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Jing, Z.*; Yamaguchi, Toshio*; Machida, Shinichi*; Hattori, Takanori; Zhou, Y.*
Journal of Chemical Physics, 163(19), p.194505_1 - 194505_12, 2025/11
Times Cited Count：0 Percentile：0.00(Chemistry, Physical)Ion solvation in a range of gigapascal pressure is of great significance for high-pressure chemical synthesis and the circulation of matter within the Earth's interior. We perform neutron scattering (NS) experiments and molecular dynamics simulations of deuterated aqueous solutions of MCl (M = Li, Na, K, Rb, and Cs) at 0.1 MPa and 0.7 GPa/298 K. An empirical potential structure refinement method analyzes the NS data. Upon compression to 0.7 GPa, the outer-shell water molecules enter the nearest neighbor of ions, and the solvated ion clusters become denser. The hydration factor 
and static hydration number 
based on the orientation distribution of the water dipole in the first solvation shell, show that the compression weakens the hydration ability of the ions. Compression suppresses the diffusion of ions, particularly of the structure-breaking ions. The ionic diffusion coefficient 
residence time of water molecules 
and dynamic hydration number 
indicate that Rb
and Cs exhibit characteristics of structure-making ions under compression. The dynamic properties are more pressure-sensitive than the static structure.
Yasue, Ayumu*; Kawakami, Mayu*; Kobayashi, Kensuke*; Kim, J.*; Miyazu, Yuji*; Nishio, Yuhei*; Mukai, Tomohisa*; Morooka, Satoshi; Kanematsu, Manabu*
Quantum Beam Science (Internet), 7(2), p.15_1 - 15_14, 2023/05
Kohara, Shinji*; Suzuya, Kentaro; Takeuchi, Ken*; Loong, C.-K.*; Grimsditch, M.*; Weber, J. K. R.*; Tangeman, J. A.*; Key, T. S.*
Science, 303(5664), p.1649 - 1652, 2004/03
Times Cited Count：175 Percentile：96.17(Multidisciplinary Sciences)Inorganic glasses normally exhibit a network of interconncted covalent-bonded structural elements that has no long-range order. In silicate glasses the network formers are based on SiO
-tetrahedra interconnected via oxygen atoms at the corners. Conventional wisdom then implies that alkaline and alkaline-earth orthosilicate materials cannot be vitrified because they do not contain sufficient network forming SiO
to establish the needed interconnectivity. We have studied a bulk magnesium orthosilicate glass obtained by containerless melting-and-cooling. We find that the role of network former is largely taken on by corner- and edge-sharing of highly distorted ionic Mg-O species that adopt 4-, 5- and 6-coordination with oxygen. The results suggest that similar novel glassy phases may be found in the containerless environment of interstellar space.
Baba, Shinichi; Ishihara, Masahiro; Minakawa, Nobuaki; Suzuki, Junichi
Proceedings of International Conference on Advanced Technology in Experimental Mechanics 2003 (ATEM '03) (CD-ROM), 4 Pages, 2003/09
The aim of the present paper is to clarify the residual stress occuring in the c/c composite to improve the manufacturing process. The residual stress was measured by a neutron diffraction method using the RESA in the JRR-3M of JAERI in this study. As a results of the residual stress measurment, it was found that the residual stress of the ring type c/c composite is the comporessive stress, and the macroscopic residual strain/stress is absorbed mainly microstructural change such as pore shape change.
JAERI-M 85-112, 67 Pages, 1985/08
no abstracts in English
