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Okane, Tetsuo; Fujimori, Shinichi; Mamiya, Kazutoshi; Okamoto, Jun; Muramatsu, Yasuji; Fujimori, Atsushi; Suzuki, Hiroyuki*; Matsumoto, Takehiko*; Furubayashi, Takao*; Isobe, Masaaki*; et al.
Journal of Magnetism and Magnetic Materials, 272-276(Suppl.), p.e297 - e298, 2004/05
Times Cited Count：5 Percentile：30.88(Materials Science, Multidisciplinary)The electronic structure of spinel-type chalcogenide CuIrS, which exhibits a metal-insulator transition (MIT) as a function of temperature, has been studied by photoemission spectroscopy (PES). Below the transition temperature 
, the valence-band PES spectra indicate a gap formation, while the overall valence-band structure is shifted to the higher binding-energy side. The line shape of the Ir 4
core-level PES spectra shows a dramatic change across , which may be associated with the variation of the Ir 5
electron states.
Kubozono, Yoshihiro*; Mimura, Kazue*; Takabayashi, Yasuhiro*; Maeda, Hironobu*; Kashino, Setsuo*; Emura, Shuichi*; Nishihata, Yasuo; Uruga, Tomoya*; Tanaka, Tsunehiro*; Takahashi, Masao*
Journal of Synchrotron Radiation, 6(Part3), p.564 - 566, 1999/05
The Rb K-edge XAFS spectra for the stable phase of RbC60 which is a quasi one-dimensional polymer were measured in the temperature range from 14.6 to 210 K in order to clarify the origin of the metal-insulator transition around 50 K. The distances and mean-square relative displacements between the Rb atom and the neighboring C atoms determined by XAFS exhibited no change around 50 K, implying that the metal-insulator transition originates from the SDW instablity.
