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Journal Articles

An in situ M$"{o}$ssbauer study using synchrotron radiation

Masuda, Ryo; Mitsui, Takaya; Ito, Keiji*; Sakaki, Koji*; Enoki, Hirotoshi*; Nakamura, Yumiko*; Seto, Makoto

Hyperfine Interactions, 204(1-3), p.139 - 142, 2012/03

 Times Cited Count:2 Percentile:76.72(Physics, Atomic, Molecular & Chemical)

We have been developing a system for in situ M$"{o}$ssbauer studies using synchrotron radiation (SR) to elucidate the mechanism of hydrogenation processes. In the system, samples reacts in an atmosphere chamber and SR-based M$"{o}$ssbauer spectra using variable-frequency nuclear monochromator and energy spectra of inelastic nuclear resonant scattering (NRS) of SR are measured. As a feasibility study, the temperature dependence of the M$"{o}$ssbauer and inelastic NRS spectra of $$^{57}$$Fe in $$c$$-GdFe$$_2$$H$$_3$$ under vacuum were measured. In both spectra, clear differences were observed between 373 K and 573 K. These differences can be interpreted by the change of microscopic environment around Fe at the dehydrogenation. Thus, it is confirmed that this system works well enough to perform the in-situ M$"{o}$ssbauer study on the dehydrogenation of $$c$$-GdFe$$_2$$H$$_3$$.

Journal Articles

M$"{o}$ssbauer study on the SmFe$$_2$$ hydride through $$^{149}$$Sm and $$^{57}$$Fe

Masuda, Ryo; Mitsui, Takaya; Ito, Keiji*; Kobayashi, Yasuhiro*; Kitao, Shinji*; Seto, Makoto

Journal of the Physical Society of Japan, 81(3), p.034714_1 - 034714_6, 2012/03

 Times Cited Count:3 Percentile:26.68(Physics, Multidisciplinary)

Journal Articles

Relation between high ionic conductivity and boson peak in superionic glass

Arai, Masatoshi; Iwase, Hiroki; Nakamura, Mitsutaka; Otomo, Toshiya*; Kartini, E.*; Ito, Keiji*; Levett, S. J.*; Bennington, S. M.*

AIP Conference Proceedings 832, p.299 - 302, 2006/05

no abstracts in English

Journal Articles

The Design of the neutron total scattering spectrometer for hydrogenous materials at J-PARC-JSNS

Suzuya, Kentaro; Kameda, Yasuo*; Otomo, Toshiya*; Yoshida, Koji*; Ito, Keiji*; Fukunaga, Toshiharu*; Misawa, Masakatsu*

Journal of Neutron Research, 13(1-3), p.123 - 128, 2005/03

The design, performance, philosophy, lessons learned and advantages of the neutron total scattering spectrometer for hydrogenous materials, FAST, under consideration for the J-PARC-JSNS, are described. In particular, novel instrumentation concept such as the small fractional scattered neutron flight path, $$gamma$$= L$$_{2}$$/(L$$_{1}$$+L$$_{2}$$), where L$$_{1}$$ is the incident flight path, moderator to sample, L$$_{2}$$ is the scattered neutron flight path from sample to detector, is presented and their expected performance at the JSNS is considered.

Journal Articles

Inelasticity effect on neutron scattering intensities of the null-H$$_{2}$$O

Kameda, Yasuo*; Sasaki, Motoya*; Usuki, Takeshi*; Otomo, Toshiya*; Ito, Keiji*; Suzuya, Kentaro; Fukunaga, Toshiharu*

Journal of Neutron Research, 11(3), p.153 - 163, 2003/09

We describe results of time-of-flight (TOF) neutron diffraction of the liquid water null-H$$_{2}$$O in order to investigate the effect of both the scattering angle and the neutron flight path ratio to the observed self-scattering intensities. An empirical inelasticity correction procedure is proposed using the self-scattering intensity observed for the null-H$$_{2}$$O.

Oral presentation

$$^{149}$$Sm synchrotron M$"{o}$ssbauer studies on hydrides of rare-earth-iron compounds

Masuda, Ryo; Mitsui, Takaya; Ito, Keiji*; Kobayashi, Yasuhiro*; Kitao, Shinji*; Seto, Makoto

no journal, , 

no abstracts in English

Oral presentation

$$^{149}$$Sm synchrotron M${"o}$ssbauer studies on hydrides of rare-earth-iron compounds SmFe$$_2$$

Masuda, Ryo; Mitsui, Takaya; Ito, Keiji*; Kobayashi, Yasuhiro*; Kitao, Shinji*; Seto, Makoto

no journal, , 

no abstracts in English

Oral presentation

M$"{o}$ssbauer study on the hydrides of C15 RFe$$_2$$ (R=Sm,Gd) compounds

Masuda, Ryo; Mitsui, Takaya; Ito, Keiji*; Sakaki, Koji*; Enoki, Hirotoshi*; Nakamura, Yumiko*; Kobayashi, Yasuhiro*; Kitao, Shinji*; Seto, Makoto

no journal, , 

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