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Journal Articles

Desulfurization reaction of high sulfur content flue gas treated by electron beam

Hirosawa, Shojiro*; Kojima, Takuji; Hashimoto, Shoji; Suzuki, Ryoji*; Aoki, Shinji*

Radioisotopes, 51(8), p.285 - 295, 2002/08

Experiments of flue gas treatment by electron beam were carried out, using simulated lignite-burning flue gas containing SO$$_{2}$$(5500ppm), NO(390ppm) and H$$_{2}$$O(22%). Removal efficiency of SO$$_{2}$$ was more than 90% at a dose of 1-2kGy. It shows applicability of electron beam for treatment of lignite-burning flue gas. Another removal reaction besides the radiation-induced radical reaction and the thermal reaction occurring without irradiation was suggested by the facts that removal of SO$$_{2}$$ by the radical reaction is only a few hundreds of ppm and the removal amounts by thermal reaction under irradiation is lower than a half of total desulfurization. The mechanism similar to thermal reaction was proposed, assuming simultaneous uptake reaction of SO$$_{2}$$ and NH$$_{3}$$ on the surface of liquid aerosol. It was suggested that ammonium nitrate having deliquescence relative humidity(DRH) of 60% at 25$$^{circ}C$$ plays an important role in producing liquid aerosols. Decrease of DRH of ammonium nitrate with increasing temperature and with formation of double salt of ammonium sulfate results in enhancement of formation of liquid aerosols.

Journal Articles

Real-time simulation and analysis on long-range atmospheric dispersions of volcanic gases discharged from the Miyake Island

Furuno, Akiko; Nagai, Haruyasu; Umeyama, Nobuaki; Chino, Masamichi

Taiki Kankyo Gakkai-Shi, 37(1), p.23 - 34, 2002/01

The active volcano Oyama in the Miyake Island has been emitting a huge amount of volcanic gases since the first eruption in July 2000. High concentrations of SO2 gas originated in Oyama frequently appear in the wide area from the northeast to the west part of Honshu, Japan. This paper describes real-time prediction of SO2 dispersion covering the Tokai and Kanto District and its verification by comparing with SO2 observation data from October to November 2000. Atmospheric dispersions of SO2 are calculated by using our software system that combines a regional atmospheric dynamic model and a particle random walk model. It was proved that the real-time prediction of our system has adequate precision. The importance of including the effect of wet deposition was also shown. The release amounts estimated from the comparison between the calculation result and the monitoring data are 20,000 - 50,000 ton/day, which is consistent to measured ones at the Miyake Island.

Journal Articles

Relation between nasty smell at Kanto area on 28 August 2000 and eruption at Miyake Island; Examination by numerical simulation

Nagai, Haruyasu; Terada, Hiroaki; Chino, Masamichi

Tenki, 48(4), p.11 - 14, 2001/04

no abstracts in English

JAEA Reports

Atmospheric dispersion simulations of volcanic gas from Miyake Island by SPEEDI

Nagai, Haruyasu; Furuno, Akiko; Terada, Hiroaki; Umeyama, Nobuaki; Yamazawa, Hiromi; Chino, Masamichi

JAERI-Research 2001-012, 28 Pages, 2001/03

JAERI-Research-2001-012.pdf:1.77MB

Japan Atomic Energy Research Institute is advancing the study for prediction of material circulation in the environment to cope with environmental pollution, based on SPEEDI (System for Prediction of Environmental Emergency Dose Information) and WSPEEDI (Worldwide version of SPEEDI), which are originally developed aiming at real-time prediction of atmospheric dispersion of radioactive substances accidentally released from nuclear facility. As a part of this study, dispersion simulation of volcanic gas erupted from Miyake Island is put into practice. After the stench incident at the west Kanto District on 28 August 2000 caused by volcanic gas from Miyake Island, simulations dealing with atmospheric dispersion of volcanic gas from Miyake Island have been carried out. This report describes the details of these studies.

JAEA Reports

Physico-chemical studies on the disposal of miscellaneous radioactive waste through A single-step process (III)

Iwase, Masanori*

JNC TJ8400 2000-063, 78 Pages, 2000/03

JNC-TJ8400-2000-063.pdf:1.93MB

This study is aimed at controlling oxidation reaction of molten metal by ash in incineration systems, and at positively utilizing the oxidation reaction for decontamination of slag. In this year, in order to investigate physico-chemical properties of mixed fused salt containing alkali sulfates, with special focus on the behaviour of oxygen anion in the melts, Cu$$^{2+}$$ / Cu$$^{+}$$ redox equilibrium experiments were carried out. Among the effect of various parameters on Cu$$^{2+}$$ / Cu$$^{+}$$ ratio in binary and ternary alkali sulfate melts, the effect of partial pressures of oxygen and SO$$_{2}$$ was mainly investigated in the study. Variation in Cu$$^{2+}$$ / Cu$$^{+}$$ ratio were presented as the function of partial pressures of oxygen and SO$$_{2}$$, respectively. Possible thermodynamic interpretation were made on the experimental results. In addition, the dissolution of Cr$$_{2}$$O$$_{3}$$ in mixed alkali sulfates were also investigated as a first step to elucidate the mechanism of hot corrosion. With this investigation, an important finding was obtained that the solubility of Cr$$_{2}$$O$$_{3}$$ for melts with same average ionic radius, in other words, oxygen ion activity, were essentially identical under constant temperature and atmosphere.

JAEA Reports

Journal Articles

Reactions of sulfur dioxide with ammonia; Dependence on oxygen and nitric oxide

Hirota, Koichi; J.Maekelae*; Tokunaga, Okihiro

Industrial & Engineering Chemistry Research, 35(10), p.3362 - 3368, 1996/00

 Times Cited Count:19 Percentile:73.69(Engineering, Chemical)

no abstracts in English

Journal Articles

Technology for electron beam treatment of coal fired flue gas

Hashimoto, Shoji; Tokunaga, Okihiro

OHM (Sougou Denki Zasshi), 82(9), p.55 - 59, 1995/09

no abstracts in English

JAEA Reports

Pilot-scale test for electron beam flue gas treatment of coal-fired boiler

Namba, Hideki; Tokunaga, Okihiro; Hashimoto, Shoji; ; ; ; ;

JAERI-Tech 95-013, 6 Pages, 1995/03

JAERI-Tech-95-013.pdf:0.57MB

no abstracts in English

Journal Articles

Pilot-scale test for electron beam purification of flue gas from coal-combustion boiler

Hashimoto, Shoji; Namba, Hideki; Tokunaga, Okihiro; ; ; ; ;

1995 SO$$_{2}$$ Control Symp., Book 3, 0, 10 Pages, 1995/03

no abstracts in English

Journal Articles

Demonstration test of electron beam flue gas treatment pilot plant of a coal fired thermal power station

; ; ; ; Namba, Hideki; Tokunaga, Okihiro; Hashimoto, Shoji; ;

Ebara Jiho, (166), p.56 - 64, 1995/00

no abstracts in English

Journal Articles

Basic research for electron beam flue gas treatment

Namba, Hideki

Genshiryoku Kogyo, 41(7), p.20 - 23, 1995/00

no abstracts in English

Journal Articles

Development of electron beam flue gas treatment technology

; ; ; ; ; Tokunaga, Okihiro; Namba, Hideki

Proc. of Power-Gen Asia 94,Conf. Papers, 1, p.457 - 465, 1995/00

no abstracts in English

Journal Articles

Pilot-scale test for electron beam purification of flue gas from a municipal waste incinerator with slaked-lime

Hirota, Koichi; Tokunaga, Okihiro; Miyata, Teijiro; Sato, Shoichi; ; ; ; ; ; ; et al.

Radiation Physics and Chemistry, 46(4-6), p.1089 - 1092, 1995/00

 Times Cited Count:10 Percentile:68.27(Chemistry, Physical)

no abstracts in English

Journal Articles

Pilot-scale test for electron beam purification of flue gas from coal-combustion boiler

Namba, Hideki; Tokunaga, Okihiro; Hashimoto, Shoji; ; ; ; ;

Radiation Physics and Chemistry, 46(4-6), p.1103 - 1106, 1995/00

 Times Cited Count:38 Percentile:94.17(Chemistry, Physical)

no abstracts in English

Journal Articles

Kinetics of SO$$_{2}$$ removal from flue gas by electron beam technique

H.Maetzing*; Namba, Hideki; Tokunaga, Okihiro

Radiation Physics and Chemistry, 42(4-6), p.673 - 677, 1993/00

 Times Cited Count:18 Percentile:82.49(Chemistry, Physical)

no abstracts in English

Journal Articles

Phase relation and thermodynamic properties of cubic fluorite-type solid solution, Ba$$_{y/2}$$Y$$_{y/2}$$U$$_{1-y}$$O$$_{2+x}$$(x$$>$$0,x=0,x$$<$$0)

Fujino, Takeo*; Yamashita, Toshiyuki; Ouchi, Kinji

Journal of Nuclear Materials, 183, p.46 - 56, 1991/00

 Times Cited Count:9 Percentile:68.62(Materials Science, Multidisciplinary)

no abstracts in English

JAEA Reports

Radiation chemical studies on the electron-beam treatment of exhaust gases

; ; ;

JAERI 1265, 17 Pages, 1980/03

JAERI-1265.pdf:0.84MB

no abstracts in English

Journal Articles

Radiation treatment of exhaust gases, XII; NO removal in moist NO-SO$$_{2}$$-O$$_{2}$$-N$$_{2}$$ mixtures containing NH$$_{3}$$

; ;

Journal of Nuclear Science and Technology, 17(11), p.822 - 830, 1980/00

 Times Cited Count:11 Percentile:73.10(Nuclear Science & Technology)

no abstracts in English

22 (Records 1-20 displayed on this page)