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Journal Articles

High-pressure-high-temperature study of benzene; Refined crystal structure and new phase diagram up to 8 GPa and 923 K

Chanyshev, A. D.*; Litasov, K. D.*; Rashchenko, S.*; Sano, Asami; Kagi, Hiroyuki*; Hattori, Takanori; Shatskiy, A. F.*; Dymshits, A. M.*; Sharygin, I. S.*; Higo, Yuji*

Crystal Growth & Design, 18(5), p.3016 - 3026, 2018/05

 Times Cited Count:19 Percentile:87.9(Chemistry, Multidisciplinary)

The high-temperature structural properties of solid benzene were studied at 1.5-8.2 GPa up to melting or decomposition using multi-anvil apparatus and in situ neutron and X-ray diffraction. The crystal structure of deuterated benzene phase II (P2$$_{1}$$/c unit cell) was refined at 3.6-8.2 GPa and 473-873 K. Our data show a minor temperature effect on the change in the unit cell parameters of deuterated benzene at 7.8-8.2 GPa. At 3.6-4.0 GPa, we observed the deviation of deuterium atoms from the benzene ring plane and minor zigzag deformation of the benzene ring, enhancing with the temperature increase caused by the displacement of benzene molecules and decrease of van der Waals bond length between the $$pi$$-conjuncted carbon skeleton and the deuterium atom of adjacent molecule. Deformation of benzene molecule at 723-773 K and 3.9-4.0 GPa could be related to the benzene oligomerization at the same conditions. In the pressure range of 1.5-8.2 GPa, benzene decomposition was defined between 773-923 K. Melting was identified at 2.2 GPa and 573 K. Quenched products analyzed by Raman spectroscopy consist of carbonaceous material. The defined benzene phase diagram appears to be consistent with those of naphthalene, pyrene, and coronene at 1.5-8 GPa.

Journal Articles

Hydrogenation of $$L$$1$$_{2}$$-type AlNi$$_{3}$$ alloy at high pressure and temperature

Endo, Naruki*; Saito, Hiroyuki; Machida, Akihiko; Katayama, Yoshinori

Journal of Alloys and Compounds, 645(Suppl.1), p.S61 - S63, 2015/10

 Times Cited Count:0 Percentile:0.01(Chemistry, Physical)

Journal Articles

Hydrogenation of a TiFe-based alloy at high pressures and temperatures

Endo, Naruki*; Saita, Itoko*; Nakamura, Yumiko*; Saito, Hiroyuki; Machida, Akihiko

International Journal of Hydrogen Energy, 40(8), p.3283 - 3287, 2015/03

 Times Cited Count:14 Percentile:37.74(Chemistry, Physical)

Journal Articles

Phase diagram of the Eu-H system at high temperatures and high hydrogen pressures

Saito, Hiroyuki; Machida, Akihiko; Matsuoka, Takehiro*; Aoki, Katsutoshi*

Solid State Communications, 205, p.24 - 27, 2015/03

 Times Cited Count:8 Percentile:37.33(Physics, Condensed Matter)

Journal Articles

Li$$_{4}$$FeH$$_{6}$$; Iron-containing complex hydride with high gravimetric hydrogen density

Saito, Hiroyuki; Takagi, Shigeyuki*; Matsuo, Motoaki*; Iijima, Yuki*; Endo, Naruki*; Aoki, Katsutoshi*; Orimo, Shinichi*

APL Materials (Internet), 2(7), p.076103_1 - 076103_7, 2014/07

 Times Cited Count:23 Percentile:69.69(Nanoscience & Nanotechnology)

Journal Articles

Single crystal growth of gallium nitride by slow-cooling of its congruent melt under high pressure

Saito, Hiroyuki; Utsumi, Wataru; Kaneko, Hiroshi*; Kiriyama, Koji*; Aoki, Katsutoshi

State-of-the-Art Program on Compound Semiconductors XLI and Nitride and Wide Bandgap Semiconductors for Sensors, Photonics, and Electronics V, p.587 - 592, 2004/10

Single crystals of GaN were successfully synthesized by slowly cooling its stoichiometric melt under high pressure. Applying high pressures above 6.0 GPa prevented decomposition and allowed the congruent melt of GaN at 2220$$^{circ}$$C, which was confirmed by an in situ X-ray diffraction study. Using a cubic-anvil-type, large volume, high-pressure apparatus and a GaN powder as a starting material, single crystal growth was achieved by reducing the temperature from 2400$$^{circ}$$C at 6.5 GPa. The X-ray rocking curve of the recovered sample showed a very narrow line width, less than 30 arcsec, suggesting a low dislocation density. Bulk specimens of Al$$_x$$Ga$$_{1-x}$$N alloys, which covered a composition range of 0$$leq$$x$$leq$$1 were also synthesized under high pressures.

Journal Articles

Synthesis of Al$$_{x}$$Ga$$_{1-x}$$N alloy by solid-phase reaction under high pressure

Saito, Hiroyuki; Utsumi, Wataru; Kaneko, Hiroshi*; Aoki, Katsutoshi

Japanese Journal of Applied Physics, Part 2, 43(7B), p.L981 - L983, 2004/07

 Times Cited Count:5 Percentile:24.35(Physics, Applied)

Bulk specimens of Al$$_{x}$$Ga$$_{1-x}$$N alloys covering a composition range of 0$$leq$$${it x}$$$leq$$1 were synthesized by a solid-phase reaction under high pressure. ${it In situ}$ X-ray diffraction profiles were measured to observe the alloying process, which began at around 800$$^{circ}$$C under 6.0 GPa. SEM observation and X-ray analysis of the recovered specimen indicated a uniform distribution of Al and Ga and continuous variations of the lattice constants against the composition, which implies that a solid solution of AlN and GaN is formed regardless of atomic composition.

Journal Articles

In situ X-ray observations of the decomposition of brucite and the graphite-diamond conversion in aqueous fluid at high pressure and temperature

Okada, Taku; Utsumi, Wataru; Kaneko, Hiroshi*; Yamakata, Masaaki*; Shimomura, Osamu

Physics and Chemistry of Minerals, 29(7), p.439 - 445, 2002/08

 Times Cited Count:16 Percentile:52.52(Materials Science, Multidisciplinary)

An experimental technique to make real-time observations at high pressure and temperature of the diamond forming process in candidate material of mantle fluids as a catalyst has been established for the first time. In situ X-ray diffraction experiments using synchrotron radiation have been performed upon a mixture of brucite (Mg(OH)$$_{2}$$) and graphite as starting material. Brucite decomposes into periclase (MgO) and H$$_{2}$$O at 3.6 GPa and 1050$$^{circ}$$C while no periclase is formed after the decomposition of brucite at 6.2 GPa and 1150$$^{circ}$$C, indicating that the solubility of the MgO component in H$$_{2}$$O greatly increases with increasing pressure. The conversion of graphite to diamond in aqueous fluid has been observed at 7.7 GPa and 1835$$^{circ}$$C. Time-dependent X-ray diffraction profiles for this transformation have been successfully obtained.

JAEA Reports

Study on high-performance fuel cladding materials; Joint research report in FY 1999-2000 (Phase 1) (Joint research)

Kiuchi, Kiyoshi; Ioka, Ikuo; Tachibana, Katsumi; Suzuki, Tomio; Fukaya, Kiyoshi*; Inohara, Yasuto*; Kambara, Shozo; Kuroda, Yuji*; Miyamoto, Satoshi*; Ogura, Kazutomo*

JAERI-Research 2002-008, 63 Pages, 2002/03


no abstracts in English

Journal Articles

Corrosion of aluminum in high pressure steam at temperatures above and below 320$$^{circ}$$C

Kondo, Tatsuo; ; Kawasaki, Masayuki

Trans.Jpn.Inst.Met., 3(2), p.110 - 118, 1962/00

no abstracts in English

Oral presentation

Aluminum-based interstitial hydride, Al$$_{2}$$CuH$$_{x}$$

Saito, Hiroyuki; Takagi, Shigeyuki*; Endo, Naruki*; Machida, Akihiko; Aoki, Katsutoshi; Orimo, Shinichi*; Katayama, Yoshinori

no journal, , 

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