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Miyagawa, Akihisa*; Hayashi, Naoki*; Iwamoto, Hibiki*; Arai, Tsuyoshi*; Nagatomo, Shigenori*; Miyazaki, Yasunori; Hasegawa, Kenta; Sano, Yuichi; Nakatani, Kiyoharu*
Analytical Sciences, 40(2), p.347 - 352, 2024/02
Times Cited Count：1 Percentile：0.00(Chemistry, Analytical)The Eu(III) distribution mechanism in single extractant-impregnated polymer-layered silica particle in a complex solution containing multiple lanthanide ions was investigated using fluorescence microspectroscopy. The rate-determining step was the reaction of Eu(III) with the two extractant molecules. The obtained mechanism and rate constants agreed with those of the single-ion distribution system, in which Eu(III) was distributed to the particles in the Eu(III) solution.
Rossi, F.; Abbas, K.*; Koizumi, Mitsuo; Lee, H.-J.; Rodriguez, D.; Takahashi, Tone
Proceedings of INMM & ESARDA Joint Virtual Annual Meeting (Internet), 7 Pages, 2021/08
Zr and Mo in concrete rubbleDo, V. K.; Furuse, Takahiro; Murakami, Erina; Aita, Rena; Ota, Yuki; Sato, Soichi
Journal of Radioanalytical and Nuclear Chemistry, 327(1), p.543 - 553, 2021/01
Times Cited Count：6 Percentile：52.13(Chemistry, Analytical)A new HCl-free chromatographic separation procedure has been developed for sequential separation of Zr and Mo from concrete matrices. Accordingly, Zr and Mo could be sensitively and selectively measured by ICP-MS/MS using ammonia reaction gas. The recoveries of greater than 90% for Zr and Mo from concretes could be achieved. The measurement condition was optimized for complete suppression of interferences from Nb and peak tailing from abundant isotopes of Zr and Mo in concrete matrices. The removal of interferences was verified by measurement of radio-contamination-free concretes used as a sample matrix blank. Method detection limits of 1.7 mBq g
and 0.2 Bq g were achieved for Zr and Mo, respectively, in the concrete matrices. The interference removal factor for Nb (equivalent to the decontamination factor in radiochemical separation) was of the order of 10
, and the abundance sensitivity was of the order of 10
, indicating that the developed method is reliable for verifying the presence of ultralow concentrations of Zr and Mo. The present method is suitable for the rapid assessment of Zr and Mo for radioactivity inventory of concrete rubble.
Rossi, F.; Koizumi, Mitsuo; Lee, H.-J.; Rodriguez, D.; Takahashi, Tone; Abbas, K.*; Bogucarska, T.*; Crochemore, J.-M.*; Pedersen, B.*; Varasano, G.*
61st Annual Meeting of the Institute of Nuclear Materials Management (INMM 2020), Vol.2, p.907 - 911, 2021/00
Oba, Hironori; Saeki, Morihisa; Yokoyama, Atsushi
Proceedings of Plasma Science Symposium 2005/22nd Symposium on Plasma Processing (PSS-2005/SPP-22), p.331 - 332, 2005/01
A plasma produced by a XeCl laser ablation of boron compound was investigated using ion probes and a quadrupole mass spectrometer. Although the ablated neutral boron atoms had a natural abundance ratio, the isotope ratio of singly ionized boron atoms having a greatly different from the natural abundance ratio was observed. The observed isotope ratio of boron ions was different from the natural abundance.
Miyabe, Masabumi; Oda, Koichi*; Oba, Masaki; Kato, Masaaki; Wakaida, Ikuo; Watanabe, Kazuo
JAERI-Tech 2004-064, 33 Pages, 2004/10
JAERI-Tech-2004-064.pdf:1.89MB
In nuclear waste materials there are various radionuclides to which standard analytical techniques are difficult to be applied. We are developing an analytical technique where such nuclides are analyzed using multi-step resonance ionization mass spectrometry. In this study, we have developed an external cavity diode laser applicable to the analysis. The wavelength and output power dependence on injection current and temperature were investigated for various types of laser diodes. Based on the data, we have obtained a suitable condition to operate the ECDL in stable single-mode oscillation, so that a continuous scanning range of about 100 GHz was realized. Additionaly, to evaluate the bandwidth of the developed ECDL, we have performed Doppler-free spectroscopy. The reasonable agreement of the measured isotope shift and HFS splitting with the reported values demonstrated that the developed ECDL is applicable to a precise laser spectroscopy as well as a laser trace analysis.
/Si(001) system observed by SiO mass spectrometry and synchrotron radiation photoemission spectroscopyTeraoka, Yuden; Moritani, Kosuke; Yoshigoe, Akitaka
Applied Surface Science, 216(1-4), p.8 - 14, 2003/06
Times Cited Count：6 Percentile：34.98(Chemistry, Physical)The experiments concerning the oxidation of Si(001) were performed at the surface reaction analysis apparatus, installed at the beamline BL23SU in the SPring-8. The SiO desorb remarkably at surface temperature of 1000 K. The desorption yield increased with increasing the incident energy of O. On the other hand, the desorption yield increased with decreasing the incident energy in the temperature region lower than 1000 K. Oxygen uptake curves observed by O-1s photoemission measurements corresponded to the SiO desorption features. These facts reveal that the passive oxidation coexists with the SiO desorption in the temperature region from 900 K to 1000 K.
Okumura, Yoshikazu; Hanada, Masaya; Kojima, Hiroaki; ; Ohara, Hiroshi
JAERI-M 89-090, 14 Pages, 1989/07
no abstracts in English
R.Kirchner*; O.Klepper*; D.Schardt*;
Nuclear Instruments and Methods in Physics Research B, 26, p.235 - 239, 1987/00
Times Cited Count：20 Percentile：86.82(Instruments & Instrumentation)no abstracts in English
Zr and Mo based on solid phase extraction combined with ICP-MS/MS, 2; Spectral interference removal for measurement of Zr and Mo by ICP-MS/MSDo, V. K.; Furuse, Takahiro; Murakami, Erina; Aita, Rena; Ota, Yuki; Tomitsuka, Tomohiro; Sano, Yuichi; Akimoto, Yuji*; Endo, Tsubasa*; Katayama, Atsushi; et al.
no journal, ,
The paper presents removal of possible interferences including from an isobar (Nb) and tailings of adjacent peaks for the quantification of Zr and Mo using an ICP-MS/MS (Agilent 8900). By using ammonia gas (NH
) as a reaction gas, Zr and Mo can be separated from each other and from Nb owing to the different reactions of those elements with the reaction gas. Based on the characterization results, we propose a measurement scheme aiming at quantification of Zr and Mo in environmental samples collected at adjacent location of Fukushima Daiichi Nuclear Power Station.
Do, V. K.; Kitamura, Kiyoshi; Horita, Takuma; Furuse, Takahiro
no journal, ,
We report an application of automated devices for multi-step chemical separation for nickel and an idea of subsequent quantification for Ni-59 using ICP-QQQ-MS. Nickel is separated on our selected automated instruments applying a conventional separation scheme. The obtained chemical recovery for Ni standard carrier was 89.8% (relative standard deviation, RSD of 2.9%, n = 3), which is consistent with the manually obtained recovery of 87.0% (RSD = 2.2%, n = 3). The quantification of Ni-59 by ICP-QQQ-MS was examined. Accordingly, the intensity of 59Ni could be deduced from an intensity correction curve for natural isotopes of nickel. The proposed analytical method is more rapid and less laborious, being expected to reduce radiation exposure to workers.
