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Aoyama, Takahito; Kato, Chiaki; Sato, Tomonori; Sano, Naruto; Yamashita, Naoki; Ueno, Fumiyoshi
Zairyo To Kankyo, 71(4), p.110 - 115, 2022/04
no abstracts in English
Kato, Chiaki; Yamagishi, Isao; Sato, Tomonori; Yamamoto, Masahiro*
Zairyo To Kankyo, 70(12), p.441 - 447, 2021/12
Zeolite particles have been used in a Cs adsorption vessel for purification of contaminated water in Fukushima Dai-ich Nuclear Power Station (1F). The used Cs adsorption vessels were kept in storage space on 1F site. The risk of localized corrosion of stainless steel used in the vessel was worried. To evaluate the risk of localized corrosion, using specially designed electrochemical testing apparatus was used under gamma-ray irradiation test. And, real size mock-up test conducted. The results showed the potential change caused by creation of HO by water radiolysis decreased by zeolite particles and the enrichment of chloride ion concentration in the vessel do not propagate during dry up procedure of Cs adsorption vessel. These data indicate the risk of localized corrosion of Cs adsorption vessel may stay at considerably low level.
Sato, Tomonori; Hata, Kuniki; Kaji, Yoshiyuki; Ueno, Fumiyoshi; Inoue, Hiroyuki*; Taguchi, Mitsumasa*; Seito, Hajime*; Tada, Eiji*; Abe, Hiroshi*; Akiyama, Eiji*; et al.
JAEA-Review 2021-001, 123 Pages, 2021/06
In the implement of the decommissioning of Fukushima Daiichi Nuclear Power Station (1F), there are many problems to be solved. Specially, the mitigation of the aging degradation by the corrosion of the structural materials is important to implement the decommissioning safely and continuously. However, there are limited data for the environmental factors of corrosion in 1F, and the condition of 1F is continuously changing. So, the literature data for the water radiolysis and the corrosion under irradiation are listed as the database of corrosion under irradiation in this report. And the new obtained radiolysis and corrosion data, which have not been reported in the literature and will be required in the decommissioning of 1F, are reported.
Omori, Atsushi*; Akiyama, Eiji*; Abe, Hiroshi*; Hata, Kuniki; Sato, Tomonori; Kaji, Yoshiyuki; Inoue, Hiroyuki*; Taguchi, Mitsumasa*; Seito, Hajime*; Tada, Eiji*; et al.
Zairyo To Kankyo, 69(4), p.107 - 111, 2020/04
To evaluate the effect of oxidants, which are formed by radiolysis of water under gamma ray irradiation, on the corrosion of a carbon steel in humid environment, ozone was introduced as a model oxidant in to humidity-controlled air at 50C in a thermo-hygrostat chamber. Corrosion monitoring was performed by using an Atmospheric Corrosion Monitor-type (ACM) sensor consisting of a carbon steel anode and an Ag cathode. The output current of the ACM sensor was increased with the increase in relative humidity and it was obviously increased with the increase in the introduced ozone concentration at each relative humidity. The results indicate that ozone accelerates the corrosion of the carbon steel. The effect of ozone on the corrosion acceleration is attributed to the fast reduction reaction and fast dissolution reaction in to water compared to that of oxygen.
Otani, Kyohei; Sato, Tomonori; Kaji, Yoshiyuki; Yamamoto, Masahiro
JAEA-Review 2019-007, 15 Pages, 2019/06
Metallic pipes under solid-liquid two phase flow is damaged by collision of solid particle to the pipe walls, and this phenomenon is named "erosion". In the case of the liquid is corrosive solution, further damage is occurred on the pipe walls chemically, and this named "erosion-corrosion". In the Fukushima Daiichi decommissioning project, the fuel debris will be crushed during removal operation of the debris and micro debris particles would be generated. It is estimated that the pipes of the circulating cooling system would be damaged under the solid-liquid two phase flow containing fuel debris particles. For the reason, the previous study about erosion and erosion-corrosion of metallic materials under solid-liquid two phase flow was surveyed. The survey showed that the damage rate by erosion and erosion-corrosion is influence by a lot of parameter in comparison to the corrosion rate which occurred in no-flow solution. Therefore, it is necessary to pay attention to selecting the experimental method and condition before the investigation about erosion-corrosion of metallic materials under solid-liquid two phase flow is carried out.
Yamamoto, Masahiro; Sato, Tomonori; Igarashi, Takahiro; Ueno, Fumiyoshi; Soma, Yasutaka
Proceedings of European Corrosion Congress 2017 (EUROCORR 2017) and 20th ICC & Process Safety Congress 2017 (USB Flash Drive), 6 Pages, 2018/09
The authors have studied the differences between outer surface and the crevice-like portion of SUS316L in high pressurized and high temperature water containing dissolved oxygen. We have already introduced that changes in the characteristics of corrosion products along the crevice directions and gap width. It is suggested that the environmental conditions are different with the features of crevice from these results. In this report, we introduce the changes in oxide films with crevice gaps and comparison with the numerical simulation data utilizing of FEM calculation.
Hata, Kuniki; Sato, Tomonori; Motooka, Takafumi; Ueno, Fumiyoshi; Hanawa, Satoshi; Kasahara, Shigeki; Tsukada, Takashi
Journal of Nuclear Science and Technology, 53(8), p.1183 - 1191, 2016/08
Times Cited Count:6 Percentile:49.29(Nuclear Science & Technology)Kato, Chiaki; Sato, Tomonori; Ueno, Fumiyoshi; Yamagishi, Isao
Proceedings of 17th International Conference on Environmental Degradation of Materials in Nuclear Power Systems - Water Reactors, Vol.2, p.1357 - 1374, 2016/05
With respect to the long-term storage of the zeolite-containing spent Cs adsorption vessels used at the Fukushima Daiichi Nuclear Power Station, the corrosion of the vessel material is one of the most important issues. In this study, we performed electrochemical tests on stainless steel specimens in zeolite-containing artificial seawater under gamma-ray irradiation. The spontaneous potential ESP and critical pitting potential VC of the type 316L steel in systems in contact with various zeolites were measured in order to evaluate the corrosion resistance of the steel. In addition, the water sample was analyzed after being irradiated, in order to determine the concentrations of various dissolved oxidants such as oxygen and hydrogen peroxide, which can accelerate the corrosion process. The steady-state rest potential increased with an increase in the dose rate; however, the increase was suppressed in contact with the zeolites. The VC value of the steel when in contact with the zeolites was slightly smaller than the VC value in bulk water; however, the choice of the zeolite used as herschelite, IE96 and IE911 hardly affect the VC value. The concentration of HO in the bulk water under irradiation also increased with the increase in the dose rate. This increase was suppressed in the systems in contact with the zeolites, owing to the decomposition of the HO by the zeolites. A clear relationship was observed between ESP and the HO concentration. As contact with the zeolites caused the increase in ESP under irradiation to be suppressed, it can be concluded that the presence of zeolites in the spent Cs adsorption vessels can reduce the probability of the localized corrosion of the stainless steel in the vessels.
Yamamoto, Masahiro; Komatsu, Atsushi; Sato, Tomonori; Nakano, Junichi; Ueno, Fumiyoshi
Proceedings of 17th Asian Pacific Corrosion Control Conference (APCCC-17) (USB Flash Drive), 8 Pages, 2016/01
In Fukushima-Daiichi Nuclear Power Station, decommissioning procedures are continuing more than 30 years until fuel debris removal. It is important to keep soundness of primary container vessel (PCV), made of carbon steel, during these procedures. Corrosion of carbon steel is well-known to be controlled by cathodic reaction, in usual, oxygen reduction reaction. Corrosion of carbon steel could be mitigated by nitrogen injection procedure. However, a lot of radioactive materials exist in cooling water, an effect of radiolysis product on corrosion is an important problem. Clarifying an irradiation effect for corrosion of carbon steel, corrosion test was conducted in Co -ray irradiated condition. Electrochemical measurements were conducted to determine cathodic current density of samples. Corrosion rates of carbon steel decrease with time in both -ray irradiated and non-irradiated conditions. Measured values of cathodic current density gradually decreased with time and then stayed at constant value.
Kato, Chiaki; Sato, Tomonori; Nakano, Junichi; Ueno, Fumiyoshi; Yamagishi, Isao; Yamamoto, Masahiro
Nihon Genshiryoku Gakkai Wabun Rombunshi, 14(3), p.181 - 188, 2015/09
In relation to the consideration for long-term storage of spent Cs adsorption vessels containing zeolites in the Fukushima Daiichi Nuclear Power Station, corrosion of the vessel material in the spent Cs adsorption vessel is one of important issues. We performed electrochemical tests of stainless steel (SUS 316L) in the zeolites containing artificial seawater under -ray irradiation. The spontaneous potential () and critical pitting potential (), of SUS 316L were measured to understand the corrosion resistance of the stainless steel in this study. The rest potential of the stainless steel increased with increasing time after -ray irradiation. The , defined as the steady rest potential, increased with increasing dose rate, while increasing was suppressed by contact with the zeolites. Concentration of HO in bulk water increased with increasing dose rate. The concentration increasing was suppressed by contact with the zeolites due to decomposition of HO. There was good relationship between and the concentration of HO. The of SUS 316L contacted with the zeolites decreased with increasing Cl ion concentration and is slightly smaller than the in the bulk water. The contact with the zeolites causes the suppressant of increasing under the irradiation. The contact with the zeolite can reduce probability in the localized corrosion for SUS 316L.
Yamamoto, Masahiro; Sato, Tomonori; Komatsu, Atsushi; Nakano, Junichi; Ueno, Fumiyoshi
Proceedings of European Corrosion Congress 2015 (EUROCORR 2015) (USB Flash Drive), 7 Pages, 2015/09
In Fukushima-Daiichi Nuclear Power Station, decommissioning procedures are continuing and it will take more than 30 years. As some structures are made of carbon steel, degradation by corrosion is large problem for structural reliability. To clarify an irradiation effect for corrosion of carbon steel, corrosion test was con-ducted in Co -ray irradiated condition. Corrosion test results showed that corrosion rates of -ray irradiated condition increased with -ray dose rates. The oxidant concentrations were also increased with -ray dose rate. From these results, a new estimation method for corrosion rate of carbon steel in water with -ray irradiated condition using radiolysis calculation is introduced and discussed.
Kato, Chiaki; Sato, Tomonori; Ueno, Fumiyoshi; Yamagishi, Isao; Yamamoto, Masahiro
Zairyo To Kankyo 2015 Koenshu (CD-ROM), p.83 - 86, 2015/05
In relation to the consideration for long-term storage of spent Cs adsorption vessels containing zeolites in the Fukushima Daiichi Nuclear Power Station, corrosion of the vessel material in the spent Cs adsorption vessel is one of important issues. We performed electrochemical tests of stainless steel (SUS 316L) in the zeolites containing artificial seawater under gamma-ray irradiation. The spontaneous potential (ESP) and critical pitting potential (VC), of SUS316L were measured to understand the corrosion resistance of the stainless steel in this study. The rest potential of the stainless steel increased with increasing time after gamma-ray irradiation. The ESP, defined as the steady rest potential, increased with increasing dose rate, while increasing ESP was suppressed by contact with the zeolites. Concentration of HO in bulk water increased with increasing dose rate. The concentration increasing was suppressed by contact with the zeolites due to decomposition of HO. There was good relationship between ESP and the concentration of HO. The VC of SUS316L contacted with the zeolites decreased with increasing Cl ion concentration and is slightly smaller than the VC in the bulk water. The contact with the zeolites causes the suppressant of increasing ESP under the irradiation. The contact with the zeolites can reduce probability in the localized corrosion for SUS316L.
Motooka, Takafumi; Sato, Tomonori; Yamamoto, Masahiro
Nihon Genshiryoku Gakkai Suikagaku Bukai Bukaiho, 7 (Internet), 2 Pages, 2015/03
At the Fukushima Daiichi Nuclear Power Plant, the seawater was injected into Spent Fuel Pool (SFP) after the accident in March 2013. It is considered that corrosion in SFP will be accelerated by the seawater injection. To prevent the corrosion, Tokyo Electronic Power Company injected hydrazine into SFP. We confirmed the hydrazine injection effect in a short time by irradiation test.
Sato, Tomonori; Yamamoto, Masahiro; Tsukada, Takashi; Kato, Chiaki
Zairyo To Kankyo, 64(3), p.91 - 97, 2015/03
In the boiling water reactors (BWRs), reactor cooling water is maintained in high purity condition by controlling of a deionizing and deaerating apparatus, however HO contains by water radiolysis. In order to determine the corrosive condition in high-temperature pure water containing HO, the electrochemical impedance spectroscopy was performed in this study. To simulate BWR condition precisely, the measurements were performed without any electrolyte. The obtained impedance responses were changed with the HO concentration. The solution resistance and polarization resistance were determined by the equivalent circuit analyses. The conductivity was determined by the obtained solution resistance and the calculation of the current flow between the working electrode and the counter electrode by the 3-demensional finite element method. The value, 4.410 S/cm, was obtained as the conductivity of the pure water at 288C. The reciprocal of the obtained polarization resistance increased in proportion with HO concentration. This indicates that the corrosion current density was determined by the diffusion limiting current density of HO. The diffusion coefficient of HO at 288C was determined using the relationship between the reciprocal of the polarization resistance and HO concentration. The obtained diffusion coefficient was 1.510 cm/s. This is about twice larger than that of the reported value of O.
Yamamoto, Masahiro; Nakano, Junichi; Komatsu, Atsushi; Sato, Tomonori; Tsukada, Takashi
Proceedings of 19th International Corrosion Congress (19th ICC) (CD-ROM), 6 Pages, 2014/11
Corrosion protection of RPV and PCV is an important issue for the long term maintenance until the end of the decommissioning procedures. One of the uncertain factors for the issue is an effect of radioactivity on corrosion of LAS and CS. Corrosion tests using LAS and CS were conducted in -rays irradiated condition. Oxygen and hydrogen peroxide concentrations in the water were measured after the tests. Corrosion test results indicated that the amounts of corrosion increased by -rays irradiation both air and nitrogen atmosphere. And also corrosion amounts increased with -ray dose rates. Electrochemical analyses indicated that cathodic reaction of Hydrogen peroxide was controlled by diffusion process. The measured diffusion constant of HO was about 0.75 times to that of oxygen. From these results, it is estimated that corrosion of LAS and CS in -ray irradiated condition was evaluated by the cathodic reduction reaction of oxidant.
Yamamoto, Masahiro; Katayama, Hideki*; Sato, Tomonori; Tsukada, Takashi
Proceedings of 2014 Nuclear Plant Chemistry Conference (NPC 2014) (USB Flash Drive), 6 Pages, 2014/10
In the Fukushima Dai-ichi Nuclear Power Plant, seawater and natural river water were poured for emergency cooling. Corrosion of materials was worried because of high chloride ion concentration from seawater. The chloride ion concentration was decreased by de-chlorination operation. However, the water was not treated in the viewpoint of microbial breeding, so that many microbes could be alive and microbially induced corrosion (MIC) was worried. So, we attempted to examine the ability of MIC occurrence by using of corrosion potential analysis. Corrosion potentials of samples rose to about 300 mV nobler than the initial values in the NB added solution. The potentials of the welded samples more easily rose than the simple plate. These potential changes are attributed to the biofilms formed on the sample surface. After about 100 days' immersion, evidence of localized corrosion was not observed. More immersion time is needed to clarify the MIC ability.
Kato, Chiaki; Sato, Tomonori; Nakano, Junichi; Ueno, Fumiyoshi; Yamagishi, Isao
Proceedings of 2014 Nuclear Plant Chemistry Conference (NPC 2014) (USB Flash Drive), 9 Pages, 2014/10
As a part of consideration for long-term storage of spent zeolite adsorption vessels in the Fukushima Daiichi Nuclear Power Station, corrosion of vessel material in the spent zeolite adsorption vessel is one of important issue. We performed electrochemical tests of stainless steel (type 316L) in the zeolite containing artificial seawater under -ray irradiation. Steady spontaneous potential (Esp) and pitting potential (VC), of type 316L was measurement. Co -rays source was used under irradiation. Dose rate of -ray irradiation was controlled for 5 kGy/h and 400 Gy/h. In anode polarization curves, there was no clear difference under irradiation and non-irradiation. The corrosion potential of type 316L increased with increasing time after -ray irradiation. The Esp was shifted to nobler by -rays irradiation, while increasing Esp was suppressed by contacted with zeolite.
Yamagishi, Isao; Nagaishi, Ryuji; Kato, Chiaki; Morita, Keisuke; Terada, Atsuhiko; Kamiji, Yu; Hino, Ryutaro; Sato, Hiroyuki; Nishihara, Kenji; Tsubata, Yasuhiro; et al.
Journal of Nuclear Science and Technology, 51(7-8), p.1044 - 1053, 2014/07
Times Cited Count:19 Percentile:78.38(Nuclear Science & Technology)For safe storage of zeolite wastes generated by treatment of radioactive saline water at the Fukushima Daiichi Nuclear Power Station, properties of the Herschelite adsorbent were studied and its adsorption vessel was evaluated for hydrogen production and corrosion. Hydrogen production depends on its water level and dissolved species because hydrogen is oxidized by radicals in water. It is possible to evaluate hydrogen production rate in Herschelite submerged in seawater or pure water by taking into account of the depth effect of the water. The reference vessel of decay heat 504 W with or without residual pure water was evaluated for the hydrogen concentration by thermal hydraulic analysis using obtained fundamental properties. Maximum hydrogen concentration was below the lower explosive limit (4 %). The steady-state corrosion potential of a stainless steel 316L increased with absorbed dose rate but its increase was repressed by the presence of Herschelite. At 750 Gy/h and 60C which were values evaluated at the bottom of the vessel of 504 W, the localized corrosion of SUS316L contacted with Herschelite would not immediately occur under 20,000 ppm of Cl concentration.
Yamamoto, Masahiro; Sato, Tomonori
Zairyo To Kankyo, 63(4), p.193 - 198, 2014/04
In Japan, all nuclear power plants were stopped at this time (2013 Dec.), because of an application to new regulatory requirements of Nuclear Regulation Authority (NRA). It is, however, recognized to one of the important energy source in some foreign countries after the Fukushima Dai-ichi accident. The running costs are much smaller than the other energy sources, especially renewable energy sources. Also, the emission of CO is very low level compare to the fossil fuels. In this report, some issues of nuclear power plants from the viewpoint of corrosion are noted and the expected research activities at near future on corrosion are documented.
Nakano, Junichi; Sato, Tomonori; Kato, Chiaki; Yamamoto, Masahiro; Tsukada, Takashi; Kaji, Yoshiyuki
Journal of Nuclear Materials, 444(1-3), p.454 - 461, 2014/01
Times Cited Count:3 Percentile:23.92(Materials Science, Multidisciplinary)Cracking growth tests were conducted in high-temperature water containing hydrogen peroxide (HO) at 561 to 423 K to evaluate the effects of HO on stress corrosion cracking (SCC) of stainless steel (SS) at temperature lower than the boiling water reactor (BWR) operating temperature. Small compact tension (CT) specimens were prepared from thermally sensitized type 304 SS. Despite the observation of only a small portion intergranular SCC (IGSCC) near the side groove of the CT specimen at 561 K in high-temperature water containing 100 ppb of HO, the IGSCC area expanded to the central region of the CT specimens at 423 and 453 K. Effects of HO on SCC appeared intensely at temperature lower than the BWR operating temperature. To estimate the environment in the cracks, outer oxide distribution on the fracture surface and fatigue pre-crack were examined by laser Raman spectroscopy and thermal equilibrium calculation was performed.