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Gu, G. H.*; Ha, H.*; Harjo, S.; Gong, W.; Louzguine-Luzgin, D. V.*; Kim, H. S.*
Materials Science & Engineering A, 943, p.148818_1 - 148818_10, 2025/10
被引用回数：4 パーセンタイル：60.79(Nanoscience & Nanotechnology)High-strength structural alloys are essential for advanced engineering. This study explores the mechanical behavior of a dual-phase AlCoNiV medium-entropy alloy (MEA) with FCC and BCC phases. The alloy shows excellent performance, with a yield strength of 1148 MPa, tensile strength of 1556 MPa, and 40% uniform elongation. In-situ neutron diffraction and EBSD analyses reveal that strength originates from the intrinsic responses of both phases. The BCC phase carries more load, while dislocation buildup at phase boundaries enhances strength via hetero-deformation-induced (HDI) strengthening. Synergistic effects, including stress partitioning and load redistribution, further improve mechanical performance. These findings highlight the role of phase-specific properties and interphase interactions in alloy robustness and offer insights for microstructural optimization.
Harjo, S.
日本結晶学会誌, 65(3), p.178 - 182, 2023/08
Observations of deformation behavior of high entropy alloys using 
neutron diffraction measurements during deformation at various temperatures are reviewed. Neutrons are used to investigate stresses and crystallographic microstructures inside engineering materials, taking advantage of their large penetrating power and the ability to see the arrangement of atoms by diffraction methods. The important structural details of high entropy alloys such as internal stresses, phase conditions, dislocations, texture etc. are discussed in relation to the deformation conditions. Some highlights are introduced: (a) Cooperative deformation in CrMnFeCoNi alloy at ultralow temperatures, (b) Stacking fault energies in CrFeCoNi and CrCoNi alloys, and (c) Load redistribution in eutectic high entropy alloy AlCoCrFeNi
during high temperature deformation.
Lobzenko, I.; 都留 智仁; 他2名*
Computational Materials Science, 219, p.112010_1 - 112010_9, 2023/02
被引用回数：7 パーセンタイル：39.88(Materials Science, Multidisciplinary)To elucidate the origin of excellent mechanical properties of high-entropy alloys (HEA), it is essential to develop the atomic-level depiction of defect structures considering the effects of the constituent elements. While classical molecular dynamics have been one of the most effective tools for understanding the defect structures from the atomic level, there is still a problem with the accuracy of the inter-atomic potential of complicated alloy systems such as HEA. A new technique for building such potentials based on machine learning was recently developed. We employed the technique and constructed highly accurate potentials with good robustness for two BCC medium-entropy alloys: MoNbTa and ZrNbTa. Atomic simulation based on the new potentials indicate significant differences in the fundamental mechanical properties of two alloys, depending on the constituent elements, that dominate deformation behavior.
Naeem, M.*; He, H.*; Zhang, F.*; Huang, H.*; Harjo, S.; 川崎 卓郎; Wang, B.*; Lan, S.*; Wu, Z.*; Wang, F.*; et al.
Science Advances (Internet), 6(13), p.eaax4002_1 - eaax4002_8, 2020/03
被引用回数：302 パーセンタイル：99.44(Multidisciplinary Sciences)High-entropy alloys exhibit exceptional mechanical properties at cryogenic temperatures, due to the activation of twinning in addition to dislocation slip. The coexistence of multiple deformation pathways raises an important question regarding how individual deformation mechanisms compete or synergize during plastic deformation. Using in situ neutron diffraction, we demonstrate the interaction of a rich variety of deformation mechanisms in high-entropy alloys at 15 K, which began with dislocation slip, followed by stacking faults and twinning, before transitioning to inhomogeneous deformation by serrations. Quantitative analysis showed that the cooperation of these different deformation mechanisms led to extreme work hardening. The low stacking fault energy plus the stable face-centered cubic structure at ultralow temperatures, enabled by the high-entropy alloying, played a pivotal role bridging dislocation slip and serration.
Harjo, S.; Gong, W.; 川崎 卓郎; Naeem, M.*; He, H.*; Wang, X.-L.*
no journal, ,
5元系CrMnFeCoNi高エントロピー合金を77Kで引張変形させると強度増加のみでなく伸びが増加したことが発見されて以来、高エントロピー合金の低温変形挙動に関する研究が重要なトピックスの一つとなった。変形挙動を理解するためには、低温下での機械的特性試験を行うと同時に、内部組織変化も調べて機械的特性変化との関連性の理解が必要である。今までの内部組織観察は、変形試験の前・後において、もしくは、変形試験の途中に中断して、顕微鏡を用いて行われたことは多く、全体の機械的試験の範囲をカバーすることができなかったり、観察領域が狭く試験片全体を代表した情報が得られなかったりすることはしばしばある。J-PARCのTAKUMIは、15Kの温度領域下での変形試験が行える周辺環境装置を完備し、その場中性子回折実験を行うことで、低温下の機械的特性を得ながら回折測定で内部組織変化を同時に調べることができる。得られたCrMnFeCoNi、CrFeCoNi及びCrCoNiの高・中エントロピー合金の低温変形挙動について紹介・比較する。
高梨 弘毅
no journal, ,
High-entropy alloys (HEAs) have attracted considerable attention, however, most of studies have been conducted using bulk magnets, and the spin-dependent transport in ferromagnetic HEA thin films have not been well investigated. In this study, we focus on FeCoNiCuPd HEAs, which exhibit a Curie temperature higher than room temperature and contain a heavy element (Pd) with relatively large spin-orbit interaction. The thin-film samples with different composition ratios of Cu and Pd under the same amount of FeCoNi, Fe
NiCoCu
Pd
(0
X+Y40), were prepared on thermally oxidized Si substrates at an ambient temperature by an ultrahigh vacuum sputtering system. All the films exhibited ferromagnetic hysteresis curves with soft magnetic behavior at room temperature. The saturation magnetization increased linearly with the Pd concentration, which might be attributed mainly to the induced Pd moment. Anisotropic magnetoresistance effect (AMR) and anomalous Hall effect (AHE) were measured for Hall-bar devices fabricated by conventional photolithography and Ar milling process. The MR ratio and the anomalous Hall conductivity showed a smooth, simple increase with the Pd concentration, suggesting that the spin-orbit interaction of constituent elements plays a significant role on the AMR and the AHE in ferromagnetic HEAs.
