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Onutai, S.; Sato, Junya; Osugi, Takeshi
Journal of Solid State Chemistry, 319, p.123808_1 - 123808_10, 2023/03
Times Cited Count：15 Percentile：97.26(Chemistry, Inorganic & Nuclear)Collaborative Laboratories for Advanced Decommissioning Science; Shibaura Institute of Technology*
JAEA-Review 2022-008, 116 Pages, 2022/06
JAEA-Review-2022-008.pdf:5.36MB
The Collaborative Laboratories for Advanced Decommissioning Science (CLADS), Japan Atomic Energy Agency (JAEA), had been conducting the Nuclear Energy Science & Technology and Human Resource Development Project (hereafter referred to "the Project") in FY2020. The Project aims to contribute to solving problems in the nuclear energy field represented by the decommissioning of the Fukushima Daiichi Nuclear Power Station, Tokyo Electric Power Company Holdings, Inc. (TEPCO). For this purpose, intelligence was collected from all over the world, and basic research and human resource development were promoted by closely integrating/collaborating knowledge and experiences in various fields beyond the barrier of conventional organizations and research fields. The sponsor of the Project was moved from the Ministry of Education, Culture, Sports, Science and Technology to JAEA since the newly adopted proposals in FY2018. On this occasion, JAEA constructed a new research system where JAEA-academia collaboration is reinforced and medium-to-long term research/development and human resource development contributing to the decommissioning are stably and consecutively implemented. Among the adopted proposals in FY2018, this report summarizes the research results of the "Development of the sintering solidification method for spent zeolite to long-term stabilization" conducted from FY2018 to FY2021 (this contract was extended to FY2021). Since the final year of this proposal was FY2021, the results for four fiscal years were summarized. The present study aims to develop a new sintering solidification method in which glass is added as a binder to spent zeolite which is adsorbed radionuclides such as Cs and the nuclides are immobilized by sintering them. In this project, the optimum conditions for sintering solidification and the basic performance of the sintered solidified body will be evaluated by cold tests, and they will be demonstrated by hot tests.
Kato, Chiaki; Yamagishi, Isao; Sato, Tomonori; Yamamoto, Masahiro*
Zairyo To Kankyo, 70(12), p.441 - 447, 2021/12
Zeolite particles have been used in a Cs adsorption vessel for purification of contaminated water in Fukushima Dai-ichi Nuclear Power Station (1F). The used Cs adsorption vessels were kept in storage space on 1F site. The risk of localized corrosion of stainless steel used in the vessel was worried. To evaluate the risk of localized corrosion, using specially designed electrochemical testing apparatus was used under gamma-ray irradiation test. And, real size mock-up test conducted. The results showed the potential change caused by creation of H
O by water radiolysis decreased by zeolite particles and the enrichment of chloride ion concentration in the vessel do not propagate during dry up procedure of Cs adsorption vessel. These data indicate the risk of localized corrosion of Cs adsorption vessel may stay at considerably low level.
Collaborative Laboratories for Advanced Decommissioning Science; Shibaura Institute of Technology*
JAEA-Review 2020-049, 78 Pages, 2021/01
JAEA-Review-2020-049.pdf:5.85MB
JAEA/CLADS had been conducting the Nuclear Energy Science & Technology and Human Resource Development Project. Among the adopted proposals in FY2018, this report summarizes the research results of the "Development of the Sintering Solidification Method for Spent Zeolite to Long-term Stabilization" conducted in FY2019.
Collaborative Laboratories for Advanced Decommissioning Science; Shibaura Institute of Technology*
JAEA-Review 2019-028, 71 Pages, 2020/03
JAEA-Review-2019-028.pdf:6.46MB
JAEA/CLADS, had been conducting the Center of World Intelligence Project for Nuclear Science/Technology and Human Resource Development (hereafter referred to "the Project") in FY2018. Among the adopted proposals in FY2018, this report summarizes the research results of the "Development of the Sintering Solidification Method for Spent Zeolite to Long-term Stabilization". The present study aims to develop the sintering solidification method for zeolites (spent zeolites) that adsorbs continuously generated radionuclides such as cesium. The sintering solidification method is able to stabilize adsorbed radionuclides such as cesium in zeolites by adding a glass as a binder to spent zeolite and sintered it. It is expected that the sintering solidification method is significantly reduce the volume of the solidified body compare with the glass solidification method and to form a stable solidified body equivalent to the calcination solidification method. In this project, we planned to select a glass suitable for the sintering solidification method and optimize the sintering temperature, etc. using non-radioactive nuclides (cold tests), and verify it by using radioactive nuclides (hot tests). In FY2018, we investigated the thermal properties of candidate glasses for binder and the effect of heating atmosphere on the sintering solidification method. Irradiated fuel for preparing simulated contaminated water containing radionuclides was selected and the condition of it was observed. In addition, we surveyed existing research results and latest research trends about solidification of zeolite, calcination solidification and so on.
Cantarel, V.; Arisaka, Makoto; Yamagishi, Isao
Journal of the American Ceramic Society, 102(12), p.7553 - 7563, 2019/12
Times Cited Count：12 Percentile：45.78(Materials Science, Ceramics)The hydrogen gas (H) production of wasteforms is a major safety concern for encapsulating nuclear wastes. For geopolymers, the H produced by radiolytic processes is a key factor because of the large amount of water present in their porous structure. Herein, the hydrogen production was measured under 
Co gamma irradiation. The effect of water saturation and sample size were studied for pure geopolymers, or using zeolites as an example waste. When geopolymer monolithic samples were large and saturated by water, the hydrogen released was measured up to two orders of magnitude lower with a 40 cm long cylinder samples (1.9
10
mol/J) than a sample in powder form (2.210
mol/J). To interpret results, a simple model was used, considering only hydrogen production, a potential recombination and its diffusion in the geopolymer matrix. Knowing the diffusion constant of the matrix, the model was able to reproduce the evolution of the hydrogen release as a function of the water saturation level and predict the evolution when sample size is increased up to 40 cm.
Kumagai, Yuta; Kimura, Atsushi*; Taguchi, Mitsumasa*; Watanabe, Masayuki
Journal of Radioanalytical and Nuclear Chemistry, 316(1), p.341 - 348, 2018/04
Times Cited Count：2 Percentile：19.49(Chemistry, Analytical)We studied effect of adsorption and condensation by zeolites on radiation-induced degradation of aqueous 2-chlorophenol (2-ClPh). This study aims to demonstrate that the solid-phase extraction using zeolites has potential advantage in treatments of aqueous organic pollutants. Among three zeolites examined in this study, a mordenite type zeolite (HMOR) that has a high Si to Al ratio (127 
3) exhibited preferable performance as the matrix for the 2-ClPh degradation. HMOR adsorbed far more 2-ClPh than the other zeolites, which have lower Si/Al ratios. The irradiation of HMOR induced degradation of adsorbed 2-ClPh into Cl
and organic by-products. We found a significant increase in Cl production by HMOR. The yield of Cl production in the presence of HMOR was as high as the yield in aqueous solution of 2-ClPh at a concentration 10 times higher. The increased Cl production indicates that the high concentration of adsorbed 2-ClPh led to effective use of the adsorbed energy of HMOR.
Kato, Chiaki; Sato, Tomonori; Ueno, Fumiyoshi; Yamagishi, Isao
Proceedings of 17th International Conference on Environmental Degradation of Materials in Nuclear Power Systems - Water Reactors, Vol.2, p.1357 - 1374, 2016/05
With respect to the long-term storage of the zeolite-containing spent Cs adsorption vessels used at the Fukushima Daiichi Nuclear Power Station, the corrosion of the vessel material is one of the most important issues. In this study, we performed electrochemical tests on stainless steel specimens in zeolite-containing artificial seawater under gamma-ray irradiation. The spontaneous potential ESP and critical pitting potential VC of the type 316L steel in systems in contact with various zeolites were measured in order to evaluate the corrosion resistance of the steel. In addition, the water sample was analyzed after being irradiated, in order to determine the concentrations of various dissolved oxidants such as oxygen and hydrogen peroxide, which can accelerate the corrosion process. The steady-state rest potential increased with an increase in the dose rate; however, the increase was suppressed in contact with the zeolites. The VC value of the steel when in contact with the zeolites was slightly smaller than the VC value in bulk water; however, the choice of the zeolite used as herschelite, IE96 and IE911 hardly affect the VC value. The concentration of HO in the bulk water under irradiation also increased with the increase in the dose rate. This increase was suppressed in the systems in contact with the zeolites, owing to the decomposition of the HO by the zeolites. A clear relationship was observed between ESP and the HO concentration. As contact with the zeolites caused the increase in ESP under irradiation to be suppressed, it can be concluded that the presence of zeolites in the spent Cs adsorption vessels can reduce the probability of the localized corrosion of the stainless steel in the vessels.
-ray irradiation in zeolite/water mixturesKumagai, Yuta
Hoshasen Kagaku (Internet), (99), p.53 - 56, 2015/04
Radiation-induced degradation of 2-chlorophenol (2-ClPh) in zeolite/water mixtures was studied in order to consider a possibility of adsorption on zeolites to improve efficiencies of irradiation treatments of water contaminated by organic compounds. The degradation of 2-ClPh by -ray irradiation was investigated as a model compound. The degradation was evaluated by chloride ion (Cl) production. A high concentration of Cl was observed after the irradiation of a mixture with a mordenite-type zeolite (NaMOR), whereas A-type and X-type zeolites showed no significant effect. Therefore, for the mixture with NaMOR, effects of pH of the solution and of the 2-ClPh concentration were examined. At pH 5.7, the excess production of Cl was induced by the addition of NaMOR. Concurrently, adsorption of 2-ClPh on NaMOR was observed. When the mixture contained a higher concentration of 2-ClPh at pH 5.7, the Cl production increased. The adsorption of 2-ClPh also increased with increasing concentration. The results suggest that organics adsorbed on zeolites are decomposed by irradiation effectively at high adsorption concentrations.
Tsuji, Takuya; Matsumura, Daiju; Kobayashi, Toru; Suzuki, Shinichi; Yoshii, Kenji; Nishihata, Yasuo; Yaita, Tsuyoshi
Clay Science, 18(4), p.93 - 97, 2014/12
-ray irradiationKato, Chiaki; Sato, Tomonori; Nakano, Junichi; Ueno, Fumiyoshi; Yamagishi, Isao
Proceedings of 2014 Nuclear Plant Chemistry Conference (NPC 2014) (USB Flash Drive), 9 Pages, 2014/10
As a part of consideration for long-term storage of spent zeolite adsorption vessels in the Fukushima Daiichi Nuclear Power Station, corrosion of vessel material in the spent zeolite adsorption vessel is one of important issue. We performed electrochemical tests of stainless steel (type 316L) in the zeolite containing artificial seawater under -ray irradiation. Steady spontaneous potential (Esp) and pitting potential (VC), of type 316L was measurement. Co -rays source was used under irradiation. Dose rate of -ray irradiation was controlled for 5 kGy/h and 400 Gy/h. In anode polarization curves, there was no clear difference under irradiation and non-irradiation. The corrosion potential of type 316L increased with increasing time after -ray irradiation. The Esp was shifted to nobler by -rays irradiation, while increasing Esp was suppressed by contacted with zeolite.
Inagaki, Yaohiro*; Idemitsu, Kazuya*; Arima, Tatsumi*; Maeda, Toshikatsu; Ogawa, Hiromichi; Itonaga, Fumio
Materials Research Society Symposium Proceedings, Vol.713, p.589 - 596, 2002/00
A large number of studies on HLW glass corrosion have shown that the glass reacts with water to form more stable mineral phases (alteration phases) during the long-term geological disposal. The phase formation is essential to evaluate the radionuclide release from the glass during the long-term disposal. The purpose of this study is to evaluate, experimentally, the mineral phase formation from HLW glass and the associated cesium release. Static corrosion tests were performed on powdered R7T7 glass in alkalline solutions at elevated temperatures to accelerate the reaction, and mineral phases formed were analyzed by XRD. The results showed that analcime (zeolite) is formed as the dominant phase coexisting with SiO(am), and beidellite(smectite) or gibbsite coexists dependiting on the conditions. The solution analysis indicated that most of the cesium is retained in the phases of beidellite and analcime by sorption.
Nakashima, Mikio;
Radiation Physics and Chemistry, 47(2), p.241 - 245, 1996/00
no abstracts in English
Nakashima, Mikio; Aratono, Yasuyuki
Radiation Physics and Chemistry, 41(3), p.461 - 465, 1993/00
Times Cited Count：20 Percentile：84.86(Chemistry, Physical)no abstracts in English
; ; ; ; ;
Hoken Butsuri, 17, p.427 - 436, 1982/00
no abstracts in English
Cs pollucite -ray source; ;
Int.J.Appl.Radiat.Isot., 32, p.595 - 599, 1981/00
Times Cited Count：3 Percentile：55.16(Nuclear Science & Technology)no abstracts in English
; ; ;
Journal of Nuclear Science and Technology, 17(1), p.83 - 85, 1980/00
Times Cited Count：0 Percentile：0.00(Nuclear Science & Technology)no abstracts in English
-ray-induced postpolymerization of vinyl monomers adsorbed on zeoliteJ.P.Quaegebeur*; Seguchi, Tadao; H.Lebail*; C.Chachaty*
Journal of Polymer Science; Polymer Chemistry Edition, 14(11), p.2703 - 2724, 1976/11
no abstracts in English
-ray irradiationMotooka, Takafumi; Yamagishi, Isao
no journal, ,
Mixtures of zeolite IE96 and artificial seawater (ASW) were poured in cylindrical tubes, and irradiated by Co-60 -rays. In the case of a zeolite bed which was fully immersed in ASW, the zeolite bed level increased slightly (1.8%) and an ASW phase formed onto the bed. The ASW level increased with the irradiation dose. In the case of a partial immersion, which simulates a drained zeolite vessel, the zeolite bed level was un-changed (0.0%).
-irradiation of A-, X-, Y- and mordenite type zeolites in aqueous solutionKumagai, Yuta; Kimura, Atsushi; Taguchi, Mitsumasa
no journal, ,
Zeolite minerals are suitable adsorbents for removal of radioactive cesium in water, because of their high radiation resistances. However, irradiation of zeolites results in decomposition of water adsorbed on the zeolites. Water decomposition produces hydrogen (H) and hydrogen peroxide (HO). H production has a risk of making an explosive gas mixture. HO causes corrosion of metals and alloys. Therefore, the radiation effects are required to be assessed and controlled. In this study, H and HO production by irradiation of zeolites in aqueous solution are comparatively studied among different types of zeolites, A-, X-, Y- and mordenite-types. The mixtures of the zeolites and aqueous solution were irradiated by Co -rays. The A-type and the X-type zeolites produced more H than the Y-type and the mordenite-type. In contrast, the HO production was inhibited by the addition of zeolites. The A-type and the X-type zeolites showed remarkable inhibition. The A-type and the X-type contains more aluminum in their frameworks than the others do. Therefore, the results suggest that aluminum sites have an important role in the reactions induced by irradiation.
