$ coordination around Cr$$^{3+}$$ resulting in creation of negative fixed-charge in the Cr-goethite particles.

Journal Articles

Effects of basicity and FeO concentration on the retention of $$^{137}$$Cs and $$^{60}$$Co in slag made from non-metallic radioactive wastes

Nakashima, Mikio; Nakashio, Nobuyuki; Kameo, Yutaka; Fukui, Toshiki*; Isobe, Motoyasu*; Otake, Atsushi*; Wakui, Takuji*; Hirabayashi, Takakuni*

Radiochimica Acta, 91(1), p.45 - 51, 2003/01

 Times Cited Count:2 Percentile:18.28(Chemistry, Inorganic & Nuclear)

no abstracts in English

JAEA Reports

Study on melting coditions of radioactive miscellaneous solid waste (Contract research)

Fukui, Toshiki; Nakashio, Nobuyuki; Isobe, Motoyasu; Otake, Atsushi*; Wakui, Takuji*; Hirabayashi, Takakuni*; Nakashima, Mikio

JAERI-Review 2000-033, 82 Pages, 2001/02

JAERI-Review-2000-033.pdf:2.61MB

no abstracts in English

Journal Articles

Analysis of corrosion products of carbon steel in wet bentonite

; Nagano, Tetsushi; Muraoka, Susumu

Hoshasei Haikibutsu Kenkyu Renrakukai Rombunshu (VI), p.53 - 63, 1991/00

no abstracts in English

Journal Articles

Chemical effects of thermal neutron irradiation on $$alpha$$-LiFeO$$_{2}$$

Aratono, Yasuyuki; Sagawa, Chiaki; Nakashima, Mikio; Saeki, Masakatsu;

Chemistry Letters, 1990, p.35 - 38, 1990/00

no abstracts in English

Journal Articles

Residence time of crud on surface of channel box in JPDR

; Tachikawa, Enzo; ; ;

Journal of Nuclear Science and Technology, 24(4), p.297 - 307, 1987/04

 Times Cited Count:4 Percentile:44.48(Nuclear Science & Technology)

no abstracts in English

Journal Articles

Compatibility between several heat resistant alloys and sintered Li$$_{2}$$O in static helium gas environment

Kurasawa, T.; ;

J. Nucl. Mater., 92(1), p.67 - 72, 1980/00

 Times Cited Count:5 Percentile:53.19(Materials Science, Multidisciplinary)

no abstracts in English

Journal Articles

Reaction of several iron and nickel based alloys with sin-tered Li$$_{2}$$O pellets

Kurasawa, T.; ; ; ; ;

J. Nucl. Mater., 80(1), p.48 - 56, 1979/00

 Times Cited Count:13

no abstracts in English

Journal Articles

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