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Journal Articles

Hydrogen absorption and diffusion behaviors in cube-shaped palladium nanoparticles revealed by ambient-pressure X-ray photoelectron spectroscopy

Tang, J.*; Seo, O.*; Rivera Rocabado, D. S.*; Koitaya, Takanori*; Yamamoto, Susumu*; Namba, Yusuke*; Song, C.*; Kim, J.*; Yoshigoe, Akitaka; Koyama, Michihisa*; et al.

Applied Surface Science, 587, p.152797_1 - 152797_8, 2022/06

 Times Cited Count:7 Percentile:75.56(Chemistry, Physical)

The hydrogen absorption and diffusion mechanisms on cube-shaped Pd nanoparticles (NPs) which are important hydrogen-storage materials were studied using X-ray photoelectron spectroscopy and DFT calculations. In the surface region, hydrogen absorption showed almost similar behavior regardless of the NPs size. It was found that the octahedral sites are more favorable than the tetrahedral sites for hydrogen occupation. We also clarified that the hydrogen atoms absorbing on the smaller-sized Pd NPs diffuse to the subsurface more actively because of the weakened Pd-H bond by the surface disordering, which plays an important role in hydrogen adsorption at a low H$$_{2}$$ pressure.

Journal Articles

Development of a plasma generator for a long pulse ion source for neutral beam injectors

Watanabe, Kazuhiro; Dairaku, Masayuki; Tobari, Hiroyuki; Kashiwagi, Mieko; Inoue, Takashi; Hanada, Masaya; Jeong, S. H.*; Chang, D. H.*; Kim, T. S.*; Kim, B. R.*; et al.

Review of Scientific Instruments, 82(6), p.063507_1 - 063507_6, 2011/06

 Times Cited Count:16 Percentile:58.89(Instruments & Instrumentation)

A long pulse plasma generator for neutral beam injectors has been developed. The plasma generator was designed to produce 65 A at 120 keV from a beam extraction area of 12 cm $$times$$ 46 cm. A type of the plasma generator is a multi-cusp plasma generator with SmCo permanent magnets. A long pulse test of the plasma generator was performed at the KSTAR NBI test stand in Korea under the Japan - Korea Fusion collaboration. It was successfully demonstrated of the long pulse operation of the plasma generator for 200 s at an arc discharge power of 70 kW which can produce 65 A beams. Plasma spatial uniformity at the beam extraction area was confirmed to be smaller than $$pm$$ 8% of the deviation from an averaged ion saturation current density. A high arc efficiency of 0.9-1.1 A/kW was obtained at the beam extraction with 73 keV, 41 A for 5 sec. From these experimental studies, a performance of this plasma generator for long pulse ion sources was confirmed.

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