Oxidation behavior of high-burnup advanced fuel cladding tubes in high-temperature steam

成川 隆文; 天谷 政樹

Journal of Nuclear Science and Technology, 56(7), p.650 - 660, 2019/07

https://doi.org/10.1080/00223131.2019.1613268

To evaluate the oxidation behavior of high-burnup advanced fuel cladding tubes in high-temperature steam, laboratory-scale isothermal oxidation tests were conducted using the following advanced fuel cladding tubes with burnups of up to 85 GWd/t: M-MDA, low-tin ZIRLO, M5, and Zircaloy-2 (LK3). These oxidation tests were performed in steam-flowing conditions at temperatures ranging from 1173 to 1473 K for durations between 120 and 4000 s, and the oxidation kinetics was evaluated. The oxidation kinetics of the high-burnup advanced fuel cladding tube specimens estimated by assuming the parabolic rate law was comparable to or slower than that of the unirradiated Zircaloy-4 cladding tube specimens reported in a previous study. It is considered that the protective effect of the corrosion layer hindered oxidation. Furthermore, no increase in the oxidation kinetics because of the pre-hydriding was observed. The onset times of the breakaway oxidations of these cladding tube specimens were comparable to those of the unirradiated Zircaloy-4 cladding tubes reported in previous studies. Therefore, it is considered that the burnup extension up to 85 GWd/t and the use of the advanced fuel cladding tubes do not significantly increase the oxidation kinetics and do not significantly reduce the onset time of the breakaway oxidation.