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Journal Articles

Swelling of radiation-cured polymer precursor powder for silicon carbide by pyrolysis

Takeyama, Akinori; Idesaki, Akira; Sugimoto, Masaki; Yoshikawa, Masahito

Journal of Asian Ceramic Societies (Internet), 3(4), p.402 - 406, 2015/12

Journal Articles

Synthesis of a minute SiC product from polyvinylsilane with radiation curing, 2; Ceramization process of radiation cured polyvinylsilane

Idesaki, Akira; Sugimoto, Masaki; Yoshikawa, Masahito; Tanaka, Shigeru; Narisawa, Masaki*; Okamura, Kiyohito*; Ito, Masayoshi*

Journal of Materials Science, 42(1), p.130 - 135, 2007/01

 Times Cited Count:2 Percentile:10.8(Materials Science, Multidisciplinary)

We have synthesized minute SiC products from polyvinylsilane (PVS), which is a liquid organosilicon polymer, with radiation curing. Since there is a close relationship between the properties of obtained SiC products and pyrolysis condition, it is important to investigate the ceramization process of PVS in order to find out the optimum pyrolysis condition. In this paper, the ceramization process of the PVS cured by $$gamma$$-ray irradiation at room temperature was investigated by gas analysis, thermogravimetric analysis, density measurement, and so on. It was found that the ceramization of $$gamma$$-ray cured PVS starts above 500K, and that drastic organic-inorganic conversion occurs in the temperature range of 700-1100K. According to the results of the changes of mass and density, it was found that the volume shrinkage of PVS during the curing and pyrolysis processes is 80%. The SiC obtained by pyrolysis at 1573K showed the density of 2.50g/cm$$^{3}$$ and microvickers hardness of 31.6GPa.

Journal Articles

Synthesis of a minute SiC product from polyvinylsilane with radiation curing, 1; Radiation curing of polyvinylsilane

Idesaki, Akira; Sugimoto, Masaki; Tanaka, Shigeru; Narisawa, Masaki*; Okamura, Kiyohito*; Ito, Masayoshi*

Journal of Materials Science, 39(18), p.5689 - 5694, 2004/09

 Times Cited Count:6 Percentile:29.02(Materials Science, Multidisciplinary)

Irradiation effect of $$gamma$$-ray on polyvinylsilane (PVS), which is a liquid organosilicon polymer, was investigated and the optimum curing condition to synthesize a minute SiC product with radiation curing was discussed. Room temperature and liquid nitrogen temperature (77K) were examined as the irradiation temperature. In both cases, the cured PVS maintaining its formed shape could be obtained by $$gamma$$-ray irradiation under vacuum, and the cured PVS in solid state at room temperature was obtained by irradiation with dose of above 3-4MGy. It was found that the efficiency of crosslinking in case of the irradiation at room temperature is higher than that in case of irradiation at 77K. The PVS injected into a mold was irradiated by $$gamma$$-ray with dose of 3.6MGy at room temperature under vacuum, and pyrolyzed at 1273 K in Ar gas atmosphere. As a result, minute SiC products which had similar shapes to the mold and the sizes of 30-60$$mu$$m were obtained.

Journal Articles

Development of SiC/SiC composite from precursor polymer by radiation application

Sugimoto, Masaki; Morita, Yosuke; Tanaka, Shigeru; Seguchi, Tadao; Ito, Masayoshi*; Okamura, Kiyohito*

IAEA-SM-365/7, p.35 - 40, 2003/09

no abstracts in English

Journal Articles

Minute SiC products synthesized from polyvinylsilane with radiation curing

Idesaki, Akira; Sugimoto, Masaki; Tanaka, Shigeru; Narisawa, Masaki*; Okamura, Kiyohito*; Ito, Masayoshi*

International Symposium in Honor of Professor K. Okamura: Collected Abstracts, 3 Pages, 2003/04

Minute SiC products were synthesized from polyvinylsilane (PVS), which is a liquid organosilicon polymer, with radiation curing. The PVS was injected into molds whose patterns were square and circle with 50$$mu$$m in side or diameter, and 10$$mu$$m in depth. The molds containing the PVS were irradiated by $$gamma$$-ray with dose of 3.6MGy at room temperature in vacuum, and heat-treated at 1273K in Ar gas atmosphere. The obtained SiC products had shapes similar to those of the molds, and the sizes of the products were about 30$$mu$$m in side or diameter.

Journal Articles

Radiation curing of polyvinylsilane as a precursor for SiC-based material

Idesaki, Akira; Sugimoto, Masaki; Tanaka, Shigeru; Narisawa, Masaki*; Okamura, Kiyohito*; Ito, Masayoshi*

Key Engineering Materials, 247, p.129 - 132, 2003/00

Polyvinylsilane (PVS), a liquid organosilicon polymer at room temperature, is expected to be used as a precursor for SiC product with minute and complex shape. In the synthesis of the SiC product, it is necessary to cure the polymer in order to retain the shape during the pyrolysis. We have used a radiation for curing of the PVS. However, there is a problem that the PVS foams during electron beam irradiation at room temperature. In this report, the curing of PVS by $$gamma$$-ray irradiation was examined, and effect of irradiation temperature was studied in order to find out conditions that prevent the foaming of PVS. It was found that the PVS is cured without foaming by the $$gamma$$-ray irradiation in both cases of the irradiation temperature at liquid nitrogen temperature (77K) and at room temperature. From the results of measurement of gel fraction and TGA, it was found that the PVS is cured more efficiently by the irradiation at room temperature than at 77K.

Journal Articles

Development of silicon carbide micro-tube from precursor polymer by radiation oxidation

Sugimoto, Masaki; Idesaki, Akira; Tanaka, Shigeru; Okamura, Kiyohito*

Key Engineering Materials, 247, p.133 - 136, 2003/00

no abstracts in English

Journal Articles

Fine silicon carbide fiber synthesized from a silicon-based polymer blend using radiation curing

Idesaki, Akira; Sugimoto, Masaki; Tanaka, Shigeru; Morita, Yosuke; Narisawa, Masaki*; Okamura, Kiyohito*; Ito, Masayoshi*

High Temperature Ceramic Matrix Composites, p.35 - 40, 2001/00

Silicon carbide (SiC) fiber, which is one of the likeliest candidates as a reinforcement fiber of ceramic matrix composites (CMCs), is synthesized from polycarbosilane (PCS). The diameter of thus SiC fibers is 10-15 $$mu$$m. In order to fabricate CMCs with 3-dimensional complex shapes, it is important to develop a SiC fiber with diameter of less than 10 $$mu$$m, flexibility, and high strength. In order to improve the spinnability of precursor polymer, we have blended polyvinylsilane (PVS), which is a liquid polymer at room temperature, to PCS as a spinning additive. According to relationship between temperature and melt viscosity of the polymer blend, it was found that the polymer can be melt-spun at about 490K, 110K lower than PCS (about 600K), and that the spinnability of the polymer is improved by blending PVS. Fine polymer fiber was obtained from the polymer blend, and finally, very fine SiC fiber with the average diameter of 6 $$mu$$m was synthesized from the PCS-PVS polymer blend.

Journal Articles

Ceramic fibers from polymer precursors

*; *; Okamura, Kiyohito*; Sugimoto, Masaki; Seguchi, Tadao

Fine Ceramic Fibers, p.207 - 229, 1999/00

no abstracts in English

Journal Articles

Use of blended precursors of poly(vinylsilane) in polycarbosilane for silicon carbide fiber synthesis with radiation curing

Narisawa, Masaki*; Idesaki, Akira*; *; *; Sugimoto, Masaki; Seguchi, Tadao; Ito, Masayoshi*

Journal of the American Ceramic Society, 82(4), p.1045 - 1051, 1999/00

 Times Cited Count:21 Percentile:76.84(Materials Science, Ceramics)

no abstracts in English

Journal Articles

Development of SiC fiber-reinforced SiC composites by radiation-cured preceramic polymer

Sugimoto, Masaki; Morita, Yosuke; Seguchi, Tadao; *

Key Engineering Materials, 164-165, p.11 - 14, 1999/00

no abstracts in English

Journal Articles

SiC-based fibers synthesized from hybrid polymer of polycarbosilane and polyvinylsilane

Idesaki, Akira*; Narisawa, Masaki*; *; Sugimoto, Masaki; Morita, Yosuke; Seguchi, Tadao; Ito, Masayoshi*

Key Engineering Materials, 164-165, p.39 - 42, 1999/00

no abstracts in English

Journal Articles

Development of super heat resistant ceramic fiber

Seguchi, Tadao

Interijento Zairyo, 5(3), p.45 - 52, 1995/00

no abstracts in English

Journal Articles

Reaction mechanisms of silicon carbide fiber synthesis by heat treatment of polycarbosilane fibers cured by radiation, II; Free radical reaction

Sugimoto, Masaki; *; *; Seguchi, Tadao

Journal of the American Ceramic Society, 78(7), p.1849 - 1852, 1995/00

 Times Cited Count:36 Percentile:84.65(Materials Science, Ceramics)

no abstracts in English

Journal Articles

Reaction mechanisms of silicon carbide fiber synthesis by heat treatment of polycarbosilane fibers cured by radiation, I; Evolved gas analysis

Sugimoto, Masaki; *; *; Seguchi, Tadao

Journal of the American Ceramic Society, 78(4), p.1013 - 1017, 1995/00

 Times Cited Count:69 Percentile:93.88(Materials Science, Ceramics)

no abstracts in English

Journal Articles

Synthesis of heat-resistant SiC fiber by radiation processing

Seguchi, Tadao; Kasai, Noboru; *

Proc. of the 4th Int. Symp. on Advanced Nuclear Energy Research (JAERI-CONF 1/JAERI-M 92-207), p.62 - 65, 1992/12

no abstracts in English

Journal Articles

Properties of the low oxygen content SiC fiber on high temperature heat treatment

*; *; *; *; Seguchi, Tadao; *

Ceram. Eng. Sci. Proc., 12(7-8), p.1007 - 1018, 1991/00

no abstracts in English

Journal Articles

Industrial application of radiation processing in Japan

Machi, Sueo

Radiation Physics and Chemistry, 14(1-2), p.155 - 170, 1979/00

no abstracts in English

Journal Articles

Fixation of photoelastic fringe patterns by gamma-rays; Effects of curing reagent and radiation dose on optical and mechanical properties of epoxy resin

Journal of Nuclear Science and Technology, 5(11), p.579 - 589, 1968/00

 Times Cited Count:0

no abstracts in English

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