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Kimura, Hiromi*; Sasaki, Masayoshi*; Morimoto, Yasutomi*; Takeda, Tsuyoshi*; Kodama, Hiroshi*; Yoshikawa, Akira*; Oyaizu, Makoto*; Takahashi, Koji; Sakamoto, Keishi; Imai, Tsuyoshi; et al.
Journal of Nuclear Materials, 337-339, p.614 - 618, 2005/03
Times Cited Count:7 Percentile:44.9(Materials Science, Multidisciplinary)no abstracts in English
Sasaki, Masayoshi*; Morimoto, Yasutomi*; Kimura, Hiromi*; Takahashi, Koji; Sakamoto, Keishi; Imai, Tsuyoshi; Okuno, Kenji*
Journal of Nuclear Materials, 329-333(Part1), p.899 - 903, 2004/08
A CVD diamond has been the reference material of a torus widow for a rf heating system in a fusion reactor. Since the window is in the circumstance of tritium, helium and radio activated dust, it is important to elucidate the effect of ions on chemical structure of the diamond, existing states of tritium and tritium inventory. Polycrystalline CVD diamond disks(=10.0mm, t=0.21mm) used in this study are the same grade as rf windows. After sputtering the surface with 1.0 keV Ar to remove oxygen impurity, the sample was irradiated with deuterium (D) or helium ions (He) at an angle of 0 degrees to the surface normal. The irradiation energies of deuterium and helium are 0.25 keV D and 0.45 keV He, respectively. The structural change of the irradiated sample was measured by X-ray Photoelectron Spectroscopy (XPS) technique. The C1s peak shift toward lower binding energy side was observed when deuterium ions irradiated. This result indicates that the diamond changes to amorphous carbon due to formation of C-D bond.
Sasaki, Masayoshi*; Morimoto, Yasutomi*; Kimura, Hiromi*; Takahashi, Koji; Sakamoto, Keishi; Imai, Tsuyoshi; Okuno, Kenji*
Journal of Nuclear Materials, 329-333(1), p.899 - 903, 2004/08
Times Cited Count:4 Percentile:29.26(Materials Science, Multidisciplinary)no abstracts in English
Shimoyama, Iwao; Baba, Yuji; Sekiguchi, Tetsuhiro; Nath, K. G.; Sasaki, Masayoshi*; Okuno, Kenji*
Journal of Vacuum Science and Technology A, 21(6), p.1843 - 1848, 2003/11
Times Cited Count:6 Percentile:28.18(Materials Science, Coatings & Films)Ion implantation method is applied to synthesize B-C-N hybrids and their electronic structures are characterized by X-ray photoelectron spectroscopy. A boron nitride film is deposited on a graphite target by borazine plasma implantation. At the interface between the BN film and the graphite, variety of bonding combinations including B-N, B-C, and C-N are observed. This proved that B-C-N hybrids is formed by this method.
Morimoto, Yasutomi*; Sasaki, Masayoshi*; Kimura, Hiromi*; Sakamoto, Keishi; Imai, Tsuyoshi; Okuno, Kenji*
Fusion Engineering and Design, 66-68, p.651 - 656, 2003/09
Times Cited Count:3 Percentile:25.79(Nuclear Science & Technology)no abstracts in English