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Journal Articles

Behavior of high-burnup advanced LWR fuel cladding tubes under LOCA conditions

Narukawa, Takafumi; Amaya, Masaki

Proceedings of International Nuclear Fuel Cycle Conference / Light Water Reactor Fuel Performance Conference (Global/Top Fuel 2019) (USB Flash Drive), p.912 - 921, 2019/09

Journal Articles

Oxidation behavior of high-burnup advanced fuel cladding tubes in high-temperature steam

Narukawa, Takafumi; Amaya, Masaki

Journal of Nuclear Science and Technology, 56(7), p.650 - 660, 2019/07

 Times Cited Count:10 Percentile:80.35(Nuclear Science & Technology)

Journal Articles

Oxidation kinetics of Zry-4 fuel cladding in mixed steam-air atmospheres at temperatures of 1273 - 1473 K

Negyesi, M.; Amaya, Masaki

Journal of Nuclear Science and Technology, 54(10), p.1143 - 1155, 2017/10

 Times Cited Count:6 Percentile:55.37(Nuclear Science & Technology)

Journal Articles

Actively controlled oxidation of Cu{001} with hyperthermal O$$_{2}$$ molecular beam

Okada, Michio*; Moritani, Kosuke; Goto, Seishiro*; Kasai, Toshio*; Yoshigoe, Akitaka; Teraoka, Yuden

Journal of Chemical Physics, 119(14), p.6994 - 6997, 2003/10

 Times Cited Count:42 Percentile:78.8(Chemistry, Physical)

The oxidation of Cu(001) with hyperthermal O$$_{2}$$ molecular beams was investigated using X-ray photoemission spectroscopy in conjunction with a synchrotron light source. The efficiency of oxidation is higher than that with ambient thermal O$$_{2}$$. Further oxidation under oxygen coverage larger than 0.5 ML occurs rather inefficiently even for the 2.3 eV beam irradiation. We found such slow oxidation of Cu corresponding to the initial stage of the Cu$$_{2}$$O formation can be interpreted in terms of a collision-induced-adsorption mechanism. The kinetics of the dissociative adsorption is well described using the first order kinetics in a simple Langmuir-type adsorption model.

Journal Articles

Real-time monitoring of initial thermal oxidation on Si(001) surfaces by synchrotron radiation photoemission spectroscopy

Yoshigoe, Akitaka; Moritani, Kosuke; Teraoka, Yuden

Japanese Journal of Applied Physics, Part 1, 42(6B), p.3976 - 3982, 2003/06

 Times Cited Count:6 Percentile:28.49(Physics, Applied)

It is well known that the thermal oxidation on Si(001) surface is an important reaction system to form of the gate-oxide films in MOSFET, since it is necessary to control the film thickness under a few nano-meter scale. Thus, we have studied the oxygen uptake and the Si oxidation states depending on the oxidation times by using the synchrotron radiation photoemission spectroscopy in 1$$times$$10$$^{-4}$$Pa of O$$_{2}$$ at the surface temperature from 870K to 1120K. We clarified the oxidation depending on the surface temperature was explained by the kinetics (Langumuir and auto-catalytic model). Using real time photoemission spectroscopy, we found that the Si$$^{4+}$$ sepcies was not formed at the initial oxidation stage.

Journal Articles

Oxidation kinetics of low-Sn Zircaloy-4 at the temperature range from 773 to 1573 K

Nagase, Fumihisa; Otomo, Takashi; Uetsuka, Hiroshi

Journal of Nuclear Science and Technology, 40(4), p.213 - 219, 2003/04

 Times Cited Count:64 Percentile:96.4(Nuclear Science & Technology)

Isothermal oxidation tests in flowing steam were performed on low-Sn Zircaloy-4 cladding tubes over the wide temperature range from 773 to 1573 K in order to obtain oxidation kinetics applicable to various loss-of-coolant accident conditions of LWRs. The oxidation generally obeys a parabolic rate law for the examined time range up to 3600s at temperatures from 1273 K to 1573K, and for a limited time range up to 900s from 773 to 1253 K. A cubic rate law is preferable for evaluating the longer-term oxidation at 1253 K and below. The parabolic rate law constant and the cubic rate law constant for measured weight gain were evaluated at every examined temperature, and Arrhenius-type equations were determined in order to describe the temperature dependence of the rate constants. It was indicated that the change of the oxidation kinetics from the cubic to the parabolic rate and the discontinuities in the temperature dependence of the rate constants are caused by the monoclinic/tetragonal phase transformation of ZrO$$_{2}$$.

JAEA Reports

Development of simulation code for MOX dissolution using silver-mediated electrochemical method (Contract research)

Kida, Takashi; Umeda, Miki; Sugikawa, Susumu

JAERI-Data/Code 2003-001, 29 Pages, 2003/03

JAERI-Data-Code-2003-001.pdf:6.34MB

MOX dissolution using silver-mediated electrochemical method will be employed for the preparation of plutonium nitrate solution in the criticality safety experiments in NUCEF. A simulation code for the MOX dissolution has been developed for the operating support. In this report an outline of the simulation code is proposed and a comparison with the experimental data and a parameter study on the MOX dissolution rate are described.The principle of this code is based on Zundelevich's model for PuO$$_{2}$$ dissolution using Ag$$^{2+}$$. The influence of nitrous acid on the material balance of Ag$$^{2+}$$ and the surface area of MOX powder on the basis of particle size distribution are taken into consideration in this model. A comparison with experimental data was carried out to confirm a validity of this model. It was confirmed that the behavior of MOX dissolution could adequately be simulated using the appropriate MOX dissolution rate constant. The parameters affecting the dissolution rate were studied, it was found that MOX particle size was major governing factor on the dissolution rate.

Journal Articles

Oxidation of zircaloy-4 under limited steam supply from 900 to 1,400$$^{circ}$$C

; ;

Journal of Nuclear Science and Technology, 23(10), p.928 - 930, 1986/00

 Times Cited Count:3 Percentile:54.23(Nuclear Science & Technology)

no abstracts in English

JAEA Reports

Development of an Apparatus for Cyclic Corrosion Test in Simulated VHTR Helium Environment

; Shindo, Masami; Kondo, Tatsuo

JAERI-M 83-093, 16 Pages, 1983/07

JAERI-M-83-093.pdf:1.45MB

no abstracts in English

Journal Articles

Oxidation kinetics and oxide film breakaway of zirconium and its alloys at high temperatures

;

Electrochem.Technol., 4(3-4), p.93 - 99, 1966/00

no abstracts in English

Oral presentation

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