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Zhang, Z.*; Hattori, Takanori; Song, R.*; Yu, D.*; Mole, R.*; Chen, J.*; He, L.*; Zhang, Z.*; Li, B.*
Journal of Applied Physics, 136(3), p.035105_1 - 035105_8, 2024/07
Times Cited Count：2 Percentile：35.22(Physics, Applied)Solid-state refrigeration using barocaloric materials is environmentally friendly and highly efficient, making it a subject of global interest over the past decade. Here, we report giant barocaloric effects in sodium hexafluorophosphate (NaPF
) and sodium hexafluoroarsenate (NaAsF) that both undergo a cubic-to-rhombohedral phase transition near room temperature. We have determined that the low-temperature phase structure of NaPF is a rhombohedral structure with space group R
and NaAsF, i.e., F
, E
, and A
. The phase transition temperature varies with pressure at a rate of dT
/dP = 250 and 310 K/GPa for NaPF and NaAsF. The pressure-induced entropy changes of NaPF and NaAsF are determined to be around 45.2 and 35.6J kg
K, respectively. The saturation driving pressure is about 40 MPa. The pressure-dependent neutron powder diffraction suggests that the barocaloric effects are related to the pressure-induced cubic-to-rhombohedral phase transitions.
Jiang, X.*; Hattori, Takanori; Xu, X.*; Li, M.*; Yu, C.*; Yu, D.*; Mole, R.*; Yano, Shinichiro*; Chen, J.*; He, L.*; et al.
Materials Horizons, 10(3), p.977 - 982, 2023/03
Times Cited Count：26 Percentile：93.14(Chemistry, Multidisciplinary)As a promising environment-friendly alternative to current vapor-compression refrigeration, solid-state refrigeration based on the barocaloric effect has been attracting world wide attention. Generally, both phases in which a barocaloric effect occurs are present at ambient pressure. Here, instead, we demonstrate that KPF
exhibits a colossal barocaloric effect due to the creation of a high-pressure rhombohedral phase. The phase diagram is constructed based on pressure-dependent calorimetric, Raman scattering, and neutron diffraction measurements. The present study is expected to provide an alternative routine to colossal barocaloric effects through the creation of a high-pressure phase.
