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Journal Articles

High-pressure polymerization of phenol toward degree-4 carbon nanothread

Yang, X.*; Che, G.*; Wang, Y.*; Zhang, P.*; Tang, X.*; Lang, P.*; Gao, D.*; Wang, X.*; Wang, Y.*; Hattori, Takanori; et al.

Nano Letters, 25(3), p.1028 - 1035, 2025/01

https://doi.org/10.1021/acs.nanolett.4c04895

Times Cited Count：5 Percentile：86.72(Chemistry, Multidisciplinary)

Saturated sp-carbon nanothreads (CNTh) have garnered significant interest due to their predicted high Young's modulus and thermal conductivity. While the incorporation of heteroatoms into the central ring has been shown to influence the formation of CNTh and yield chemically homogeneous products, the impact of pendant groups on the polymerization process remains underexplored. In this study, we investigate the pressure-induced polymerization of phenol, revealing two phase transitions occurring below 0.5 and 4 GPa. Above 20 GPa, phenol polymerizes into degree-4 CNThs featuring hydroxyl and carbonyl groups. Hydrogen transfer of hydroxyl groups was found to hinder the formation of degree-6 nanothreads. Our findings highlight the crucial role of the hydroxyl group in halting further intracolumn polymerization and offer valuable insights for future mechanism research and nanomaterial synthesis.

Journal Articles

Degradation of 2-chlorophenol by -ray irradiation in zeolite/water mixtures

Kumagai, Yuta

Hoshasen Kagaku (Internet), (99), p.53 - 56, 2015/04

Radiation-induced degradation of 2-chlorophenol (2-ClPh) in zeolite/water mixtures was studied in order to consider a possibility of adsorption on zeolites to improve efficiencies of irradiation treatments of water contaminated by organic compounds. The degradation of 2-ClPh by -ray irradiation was investigated as a model compound. The degradation was evaluated by chloride ion (Cl $^{-}$ ) production. A high concentration of Cl $^{-}$ was observed after the irradiation of a mixture with a mordenite-type zeolite (NaMOR), whereas A-type and X-type zeolites showed no significant effect. Therefore, for the mixture with NaMOR, effects of pH of the solution and of the 2-ClPh concentration were examined. At pH 5.7, the excess production of Cl $^{-}$ was induced by the addition of NaMOR. Concurrently, adsorption of 2-ClPh on NaMOR was observed. When the mixture contained a higher concentration of 2-ClPh at pH 5.7, the Cl $^{-}$ production increased. The adsorption of 2-ClPh also increased with increasing concentration. The results suggest that organics adsorbed on zeolites are decomposed by irradiation effectively at high adsorption concentrations.

Journal Articles

Decomposition of -nonylphenols in water and elimination of their estrogen activities by $^{60}$ Co -ray irradiation

Kimura, Atsushi; Taguchi, Mitsumasa; Otani, Yoshimi*; Takigami, Machiko; Shimada, Yoshitaka*; Kojima, Takuji; Hiratsuka, Hiroshi*; Namba, Hideki

Radiation Physics and Chemistry, 75(1), p.61 - 69, 2006/01

https://doi.org/10.1016/j.radphyschem.2005.05.016

Times Cited Count：13 Percentile：63.58(Chemistry, Physical)

Decomposition of -Nonylphenols (NPs) in water at 1 mol dm $^{-3}$ was decreased exponentially with absorbed dose when NPs were irradiated by $^{60}$ Co-rays. Two products having molecular weight of 236, presumably OH adducts of NPs, were detected by LC-MS analyses. The elimination of estrogen activity of aqueous NPs solution including such irradiation products at 5000 Gy (J kg $^{-1}$ ) was confirmed by the yeast two hybrid assay. These results should expand the application of ionizing radiation to the treatment of NPs.

Journal Articles

Development of a heat-resistant neutron shielding resin for the national centralized tokamak

Morioka, Atsuhiko; Sakurai, Shinji; Okuno, Koichi*; Tamai, Hiroshi

Purazuma, Kaku Yugo Gakkai-Shi, 81(9), p.645 - 646, 2005/09

http://doi.org/10.1585/jspf.81.645

A 300 $^{circ}$ C heat-resistant neutron shielding material is newly developed, which consists of phenol-based resin with 5 weight-% boron. The neutron shielding performance of the developed resin, examined by the $^{252}$ Cf neutron source, is almost the same as that of the polyethylene. The resin is applicable to the port section of vacuum vessel of the DD plasma device to suppress the streaming neutrons and to reduce the nuclear heating of the superconducting coils.