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Journal Articles

Photoluminescence characterization of $$beta$$-FeSi$$_{2}$$ prepared by ion beam sputter deposition (IBSD) method

Zhuravlev, A. V.; Yamamoto, Hiroyuki; Shimura, Kenichiro*; Yamaguchi, Kenji; Shamoto, Shinichi; Hojo, Kiichi; Terai, Takayuki*

Thin Solid Films, 515(22), p.8149 - 8153, 2007/08

 Times Cited Count:3 Percentile:17.87(Materials Science, Multidisciplinary)

A semiconducting silicide, $$beta$$-FeSi$$_{2}$$, formed on a Si substrate, is known to exhibit strong photoluminescence (PL) peak at around 0.8 eV when it is annealed at high temperature (1073-1173 K). On the other hand, dislocation-related band of Si has intensity maxima at 0.81 eV. In the present study, the PL spectra were taken at the various stages of IBSD in order to understand the processes that are responsible for the observed PL enhancement. We observed a strong PL peak at around 0.8 eV in IBSD-grown $$beta$$-FeSi$$_{2}$$ film on Si substrate, as well as in substrate itself, upon thermal annealing in air at 1153 K. The most pronounced peak at 0.8 eV was observed when Si substrates were sputter etched by Ne$$^{+}$$, prior to the thermal annealing in air. However, the temperature dependence of peak intensity of $$beta$$-FeSi$$_{2}$$ was different from that of SE-treated Si, where thermal quenching appeared to occur at slightly lower temperature in the former.

Journal Articles

Growth of $$beta$$-FeSi$$_2$$ thin films on $$beta$$-FeSi$$_2$$ (110) substrates by molecular beam epitaxy

Muroga, Masataka*; Suzuki, Hirokazu*; Udono, Haruhiko*; Kikuma, Isao*; Zhuravlev, A. V.; Yamaguchi, Kenji; Yamamoto, Hiroyuki; Terai, Takayuki*

Thin Solid Films, 515(22), p.8197 - 8200, 2007/08

 Times Cited Count:6 Percentile:31.31(Materials Science, Multidisciplinary)

Semiconducting ${it $beta$}$-FeSi$$_2$$ has received much attention as a material for Si-based optoelectronic devices. There are a number of studies on heteroepitaxy of ${it $beta$}$-FeSi$$_2$$ film on Si. However, growth experiments of ${it $beta$}$-FeSi$$_2$$ film on single crystalline ${it $beta$}$-FeSi$$_2$$ substrate have not been investigated yet. Recently, single crystalline ${it $beta$}$-FeSi$$_2$$ with large growth facets by solution growth method using Ga solvent. By obtaining a smooth surface on the substrate, we have succeeded in growing ${it $beta$}$-FeSi$$_2$$ film on ${it $beta$}$-FeSi$$_2$$(110) substrate using molecular-beam epitaxy.

Oral presentation

On the improvement of photoluminescence properties of iron disilicide film fabricated on Si substrate

Yamaguchi, Kenji; Zhuravlev, A.; Shimura, Kenichiro; Yamamoto, Hiroyuki; Shamoto, Shinichi; Hojo, Kiichi

no journal, , 

no abstracts in English

Oral presentation

Photoluminescence characterization of ion beam sputter deposition process to fabricate $$beta$$-FeSi$$_2$$

Zhuravlev, A.; Yamaguchi, Kenji; Shimura, Kenichiro*; Yamamoto, Hiroyuki; Shamoto, Shinichi; Hojo, Kiichi; Terai, Takayuki*

no journal, , 

no abstracts in English

Oral presentation

Photoluminescence characteristics of ${it $beta$}$-FeSi$$_2$$ films on SOI substrate

Shimura, Kenichiro*; Zhuravlev, A. V.; Yamamoto, Hiroyuki; Yamaguchi, Kenji; Shamoto, Shinichi; Hojo, Kiichi; Terai, Takayuki*

no journal, , 

In order to improve PL characteristics of ${it $beta$}$-FeSi$$_2$$ film on SOI (silicon-on-insulator) substrate, a template method was employed to control the inter-diffusion processes at the interface of ${it $beta$}$-FeSi$$_2$$/SOI. In contrast to the case without employing template layer, the template method employed in the present study was found to be effective to enhance PL intensity of ${it $beta$}$-FeSi$$_2$$ film formed on SOI substrate.

Oral presentation

Sputter etching effects on photoluminescence of $$beta$$-FeSi$$_2$$ fabricated by ion beam sputter deposition method

Zhuravlev, A. V.; Yamamoto, Hiroyuki; Shimura, Kenichiro*; Yamaguchi, Kenji; Shamoto, Shinichi; Hojo, Kiichi; Terai, Takayuki*

no journal, , 

no abstracts in English

Oral presentation

Sputter etching effects on photoluminescence of $$beta$$-FeSi$$_{2}$$ grown on Si by ion beam sputter deposition method

Zhuravlev, A. V.; Yamamoto, Hiroyuki; Shimura, Kenichiro*; Yamaguchi, Kenji; Shamoto, Shinichi; Hojo, Kiichi; Terai, Takayuki*

no journal, , 

Semiconducting silicide, $$beta$$-FeSi$$_{2}$$ formed on Si, is known to exhibit photoluminescence (PL) peak at around 0.8 eV. However, substrate Si also has a luminescence peak at 0.80 eV, which nearly coincides with that of $$beta$$-FeSi$$_{2}$$, so that the origin of PL peak from $$beta$$-FeSi$$_{2}$$/Si is always a point of issue. In this study, the dependence of PL characteristics sputter etched (SE) Si and silicide on SE Si on ion beam energy applied to Si substrate was investigated. The PL intensity of the annealed $$beta$$-FeSi$$_{2}$$ on Si substrate increased as the SE energy applied to the substrate increased. In the case of 5 keV SE in both cases the strong PL signal was observed thereby indicating the contribution of irradiation defects to the observed PL spectra, but in case of no SE and 2 keV SE the PL intensity from silicide sample are higher than PL from SE Si. It can be concluded that the SE can be employed to control the PL properties of $$beta$$-FeSi$$_{2}$$ film on Si substrate.

Oral presentation

Nanostructural observation of interface between $$beta$$-FeSi$$_{2}$$ thin films and Si or silicon-on-insulator substrates

Sasase, Masato*; Zhuravlev, A.*; Shimura, Kenichiro*; Yamaguchi, Kenji; Yamamoto, Hiroyuki; Shamoto, Shinichi; Terai, Takayuki*; Hojo, Kiichi

no journal, , 

The effect of the substrate/film interface structure and compositional changes at the interface has been investigated by using two different substrates (Si(100), silicon-on-insulator (SOI)) with cross sectional transmission electron microscope (TEM). The observed images show that the $$beta$$-FeSi$$_{2}$$ on Si(100) were aggregated through the subsequent annealing, forming $$beta$$-FeSi$$_{2}$$ particles with the size of 20$$sim$$200 nm. In the SOI sample, expansion of the buried SiO$$_{2}$$ layer was significantly seen from TEM images and EDS mapping through the subsequent annealing. Aggregation also occurred to form 20$$sim$$30 nm $$beta$$-FeSi$$_{2}$$ particles with SOI substrate. No $$beta$$-FeSi$$_{2}$$/Si interface is observed since the SiO$$_{2}$$ layer swelled and top surface Si layer disappeared through the annealing. On the other hand, the $$beta$$-FeSi$$_{2}$$/Si interface is still observed even after the subsequent annealing when Si(100) substrate was employed.

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